中文摘要
經由化學氧化法，十二羰三釕[Ru3(CO)12]與含磷雙牙配子1,6-雙二苯己烷（Ph2P(CH2)6PPh2(dpph)）和1,5-雙二苯戊烷（Ph2P(CH2)5PPh2(dpppe)）反應，生成[{Ru3(CO)11}2(μ-dpph)] ( 1 )及[{Ru3(CO)11}2(μ-dpppe)] ( 1a )兩個配位化合物。
經由水熱法以含氮配子2,2'-雙嘧啶（2,2'-bipyrimidine），含磷配子1,1-雙二苯甲烷（Ph2P(CH2)PPh2(dppm)）和氯化釕反應，可得
[{RuCl2(dppm)}2(bpym)] ( 2 )。
以含氮配子2,2'-雙嘧啶（2,2'-bipyrimidine）、二氯對焜酸（chloranilic acid (H2CA)）利用擴散法分別和硝酸銅及氯化鋅反應，可得[Cu(CA)(bpym)(H2O)]·H2O ( 3 )及[Zn2(CA)2(H2O)4(bpym)]·H2O
( 4 )。
以氯化鈷和啶-3,5-雙酸（pyridine-3,5-dicarboxylic acid (3,5-pdc)），及4,4'-雙啶（4,4'-bipyridine）分別經由水熱法、擴散法進行反應，形成[Co(3,5-pdc) (H2O)5]·2H2O ( 5 )、[Co(3,5-pdc)(H2O)2]
( 6 )及[Co(4,4'-bipy) (H2O)4] (3,5-pdc)·3H2O ( 7 )。
以含氮配子反式-4-啶丙烯酸（trans-4-pyridylacrylic acid）和氯化鎳及氯化鈷經水熱法反應，可得[Ni(trans-4-pyridylacrylate)2
(H2O)2] ( 8 )及[Co(trans-4-pyridylacrylate)2]( 9 )。
以上產物，其中( 1 )、( 2 )、( 3 )、( 4 )、( 5 )、( 6 ) 、( 7 )、( 8 ) 、( 9 )已由X射線單晶繞射獲得晶體結構，( 1a )則經由紅外線光譜
及相關數據預測其結構。
( 1 )之深紅色晶體屬單斜晶系，空間群P 21/c，a = 9.771(2) Å，
b = 23.676(3) Å，c = 14.580(3) Å，β = 92.27(2)，最後Rf = 0.045（3665個繞射點）。分子為雙單元單取代結構，有一個反置中心位於C14
與C14A兩個原子中間。
( 2 )之黑色片狀晶體屬單斜晶系，空間群P 21/c，a = 11.262(4) Å， b = 16.584(3) Å，c = 15.352(6) Å，β = 109.77(4)，最後Rf = 0.047（3532個繞射點）。分子為雙聚合物，有一個反置中心位於C3與C3A
中間。
( 3 )之黑色晶體屬單斜晶系，空間群P 21 /c，a = 9.283(2) Å， b = 13.514(3) Å，c = 13.486(3) Å，β = 94.303(2)，最後Rf = 0.0464（3429
個繞射點）。為一單分子錯合物。
( 4 )之黑色晶體屬三斜晶系，空間群P 1，a=8.134(2) Å， b = 9.573(2) Å，c = 10.111(2) Å，α = 82.39(2)，β =72.22(2)，γ= 69.78(2)，最後Rf = 0.023 ( 2495個繞射點)。分子為雙聚合物，有一
個反置中心位於C4與C4A兩個原子中間。
( 5 )之橘黃色晶體屬立方晶系，空間群P na21，a = 15.846(3) Å，
b = 11.725(1) Å，c = 6.978(1) Å，最後Rf = 0.037（1519個繞射點）。
( 6 )之紫紅色晶體屬單斜晶系，空間群C 2/c，a = 9.911(1) Å，
b = 11.987(2) Å，c = 7.4062(9) Å，β = 105.173(2)，最後Rf = 0.059（911個繞射點）。其結構為二維網狀的聚合物。
( 7 )之橘黃色晶體屬三斜晶系，空間群P 1，a = 6.992(3) Å，
b = 11.440(7) Å，c = 14.084(2) Å，α= 105.31(3)，β = 92.82(2)，
γ= 94.56(4)，最後Rf = 0.049（3031個繞射點）。分子為聚合物，分子主體為以4,4'-雙啶配子橋接鈷原子之一維鏈狀結構。
( 8 )之淺藍色晶體屬立方晶系，空間群P can，a = 6.9948(9) Å，
b = 13.735(2) Å，c = 16.723(8) Å，最後Rf = 0.031（1225個繞射點）。
其結構為二維網狀的聚合物。
( 9 )之紫紅色晶體屬單斜晶系，空間群C c，a = 11.536(3) Å， b = 21.2140(2) Å，c =8.523(1) Å，β= 130.53(2)，最後Rf = 0.033（1370
個繞射點）。其結構為鑽石型三維網狀結構。

Abstract
The reaction of [Ru3(CO)12] with Ph2P(CH2)6PPh2(dpph) or Ph2P(CH2)5PPh2(dpppe) by the chemical oxidation method with TMNO as initator yielded two complexes : [{Ru3(CO)11}2(μ-dpph)] ( 1 ) and[{Ru3(CO)11}2(μ-dpppe)] ( 1a ).
Treatment of 2,2'-bipyrimidine and Ph2PCH2PPh2 (dppm) with RuCl3 by hydrothermal method afforded [{RuCl2(dppm)}2(bpym)] ( 2 ).
The reaction of 2,2'-bipyrimidine, and H2CA(chloranilic acid) with Cu(NO3)2·2H2O or ZnCl2 by the diffusion method yielded two complexes : [Cu(CA)(bpym)(H2O)]·H2O ( 3 ) and[Zn2(CA)2(H2O)4(bpym)]·2H2O
( 4 )。
The reaction of CoCl2·6H2O with pyridine-3,5-dicarboxylic acid by the hydrothermal method or the diffusion method yielded three complexes :[Co(3,5-pdc)(H2O)5]·2H2O ( 5 ), [Co(3,5-pdc)(H2O)2] ( 6 )and [Co(4,4'-bipy) (H2O)4] (3,5-pdc)·3H2O ( 7 )。
We treated trans-4-pyridylacrylic acid with NiCl2·6H2O or CoCl2·6H2O by the hydrothermal method to give complexes [Ni(trans-4-pyridylacrylate)2(H2O)2] ( 8 ) and [Co(trans-4-pyridylacrylate)2] ( 9 )。
Crystal structures of the complexes (1), (2), (3), (4), (5), (6), (7), (8) and (9) have been determined by the X-ray diffraction method.
(1), Monoclinic, space group P 21/c, a = 9.771(2) Å, b = 23.676(3) Å, c = 14.580(3) Å, β = 92.27(2), Final Rf = 0.045 for 3665 observations.
(2), Monoclinic, space group P 21/c, a = 11.262(4) Å, b = 16.584(3) Å, c = 15.352(6) Å, β = 109.77(4), Final Rf = 0.047 for 3532 observations.
(3), Monoclinic, space group P 21/c, a = 9.283(2) Å, b = 13.514(3) Å, c = 13.486(3) Å, β = 94.303(2), Final Rf = 0.0464 for 3429 observations.
(4), Triclinic, space group P, a=8.134(2) Å， b = 9.573(2) Å，c = 10.111(2) Å，α = 82.39(2)，β =72.22(2)，γ= 69.78(2), Final
Rf = 0.023 for 2495 observations.
(5), Orthorhombic, space group P na21, a = 15.846(3) Å, b = 11.725(1) Å,
c = 6.978(1) Å, Final Rf = 0.037 for 1519 observations.
(6), Monoclinic, space group C 2/c, a = 9.911(1)) Å, b = 11.987(2) Å, c = 7.4062(9) Å, β = 105.173(2), Final Rf = 0.059 for 911 observations.
(7), Triclinic, space group P, a = 6.992(3) Å, b = 11.440(7) Å, c = 14.084(2) Å, α = 105.31(3), β = 92.82(2), γ = 94.56(4), Final Rf = 0.049 for 3031 observations.
(8), Orthorhombic, space group P can, a = 6.9948(9) Å, b = 13.735(2) Å, c = 16.723(8) Å, Final Rf = 0.031 for 1225 observations.
(9), Orthorhombic, space group C c, a = 11.536(3) Å, b = 21.2140(2) Å，c =8.523(1) Å，β= 130.53(2), Final Rf = 0.033 for 1370 observations.

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