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研究生: 陳慶宏
Chen Ching Hong
論文名稱: 強塑劑於高性能混凝土中之效能評估
The effective evaluation of superplasticizer in high performance concrete
指導教授: 許貫中
Hsu, Kung-Chung
學位類別: 碩士
Master
系所名稱: 化學系
Department of Chemistry
論文出版年: 2000
畢業學年度: 88
語文別: 中文
論文頁數: 125
中文關鍵詞: 強塑劑最佳劑量
英文關鍵詞: superplasticizer, optimal dosage
論文種類: 學術論文
相關次數: 點閱:119下載:0
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  • 混凝土由於來源充足、價格低廉、污染性低及優越抗壓強度,因此成為結構工程上使用最多的材料,而強塑劑則是拌製混凝土高流動性的主要成份之一。
    強塑劑的種類、分子量、添加劑量、拌和方式及添加時機均會影響其在水泥表面的吸附行為,進而影響新拌混凝土的工作性及硬固混凝土的機械性與耐久性,故強塑劑的了解與應用在混凝土科技上扮演相當重要的角色。
    本論文乃針對幾種商業強塑劑(SNF、SMF、MLS、PCA、HP-70、SNF+PCA、HP-11R),分析其基本性質、減水率及其添加對水泥(砂)漿流變性質之影響,進而決定不同配比下所需強塑劑的最佳劑量及影響最佳劑量各項因素之探討,並建立迴歸方程式以便迅速找出不同配比的混凝土之最佳劑量。
    由實驗結果得知,這幾種強塑劑適量的添加於水泥(砂)漿中均有不錯的減水效果,而SNF、PCA、SNF+PCA之流動性維持較MLS、SMF佳,且藉由黏度計所測得的視黏度及屈服應力與馬緒流動錐所測得的流動時間及迷你坍度錐所測得的平均擴散直徑均可決定不同配比下強塑劑的最佳劑量。在相同配比下,以SMF及MLS所需最佳劑量較高,其他幾種則較低;水灰比愈高,所需最佳劑量愈低;添加飛灰、增加砂含量會使得最佳劑量提高;添加爐石則會降低最佳劑量;水泥、砂種類對最佳劑量亦有影響。最後,建立迴歸方程式以預測不同配比的混凝土所需強塑劑之最佳劑量。

    Concrete is the material mostly used in construction engineering because of its availability in source, low cost, low pollution and excellent compressive strength. Superplasticizer (Sp) is one of the main components to make concrete with high fluidity.
    It is reported that the type, molecular weight, dosage, mixing method and time of addition of Sps affect their adsorption behavior on cement particles, the workability of fresh concrete, and the mechanical properties and durability of hardened concrete. Therefore, the understanding and application of Sps are important on the concrete technology.
    This thesis has evaluated the basic properties and water-reduction of 7 commercial Sps, namly SNF, SMF, MLS, PCA, SNF+PCA, HP-70 and HP-11R, studied the effect of Sps on the rheology properties of cement pastes or mortars, determined the optimal Sp dosage and finally correlated the optimal dosage for concrete with different mix proportions by several correlation equations.
    The tested results indicate that all Sps exhibit good water-reduction effects. Both SMF and MLS show worse fluidity retention than the others. The optimal dosage of Sps was determined from the measured apparent viscosity, yield stress, Marsh cone flow time and mini-slump for various mix proportions. The optimal dosage of both SMF and MLS is higher than the others; the optimal dosage of all Sps increases with decreasing w/c ratio and increasing sand content;It also increases as fly ash replacement is increased or slag replacement is decreased. Different type of cement and sand show different effects on the optimal dosage. Finally, correlation equation were established to correlate the experimental values.

    第一章 緒論 5 第二章 文獻回顧 7 2.1 水泥 7 2.1.1波特蘭水泥的製造及成份 7 2.1.2水泥的水化 7 2.2 混凝土 13 2.3 高性能混凝土 15 2.3.1 高性能混凝土的由來 15 2.3.2 高性能混凝土之定義 15 2.3.3 高性能混凝土材料的性質 16 2.4 台灣混凝土 18 2.5 強塑劑 19 2.5.1 摻料及強塑劑的定義 19 2.5.2 強塑劑的添加目的 22 2.5.3 塑化劑與強塑劑之差異 23 2.5.4 強塑劑之主要成份 24 2.5.5 強塑劑的作用機制 28 2.6 強塑劑效能的評估 32 2.6.1 強塑劑使用考量因素 32 2.6.2 強塑劑效能之評估方式 32 2.6.3 強塑劑最佳劑量之決定原則 34 第三章 實驗部分 36 3.1 實驗材料 36 3.2 實驗儀器級數據處理 41 3.3 實驗流程與方法 43 第四章 強塑劑基本性質分析 44 4.1 強塑劑基本性質分析 44 4.1.1 固含量測定 44 4.1.2 密度測定 44 4.1.3 黏度測試 44 4.1.4 穩定性測定 44 4.1.5 凝膠滲透層析 44 4.1.6 紅外光光譜分析 45 4.1.7 紫外光光譜分析 45 4.1.8 表面張力分析 46 4.2 水泥漿泌水之測試 46 4.3 水泥漿凝結時間之測試 46 4.4 水泥漿流動性之測試 47 4.4.1 馬緒錐流動時間之測試 47 4.4.2 迷你坍度錐平均擴散直徑之測試 4.4.3 Brookfield黏度計之屈服應力測試 47 第五章 結果與討論 48 5.1 強塑劑基本性質分析 48 5.1.1 強塑劑的固含量 49 5.1.2 強塑劑的比重 49 5.1.3 強塑劑的黏度 49 5.1.4 強塑劑的分子量 49 5.1.5 強塑劑穩定性測試 53 5.1.6 表面張力之測試 54 5.1.7 紅外光光譜分析 56 5.1.8 紫外光光譜分析 60 5.2 各種強塑劑於水泥漿中減水率之測試 64 5.3 強塑劑最佳劑量之決定 68 5.3.1 Marsh cone流動時間決定強塑劑最佳劑量 68 5.3.2 Brookfield黏度計之視黏度求最佳劑量 71 5.3.3 由Brookfield黏度計之屈服應力求最佳劑量 75 5.3.4 各種評估方式決定強塑劑最佳劑量之結果比較 79 5.4 添加強塑劑對水泥漿流動性維持之測試 82 5.5 水泥與強塑劑之相容性測試 85 5.6 泌水測試 87 5.7 影響強塑劑最佳劑量因素之探討 91 5.7.1 水灰比對強塑劑最佳劑量之影響 91 5.7.2 飛灰與爐石的添加對強塑劑最佳劑量之影響 92 5.7.3 不同砂種類及用量對強塑劑最佳劑量之影響 95 5.7.4 不同水泥種類對強塑劑最佳劑量之影響 100 5.8 水泥砂漿不同配比下最佳劑量及最大擴散直徑之預測 102 5.9 由水泥砂漿預測混凝土使用強塑劑之最佳劑量 111 第六章 結論與建議 117 6.1 結論 117 6.2 建議 118 第七章 參考資料 119

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