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研究生：	吳宗賢 Wu, Chung-Xian
論文名稱：	結合電化學方法與電子顯微鏡探討鍍鋅鋼板表面塗層之抗蝕研究 A Study On Combining Electrochemical Methods And Electron Microscope To Explore Corrosion Resistance Of Coating On Zn-Coated Steel Sheet
指導教授：	呂家榮 Lu, Chia-Jung
口試委員：	劉茂煌 Liu, Mao-Huang 李君婷 Li, Chun-Ting 呂家榮 Lu, Chia-Jung
口試日期：	2023/06/16
學位類別：	碩士 Master
系所名稱：	化學系 Department of Chemistry
論文出版年：	2023
畢業學年度：	111
語文別：	中文
論文頁數：	97
中文關鍵詞：	抗蝕性、氧化矽奈米複合塗層、鋯鈍化處理、鍍鋅鋼板
英文關鍵詞：	corrosion resistance, silicon dioxide nano-composite coating, zirconium passivation treatment, galvanized steel sheet
研究方法:	實驗設計法
DOI URL：	http://doi.org/10.6345/NTNU202300941
論文種類：	學術論文
相關次數：	點閱：44 下載：0
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第一章	緒論	1
1研究動機	1
2 金屬的腐蝕和抗腐蝕	2
2.1 金屬材料的腐蝕	2
2.2 腐蝕的分類	3
2.3 抗腐蝕方法	7
3 鍍鋅鋼板表面處理	10
3.1 鈍化處理	12
3.2 塗油	13
3.3 抗指紋薄膜	13
4 溶膠–凝膠法	14
4.1 水解反應(Hydrosis)	14
4.2 縮合反應(Condensation)	15
5 塗層塗佈方式	17
5.1 沉浸塗佈法(Dip coating)	17
5.2 旋轉塗佈法(Spin coating)	17
5.3 噴霧塗佈法(Spray coating)	18
5.4 電泳塗佈法(Electrophoretic deposition)	18
5.5 滾輪塗佈法	19
6 鋼板表面塗層抗蝕性分析方法	20
6.1 塔弗曲線(Tafel)	20
6.2 電化學阻抗譜(Electrochemical impedance spectroscopy)	22
6.3 掃描式電子顯微鏡(Scanning electron microscope)	28
6.4 能量色散X射線譜	29
6.5 動態光散色粒徑分析儀(Dynamic Light Scattering)	31
6.6 鹽霧試驗(Salt-spray test)	32
第二章	實驗部分	33
1 實驗藥品與儀器	33
1.1 實驗藥品	33
1.2 器材與設備	34
1.3 分析儀器	35
2 配方之製備	40
2.1 製備E配方	40
2.2 製備DD配方	41
2.3 鋯鈍化液之製備	41
3 實驗方法	42
3.1 鋯鈍化鋼板處理	43
3.2 塗佈E配方與DD配方試片	44
3.3 掃描式電子顯微鏡試片前處理	45
3.4 Tafel曲線數據處理	46
第三章	結果與討論	47
1 環保型鋯鈍化塗層之研究	47
1.1 不同鈍化液濃度	47
1.2 鈍化液pH值對抗蝕性之影響	53
2 含矽封孔劑之研究	63
2.1 E配方討論	63
2.2 DD配方討論	66
2.3 不同含矽封孔劑對抗腐蝕性之差異	67
3	磷酸皮膜鈍化塗層之探討	73
3.1 表面結構與成分分析	73
3.2 電化學分析儀測量結果	76
4 鋅鎳層與電鍍鎳抗腐蝕之研究	79
4.1 表面結構與成分分析	79
4.2電化學分析儀量測結果	83
第四章	結論及未來展望	87
參考文獻	89
                                

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