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研究生: 陳宜樺
Chen, Yi-Hua
論文名稱: 透過氫氣作用控制磁性層間交互耦合效應
Modulation of magnetic interlayer-coupling in Fe/Pd/Fe/MgO(001) through cyclic hydrogenation
指導教授: 林文欽
Lin, Wen-Chin
學位類別: 碩士
Master
系所名稱: 物理學系
Department of Physics
論文出版年: 2017
畢業學年度: 105
語文別: 中文
論文頁數: 36
中文關鍵詞: 磁性合金薄膜氫氣效應
英文關鍵詞: Magnetism, alloy, thin film, hydrogenation
DOI URL: https://doi.org/10.6345/NTNU202202052
論文種類: 學術論文
相關次數: 點閱:82下載:20
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  • 長期以來,鈀一直作為氫氣解離和吸附的高效催化劑。在鈀合金或內米結構中,鈀的氫化容易引起相鄰材料有顯著的鄰近效應。在本實驗中,我們在超高真空中使用電子束蒸發磊晶法,在MgO (001)的基底上製備了磁性界面耦合系統。通過退火處理,可以得到平坦的MgO (001)表面,用來沉積Fe/Pd/Fe三層膜。
      在一定鈀的厚度下,通過磁光柯爾效應在平行(In-Plane)方向,可以在Fe/Pd/Fe/MgO(001)系統中觀察到清楚的雙磁滯曲線。這現象說明頂層和底層鐵層之間的反鐵磁耦合。隨著室溫下的氫氣脫吸附,反鐵磁層間耦合有明顯的變化,如雙磁滯曲線的矯頑場變化所示。這結果表示,鐵/鈀多層膜系統未來可以應用為敏感性高的氫氣感測GMR傳感器

    Pd has long been used as a high efficient catalyst for hydrogen dissociation and absorption. In the Pd-alloys or nanostructures, the hydrogenation of Pd easily brings in pronounced proximity effect upon the adjacent functional materials.
      In this experiment, we prepared the magnetic exchange interlayer coupled system, Fe/Pd/Fe trilayers, on MgO(001) substrates using e-beam evaporation in an ultrahigh vacuum. Through a suitable annealing process, a flat MgO(001) surface can be achieved for the deposition of the Fe/Pd/Fe trilayer.
      With a certain Pd thickness, clear double hysteresis loops were observed in the Fe/Pd/Fe/MgO(001) system by using magneto optical Kerr effect in the in-plane direction. This indicates the antiferromagnetic coupling between the top and bottom Fe layers. With cyclic hydrogen absorption and desorption at room temperature, the antiferromagnetic interlayer-coupling was considerably and reversibly changed, as indicated by the change of the shift field of the double loops. This observation suggests that the Fe/Pd-multilayer system can serve as a GMR sensor for sensitive hydrogen sensing in the future applications.

    摘要 I Abstract II 目錄 III 第一章 緒論 1 1-1氫氣對磁性的影響 1 1-2層間耦合(Interlayer coupling) 4 第二章 基本原理 7 2-1晶格結構 7 2-2磁性材料 8 2-3氫氣系統 9 第三章 實驗儀器 11 3-1高真空系統(UHV) 11 3-2鍍膜系統(MBE) 13 3-3磁光柯爾效應(Magneto-Optical Kerr Effect, MOKE) 14 第四章 實驗結果與討論 17 4-1 MgO基板處理 17 4-2 製備Pd/Fe/Pd/Fe/MgO 22 4-3 Fe/Pd/Fe/MgO (001) 薄膜在不同氫氣濃度下的磁性變化 23 4-4 Fe/Pd/Fe/MgO (001)薄膜的剖面結構與成果分析 26 第五章 結論 28 參考文獻 29 附錄 31 致謝 35

    【1】. W.C. Lin et al., J. Appl. Phys. 112, 063914 (2012).
    【2】. W.C. Lin, B. Y. Wang, H. Y. Huang, C. J. Tsai, V. R. Mudinepalli, J. Alloys Comp. 661, 20-26 (2016).
    【3】. W.C. Lin, C.J. Tsai, H.Y. Huang, B.Y. Wang, V.R. Mudinepalli, and H.C. Chiu, Appl. Phys. Lett. 106, 12404 (2015).
    【4】. W.C. Lin, Cheng-Jui, Tsai, Xin-Ming Liu, and Adekunle O. Adeyeye, J. Appl. Phys. 116, 073904 (2014).
    【5】. W.C. Lin, C.-J. Tsai, B.-Y. Wang, C.-H. Kao, and W.-F. Pong, Appl. Phys. Lett. 102, 252404 (2013).
    【6】. W.C.-C. Chiu, W. C. Lin, Y.-C. Yeh, and K. J. Song Appl. Phys. Lett. 102, 242403 (2013)
    【7】. W.C. Lin, C.-S. Chi, T.-Y. Ho, C.-J. Tsai Thin Solid Films, 531, 487 (2013).
    【8】. P.C. Chang, Y.C. Chen, C.C. Hsu, V.R. Mudinepalli, H.C. Chiu, W.C. Lin, Journal of Alloys and Compounds 710, 37-46 (2017)
    【9】. A. Mimura, N. Konishi, K. Ono, J. Owada, Y. Hosokawa, Y. Ono, T. Suzuki, K. Miyata, and Y. Hawakami, IEEE Trans. Electron Devices 36, 351 (1989).
    【10】 P. Grünberg, R. Schreiber, M.B. Brodsky, H. Sower, Phys. Rev. Lett. 57, 2442 (1986)
    【11】 C. Chappert, J.P. Renard: Europhys. Lett. 15, 553 (1991)
    【12】 P. Bruno, C. Chappert, Phys. Rev. Lett. 67, 1602 (1991).
    【13】 O. O. Brovko, P. A. Ignatiev, V. S. Stepanyuk, and P. Bruno, Phys. Rev. Lett. 101, 036809 (2008)
    【14】 Z. Celinski and B. Heinrich, J. Magn. Magn. Mater. 99, L25 (1991);
    【15】 J. Skoryna, et al. J. Alloys Compd. 645, S280–S283 (2015)
    【16】 T. Kanaji, K. Asano, and S. Nagata, Vacuum 23, 55 (1973)
    【17】 V. Serin, S. Andrieu, R. Serra, F. Bonell, C. Tiusan, L. Calmels, M. Varela, S. J. Pennycook, E. Snoeck, M. Walls, and C. Colliex, Phys. Rev. B 79, 144413 (2009).
    【18】 D. Odkhuu, W.S. Yun, S.H.Rhim, S.C. Hong, M. M. M. 414, 126–131(2016)
    【19】 J. S. Lee, S. G. Kim, S. Cho and J. Jang, Nanoscale, 7, 20665–20673, (2015)
    【20】 M. Ramanathan, G. Skudlarek, H. H. Wang, S. B. Darling, Nanotechnology, 21, 125501 (2010)
    【21】 R. Delmelle and J. Proost, Phys. Chem. Chem. Phys. 13, 11412 (2011)
    【22】 M.G. Kim, U. Dahmen, J. Am. Ceram. Soc. 70. 146. (1987)
    【23】 J. Green, J. Mater. Sci. 18 637. (1983)
    【24】 D.K. Aswal, K.P. Muthe, Shilpa Tawde, Sipra Chodhury, N. Bagkar, Ajay Singh, S.K. Gupta, J.V. Yakhmi, J. C. G. 236, 661–666 (2002)

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