Author: |
陳宜樺 Chen, Yi-Hua |
---|---|
Thesis Title: |
透過氫氣作用控制磁性層間交互耦合效應 Modulation of magnetic interlayer-coupling in Fe/Pd/Fe/MgO(001) through cyclic hydrogenation |
Advisor: |
林文欽
Lin, Wen-Chin |
Degree: |
碩士 Master |
Department: |
物理學系 Department of Physics |
Thesis Publication Year: | 2017 |
Academic Year: | 105 |
Language: | 中文 |
Number of pages: | 36 |
Keywords (in Chinese): | 磁性 、合金 、薄膜 、氫氣效應 |
Keywords (in English): | Magnetism, alloy, thin film, hydrogenation |
DOI URL: | https://doi.org/10.6345/NTNU202202052 |
Thesis Type: | Academic thesis/ dissertation |
Reference times: | Clicks: 77 Downloads: 20 |
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長期以來,鈀一直作為氫氣解離和吸附的高效催化劑。在鈀合金或內米結構中,鈀的氫化容易引起相鄰材料有顯著的鄰近效應。在本實驗中,我們在超高真空中使用電子束蒸發磊晶法,在MgO (001)的基底上製備了磁性界面耦合系統。通過退火處理,可以得到平坦的MgO (001)表面,用來沉積Fe/Pd/Fe三層膜。
在一定鈀的厚度下,通過磁光柯爾效應在平行(In-Plane)方向,可以在Fe/Pd/Fe/MgO(001)系統中觀察到清楚的雙磁滯曲線。這現象說明頂層和底層鐵層之間的反鐵磁耦合。隨著室溫下的氫氣脫吸附,反鐵磁層間耦合有明顯的變化,如雙磁滯曲線的矯頑場變化所示。這結果表示,鐵/鈀多層膜系統未來可以應用為敏感性高的氫氣感測GMR傳感器
Pd has long been used as a high efficient catalyst for hydrogen dissociation and absorption. In the Pd-alloys or nanostructures, the hydrogenation of Pd easily brings in pronounced proximity effect upon the adjacent functional materials.
In this experiment, we prepared the magnetic exchange interlayer coupled system, Fe/Pd/Fe trilayers, on MgO(001) substrates using e-beam evaporation in an ultrahigh vacuum. Through a suitable annealing process, a flat MgO(001) surface can be achieved for the deposition of the Fe/Pd/Fe trilayer.
With a certain Pd thickness, clear double hysteresis loops were observed in the Fe/Pd/Fe/MgO(001) system by using magneto optical Kerr effect in the in-plane direction. This indicates the antiferromagnetic coupling between the top and bottom Fe layers. With cyclic hydrogen absorption and desorption at room temperature, the antiferromagnetic interlayer-coupling was considerably and reversibly changed, as indicated by the change of the shift field of the double loops. This observation suggests that the Fe/Pd-multilayer system can serve as a GMR sensor for sensitive hydrogen sensing in the future applications.
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