簡易檢索 / 詳目顯示

研究生: 歐哲豪
Ou, Che-Hao
論文名稱: Development of a Precision Tensiometer with Differential Capillary Instability Method
Development of a Precision Tensiometer with Differential Capillary Instability Method
指導教授: 黃仲仁
Huang, Jung-Ren
學位類別: 碩士
Master
系所名稱: 物理學系
Department of Physics
論文出版年: 2017
畢業學年度: 105
語文別: 英文
論文頁數: 53
中文關鍵詞: TensiometerInterfacial TensionCapillary InstabilitySodium Dodecyl Sulfate
英文關鍵詞: Tensiometer, Interfacial Tension, Capillary Instability, Sodium Dodecyl Sulfate
DOI URL: https://doi.org/10.6345/NTNU202203056
論文種類: 學術論文
相關次數: 點閱:82下載:2
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報

無中文摘要

We created a new method, the Differential Capillary Instability Method, to measure the interfacial tension of fluid interfaces by creating two separated interfaces using capillary tubes. The differential nature from separated interfaces of this original design eliminates the need to explicitly define the pressure value at any of the interfaces, which sets a lower demand for the experimental condition. The capillary nature eliminates the need to numerically determine the geometrical profile of the interface. The instability nature of the measuring process allows us to pinpoint the value of interfacial tension with high precision. We’ve measured the surface tension of a few common samples with our Differential Capillary Instability Tensiometer and we compared the results with some published values. The measurement result shows a general consistency with the reported values acquired by other methods in several other researches. Various kinds of conditions have been carried out to test the method with different samples, surface property of capillary tubes, and formation speed of the interface. Some operation principles was concluded to optimize the measurement when applying the Differential Capillary Instability Method.

Abstract i Contents ii List of Figures and Tables iii Chapter 1. Introduction 1 1.1 Existing Methods to Measure Interfacial Tension 1 1.2 The Differential Capillary Instability Method 5 Chapter 2. The Principle of Differential Capillary Instability Method 7 2.1 The Young-Laplace Equation 7 2.2 Theory of Differential Capillary Instability Method 10 2.3 The Effects of Surface Property of Capillary Tubes 14 Chapter 3. Apparatus and Operation 15 3.1 Apparatus of the Differential Capillary Instability Tensiometer 15 3.2 Operating Procedure of the Differential Capillary Instability Tensiometer 17 3.2.1 Preparation of the Apparatus 18 3.2.2 Measurement Procedure 19 Chapter 4. Experimental Results 23 4.1 Results with Hydrophilic Capillary Tubes 23 4.2 Results with Hydrophobic Capillary Tubes 24 4.3 Results with Different Pumping Rates 25 4.4 The Sources of Error 26 Chapter 5. Discussions and Conclusion 33 5.1 Discussions on Results with Hydrophilic Capillary tubes 33 5.2 Discussions on Results with Hydrophobic Capillary tubes 35 5.3 Discussions on Results with Different Pumping Rates 36 5.4 Operation Principles of Differential Capillary Instability Method 36 5.5 Conclusion 37 5.6 Future Direction 38 References 39 Appendix 40 Α1. Photos of the Differential Capillary Instability Tensiometer 40 Α2. Code for the Image Processing and Analysis 44

[1] Adamson, A. W., & Gast, A. P. (1967). Physical chemistry of surfaces.
[2] Siqveland, L. M., & Skjæveland, S. M. (2014). Derivations of the Young-Laplace equation.
[3] Pallas, N. R., & Pethica, B. A. (1989). The surface tension of water. Colloids and surfaces, 36(3), 369-372.
[4] Vazquez, G., Alvarez, E., & Navaza, J. M. (1995). Surface tension of alcohol water+ water from 20 to 50. degree. C. Journal of chemical and engineering data, 40(3), 611-614.
[5] Hines, J. D. (1996). The preparation of surface Chemically pure sodiumn-dodecyl sulfate by foam fractionation. Journal of colloid and interface science, 180(2), 488-492.
[6] Mysels, K. J. (1986). Surface tension of solutions of pure sodium dodecyl sulfate. Langmuir, 2(4), 423-428.
[7] Hernáinz-Bermúdez de Castro, F., Galvez-Borrego, A., & Calero-de Hoces, M. (1998). Surface Tension of Aqueous Solutions of Sodium Dodecyl Sulfate from 20 C to 50 C and pH between 4 and 12. Journal of Chemical & Engineering Data, 43(5), 717-718.
[8] Gildnyi, T., Stergiopoulos, C., & Wolfram, E. (1976). Equilibrium surface tension of aqueous surfactant solutions. Colloid & Polymer Science, 254(11), 1018-1023.
[9] Johnson, C. M., & Tyrode, E. (2005). Study of the adsorption of sodium dodecyl sulfate (SDS) at the air/water interface: targeting the sulfate headgroup using vibrational sum frequency spectroscopy. Physical Chemistry Chemical Physics, 7(13), 2635-2640.
[10] Hines, J. D., Thomas, R. K., Garrett, P. R., Rennie, G. K., & Penfold, J. (1997). Investigation of mixing in binary surfactant solutions by surface tension and neutron reflection: anionic/nonionic and zwitterionic/nonionic mixtures. The Journal of Physical Chemistry B, 101(45), 9215-9223.

下載圖示
QR CODE