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研究生: 夏德耀
Hsia, Te-Yao
論文名稱: 添加奈米石墨烯齒輪油於四行程機車引擎性能與廢氣排放影響之研究
The Effects of Adding Nano Graphene Gear Oil on Performance and Exhaust Emissions of Four-Stroke Motorcycle Engine
指導教授: 呂有豐
Lue, Yeou-Feng
口試委員: 莫懷恩
Mo, Huai-En
鄧敦平
Teng, Tun-Ping
呂有豐
Lue, Yeou-Feng
口試日期: 2021/07/05
學位類別: 碩士
Master
系所名稱: 工業教育學系
Department of Industrial Education
論文出版年: 2022
畢業學年度: 110
語文別: 中文
論文頁數: 122
中文關鍵詞: 奈米石墨烯齒輪油(NGGO)黏度試驗磨潤試驗粒狀汙染物(PM)排放廢氣汙染排放
英文關鍵詞: Nano graphene gear oil, Viscosity, Tribology, Particulate matter emissions, Exhaust emissions
研究方法: 實驗設計法
DOI URL: http://doi.org/10.6345/NTNU202200617
論文種類: 學術論文
相關次數: 點閱:102下載:11
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  • 本研究將改質石墨烯(Gr)作為利用二階合成法添加於原廠齒輪油中製備成NGGO,冀望NGGO獲得Gr所具備之特性,藉以優化原廠齒輪油性能。為探討添加Gr是否有效優化原廠齒輪油,將NGGO進行基礎試驗與實車試驗。基礎試驗包括沉降、黏度、比熱、導熱及磨潤試驗;實車試驗包含ECE-40、定速(50 km/h)、平路與爬坡試驗,於車輛運行過程中量測其能源效率、各點元件溫度、汙染排放與車速扭矩。本研究NGGO製備比例為0.005、0.01、0.02、0.03、0.05、0.1、0.2、0.3、0.4及0.5 wt.%,經過基礎試驗評比0.03 wt.%為最佳濃度,與原油相比在黏度試驗中改善12.66 %、導熱係數提升5 %、磨潤試驗耗損量改善10.17 %。將0.03 wt.%分別添加油酸(OA)或真空試驗後發現皆無明顯改善NGGO性質。於實車試驗中,ECE-40及定速行車型態測試,平均能源效率改善6.22 %、齒輪油溫度平均下降15.90 %,因動力輸出改善使引擎燃燒更加完善,導致燃燒室周圍元件(火星塞及排氣管內外側)溫度上升。添加NGGO之車輛有效改善HC及CO排放,單趟ECE-40平均分別減少40.48 %及8.64 %,PM排放也因燃燒完全而下降,總數平均下降40.61 %。平路試驗NGGO相較於原廠齒輪油減少40 s達到穩定車速,整體行駛扭矩也較平穩。

    The research is using graphene(Gr) as an additive material to mix with the original gear oil to be nano graphene gear oil(NGGO), and study the performance of basic properties and vehicle test between NGGO and original gear oil via adding dispersant OA to NGGO or vacuum test. The basic property test includes sedimentation, viscosity, specific heat, heat conduction and tribology test, vehicle test includes ECE-40, constant speed (50 km/h), flat road and climbing test, and measure the energy efficiency, temperature of specified parts, exhaust emissions, torque and speed during the vehicle running. The concentration of NGGO include 0.005, 0.01, 0.02, 0.03, 0.05, 0.1, 0.2, 0.3, 0.4 and 0.5 wt. %. After basic test, 0.03 wt. % was the best choice concentration. Compared with base oil, test results show that the dynamic viscosity improved by 12.66 %, the thermal conductivity increased by 5 %, and the wear test loss was improved by 10.17 %. After adding 0.03 wt.% to OA or vacuum test, it was found that there was no significant improvement in the properties of NGGO. In the vehicle test, ECE-40 and constant speed state test, the average energy efficiency has improved up to 6.22 %, and the gear oil temperature has dropped down by an average of 15.90 %. Due to the improved power output, the engine combustion is more perfect, which causes the temperature of the components around the combustion chamber (the spark plug and the inside and outside of the exhaust pipe) to rise. The vehicles added with NGGO can effectively improve HC and CO emissions. A single-trip of ECE-40 reduces 40.48 % and 8.64 % on average; PM emissions are also reduced due to complete combustion, with a total reduction of 28.86 % on average.NGGO compared with the original gear oil in flat road test, NGGO reduced 40 sec to achieve stable vehicle speed, and all of vehicle torque was stable.

    謝誌 i 摘要 ii Abstract iii 目錄 v 圖次 viii 表次 xii 第一章 緒論 1 1.1 前言 1 1.2 研究動機 2 1.3 研究目的 4 1.4 研究方法 4 1.5 論文架構 6 第二章 相關理論與分析 7 2.1 潤滑與齒輪 7 2.1.1 機械效率之影響 7 2.1.2 齒輪壽命之影響 8 2.1.3 齒輪損耗之影響 8 2.1.4 齒輪動力學之影響 9 2.1.5 潤滑與齒輪之衝突 9 2.2 奈米流體 10 2.2.1 奈米流體製備 10 2.2.2 流變性能 11 2.2.3 熱物理性質相關 12 2.2.4 磨潤性能 13 2.3 石墨烯、齒輪油、石墨烯奈米流體相關研究 13 2.3.1 石墨烯 (graphene, Gr) 13 2.3.2 齒輪油 14 2.3.3 石墨烯奈米流體 15 2.4 車輛汙染排放 15 2.4.1 PM排放 15 2.4.2 廢氣排放 16 2.5 機車性能檢測方式 17 2.5.1 燃油能源效率 17 2.5.2 廢氣檢測 21 第三章 實驗方法與裝置 23 3.1 Gr檢測 24 3.1.1 Gr成分檢測 24 3.1.2 Gr外觀檢測 25 3.2 NGGO製備 28 3.2.1 製備方法與比例 28 3.3 NGGO性質量測 37 3.3.1 沉降試驗 37 3.3.2 黏度量測試驗 37 3.3.3 比熱量測試驗 42 3.3.4 導熱量測試驗 47 3.3.5 磨潤試驗 51 3.4 NGGO實車試驗 57 第四章 實驗結果與討論 69 4.1 Gr外觀性質檢測結果 69 4.2 NGGO基礎性質量測 70 4.2.1 沉降試驗 70 4.2.2 黏度試驗 71 4.2.3 比熱試驗 75 4.2.4 導熱試驗 78 4.2.5 磨潤試驗 81 4.2.6 綜合評比 87 4.3 實車試驗 89 4.3.1 試驗環境 89 4.3.2 行車型態車速 90 4.3.3 能源效率 94 4.3.4 各點元件溫度 96 4.3.5 汙染排放 99 4.3.6 車輛扭矩 103 第五章 結論與建議 105 5.1 結論 105 5.2 後續研究與建議 107 參考文獻 109 符號釋義 121

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