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研究生: 林俊佑
論文名稱: 鑭摻雜極薄氧化鉿介電層影響之研究
The Influence of Lanthanum Doping Position in Ultra-Thin High-k HfO2 Films
指導教授: 周明
學位類別: 碩士
Master
系所名稱: 機電工程學系
Department of Mechatronic Engineering
論文出版年: 2010
畢業學年度: 98
語文別: 中文
論文頁數: 93
中文關鍵詞: 氧化鉿溅鍍機氧化鑭鉿高介電係數介電層傳導機制
論文種類: 學術論文
相關次數: 點閱:107下載:0
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  • 將鑭摻雜於極薄氧化鉿層,以共鍍的方式完成,形成HfO2/HfLaO/p-Si 與HfLaO/HfO2/p-Si結構,再經由快速熱退火製程,在製程溫度850 °C環境下進行退火。
    材料分析特性如下,運用X-ray反射技術(XRR)藉由膜層光學干涉現象分析單層厚度。使用X-ray繞射光譜儀(XRD)來分析HfO2與silicate是否產生結晶像,以及分析在不同比例厚度有產生結晶。從HfLaO/HfO2/p-Si結構的介面層有較多的silicate與HfO2/HfLaO/p-Si結構作比較。從nano-AES結論中可得知,當鑭摻雜於上層的HfLaO/HfO2/p-Si結構,有較多的鉿會擴散至Si基板。另一方面HfO2/HfLaO/p-Si結構,有較少的擴散的現象產生,此結構有抑止鉿擴散現象,與HfLaO/HfO2/p-Si結構作比較,此現象可以從XPS與TEM分析儀器驗證。在電性分析方面,分析漏電流、電容值量測,及漏電流機制分析。

    第一章 緒論 1 1-1 高介電常數 (high-k)發展 1 1-2 本論文研究方向 1 第二章 文獻探討 2 2-1 金氧半場效電晶體 (metal-oxide-semiconductor field-effect transistor, MOSFET)結構與特性 2 2-2 MOS電容之結構與特性 3 2-2-1 理想之MOS元件 3 2-3 閘極漏電流與氧化層厚薄之關係 7 2-4 介電常數理論 8 2-4-1高介電常數薄膜 9 2-4-1-1 ZrO2薄膜介紹 9 2-4-1-2 Al2O3薄膜介紹 9 2-4-1-3 Y2O3薄膜介紹 10 2-4-1-4 CeO2薄膜介紹 10 2-4-2 氧化鉿與氧化鑭薄膜介紹 11 2-4-3 退火溫度對HfO2薄膜物理及電性影響 11 2-4-3-1 快速熱退火 (Rapid Thermal Anneal, RTA) 11 2-4-3-2 退火溫度對HfO2薄膜物理影響 12 2-4-3-3 退火溫度對HfO2薄膜電性影響 14 2-5 漏電流機制之簡介 15 2-5-1 蕭基發射 (Schottky emission) 15 2-5-2 普爾-法蘭克發射(Poole-Frenkel Emission) 16 2-6 四種氧化層電荷 17 2-6-1 移動離子電荷 (mobile ionic charge, Qm) 18 2-6-2 氧化層陷阱電荷 (oxide trapped charge, Qot) 18 2-6-3 固定氧化層電荷 (fixed oxide charge, Qf) 19 2-6-4 介面陷阱電荷 (interface trapped charge, Qit) 19 2-7 介面層 (interfacial layer) 19 第三章 實驗設計 21 3-1 製程理論與原理 21 3-1-1 直流濺射鍍膜原理及功能 21 3-1-2 直流濺射鍍膜構造及機制 22 3-1-3 射頻濺射鍍膜原理及功能 23 3-1-4 射頻濺射鍍膜構造及機制 24 3-1-5 真空系統 25 3-1-6 退火與快速熱退火系統 27 3-2 分析儀器原理 29 3-2-1 X光繞射原理與X-ray繞射光譜儀 29 3-2-2 X光電子能譜儀 30 3-2-3 橢圓儀 32 3-2-4 穿透式電子顯微鏡 33 3-2-5 TEM試片製備 34 3-3 實驗方法與步驟 35 3-3-1氧化鉿 (HfO2)與氧化鑭鉿 (HfLaO)薄膜電容器製程 35 3-3-2 分析使用儀器 36 第四章 結果與討論 37 4-1 物理特性分析及討論 37 4-1-1 X-ray繞射光譜儀分析及討論 (X-ray diffraction, XRD) 37 4-1-2 X-ray反射技術 (X-ray reflectivity, XRR)分析及討論 38 4-1-3 AFM分析及討論 38 4-1-4 nano-Auger electron microscopy分析及討論 38 4-1-5 XPS分析及討論 39 4-1-6 HRTEM分析及討論 40 4-2電性分析及討論 41 4-2-1 漏電流特性(leakage urrent density–voltage, J-V)分析及討論 41 4-2-2 電容特性(capacitance-voltage, C-V)分析及討論 41 4-2-3 蕭基發射(Schottky emission)漏電流機制分析及討論 43 第五章 結論與未來展望 45 5-1電容器之物性及電性 45 5-2未來展望 46 圖目錄 47 參考文獻 88

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