簡易檢索 / 詳目顯示

回結果列表
研究生： 吳杏旋
論文名稱： 添加陰離子型分散劑之鈦酸鋇漿體在不同pH值下的分散行為
指導教授： 許貫中
Hsu, Kung-Chung
學位類別： 碩士
Master
系所名稱： 化學系
Department of Chemistry
論文出版年： 2004
畢業學年度： 92
語文別： 中文
論文頁數： 165
中文關鍵詞： 鈦酸鋇 、分散劑 、pH 、分散性質
英文關鍵詞： BaTiO3, dispersant, pH, properties
論文種類： 學術論文
相關次數： 點閱：422  下載：18 
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報

    • 本研究主要是延續實驗室所研發出來的陰離子型分散劑PCOB poly〔(4-carboxyamino-4-oxo-2-butenate)-acrylamide〕，與商用型之甲基丙烯酸鈉鹽PMAA-Na〔sodium salt of poly(methacrylic acid)〕應用於鈦酸鋇粉末探討在不同pH值之分散效果，其中PCOB係以馬來酸酐和氨基甲酸銨鹽反應生成4-羧基氨基-4酮基-2-丁烯酸銨鹽單體，再與丙烯醯胺經自由基聚合反應而得。所得之PCOB以H1-NMR及FTIR確認其結構並利用GPC測定其分子量。
    而評估添加分散劑對於鈦酸鋇漿體穩定性的影響，主要方法有黏度，沈降體積，粒徑分佈，並利用高分子之解離率，表面電位，及吸附量來加以解釋，且利用ICP-MASS來測量Ba2+的溶出量，實驗發現添加PCOB能減少鋇離子的溶出，因為PCOB吸附量較PMAA-Na多，且PCOB擁有兩個羧基可以吸附較多鋇離子。由黏度實驗、沈降實驗及粒徑分佈發現添加PCOB能穩定鈦酸鋇漿體，其分散效果可和PMAA-Na相當，且隨著pH值越高，所需要的漿體穩定劑量越少。另外胚體在經過壓胚、燒結後，發現其密度及介電常數均較PMAA-Na高，顯示PCOB確實能有效分散鈦酸鋇漿體。
    實驗結果顯示鈦酸鋇漿體在pH=7、9、12時，對於漿體之穩定皆存在一飽和劑量，在此劑量以上，漿體可維持良好之分散，且隨著pH值增加，達到穩定分散所需之飽合劑量越少，即在pH值較高時，僅需較少量之分散劑即可使漿體達到良好之分散。

    This study continues the research and development of an anionic water-soluble copolymer,poly〔(4-carboxyamino-4-oxo-2-butenate) acrylamide〕(PCOB),which was copmared with PMAA-Na〔sodium salt of poly(methacrylic acid)〕and applied to BaTiO3 powder at different pH to characterise the dispersive ability. PCOB was prepared from 4-carboxyamino- 4-oxo-2-butenate and acrylamide through a free radical copolymerization.4-carboxy
    amino-4-oxo-2-butenate was made by reacting maleic anhydride with ammonium carbamate. The chemical structure of PCOB were verified from their H1-NMR and FTIR spectra.,and the molecular weight of PCOB was measured by GPC.
    The dispersion ability of PCOB on aqueous BaTiO3 slurries was evaluated from viscosity, sedimentation volume , particle size distribution, and dissussed by using the dissociation of PCOB ,zeta potential of particles, and adsorption of PCOB onto particles.Also, the amount of leached Ba2+ ion from BaTiO3 to slurry was measured.The result shows that PCOB causes less Ba2+ ion dissolved into solution.,because greater amount of PCOB adsorbed on BaTiO3 particles.From the experimental results
    of viscosity, sediment volume, and particle size distribution, added PCOB was found to be effective in making a stable BaTiO3 slurry.The dispersion effect is similar to PMAA-Na. The amount of PCOB or PMAA-Na required to stabilize aqueous BaTiO3 suspensions are decreased with increasing pH.
    Finally, the sintered parts with PCOB exhibits higher density and dielectric constant than those with PMAA-Na.
    Experimental results exhibit BaTiO3 slurries with pH=7,9,12,have a appropriate amount of dispersant for stabilize
    aqueous BaTiO3 suspensions,above the point ,slurry can maintain
    well dispersion. When the pH value is higher,less amount of dispersant that can making BaTiO3 slurry stable.

    第一章 緒論……………………………………………………………..1 第二章 文獻回顧………………………………………………………..3 2-1鈦酸鋇粉末的合成…………………………………………………..3 2-2粉體分散系統穩定性分析之文獻探討……………………………..7 2-3鈦酸鋇微結構與電性的研究……………………………………….17 2-4分散原理...............................................21 2-4-1粒子的特性……………………………………………………...21 2-4-2膠體粒子間表面作用力的形式…………...................23 2-4-3分散機構………………………………………………………...25 2-5電雙層理論………………………………………………………….33 2-6分散效果之評估方法……………………………………………….35 2-6-1粒子的沈降方式………………………………………………...35 2-6-2沈降法的原理…………………………………………………...36 2-6-3分散系統的流變性質…………………………………………...38 2-7有機分子對粒子表面的吸附行為及吸附等溫線………………….41 第三章高分子的合成與鑑定………………………………………....44 3-1前言………………………………………………………………….44 3-2高分子的合成……………………………………………………….44 3-2-1實驗藥品和儀器設備…………………………………………...44 3-2-2實驗步驟………………………………………………………...46 3-3核磁共振(NMR)光譜分析……………………………………......47 3-4紅外線(IR)光譜分析……………………………………………….48 3-5分子量的評估……………………………………………………….48 3-6 PCOB之固含量測定………………………………………………..49 3-7結果與討論………………………………………………………….50 3-7-1高分子結構鑑定………………………………………………...50 3-7-2分子量的量測…………………………………………………...50 3-7-3固含量的量測…………………………………………………...51 第四章BaTiO3粒子分散效果評估……………………………………..56 4-1前言………………………………………………………………...56 4-2實驗評估…………………………………………………………….57 4-2-1藥品與儀器設備………………………………………………...57 4-2-2實驗材料………………………………………………………...58 4-3實驗製程…………………………………………………………….58 4-3-1漿體的製備……………………………………………………...58 4-3-2燒結體的製備…………………………………………………...58 4-4性質分析…………………………………………………………….59 4-4-1 X光粉末繞射(XRD)分析………………………………………..59 4-4-2分散劑解離率的量測…………………………………………...59 4-4-3黏度量測………………………………………………………...59 4-4-4沈降高度………………………………………………………...60 4-4-5粒徑分佈………………………………………………………...60 4-4-6表面電位………………………………………………………...60 4-4-7吸附量…………………………………………………………...61 4-4-8鋇離子溶出量…………………………………………………...61 4-4-9胚體密度………………………………………………………...62 4-4-10介電常數與介電損失…………………………………………..63 4-4-11微結構分析..........................................64 第五章 鈦酸鋇之分散行為結果與討論……………………………..69 5-1鈦酸鋇在水中的解離……………………………………………….69 5-2分散劑在水中的解離率…………………………………………….72 5-3鈦酸鋇漿體的黏度………………………………………………….76 5-4鈦酸鋇漿體的粒徑分佈…………………………………………….81 5-5鈦酸鋇粒子的表面電位…………………………………………….89 5-6 鈦酸鋇粒子的沈降………………………………………………..94 5-7分散劑在鈦酸鋇粒子上的吸附…………………………………..103 5-8鈦酸鋇漿體之Ba2+溶出量………………………………………..113 5-9鈦酸鋇胚體的密度………………………………………………..118 5-10鈦酸鋇胚體的之電性…………………………………………….123 5-11鈦酸鋇胚體的微結構分析……………………………………….129 5-12鈦酸鋇與PCOB及PMAA-Na系統之凝膠穩定圖……………......148 第六章 結論………………………………………………………….150 第七章 參考資料…………………………………………………….152

    第七章 參考資料
    1. C. Gόmez-Yáňez, H. Balmori-Ramírez, F. Martínez, “Colloidal processing of BaTiO3 using ammonium polyacrylate as dispersant” Ceramics International 26 (2000) 609-616
    2. X. Wang, B. I. Lee, L. Mann, “Dispersion of barium titanate with polyaspartic acid in aqueous media”, Colloids and Surfaces A: Physicochemical and Engineering Aspects 202 (2002) 71-80
    3. W. J.Tseng, S. Li, “Rheology of colloidal BaTiO3 suspension with ammonium polyacrylate as a dispersant”, Materials Science and Engineering A333 (2002) 314-319
    4. J. Davies, J.G.P. Binner,“ The role of ammonium polyacrylate in dispersing concentrated alumina suspensions”, Journal of the European Ceramics Society 20 (2000) 1539-1553
    5. A. Tsetsekou, C. Agrafotis, A. Milias,“Optimization of the rheological properties of alumina slurries for ceramic processing applications PartⅠ：Slip casting”, Journal of the European Ceramics Society 21(2001)363-373
    6. D. Liu,“Influence of dispersant on powder dispersion and properties of zirconia green compacts”, Ceramics International 26 (2000) 279-287
    7. M.C. B. Lόpez, B. Rand, F.L. Riley,“Polymeric stabilization of aqueous suspensions of barium titanate PartⅠ: Effect of pH”,Journal of the European Ceramics Society 20(2000)1579-1586
    8. R. Moreno,“The Role of Slip Additives in Tape-Casting Technology：Part Ⅰ-Solvents and Dispersants”ENGINEERING VOLUME 71, No.10,OCTOBER 1992
    9. 劉鳳錦,“鈦酸鋇的溶膠凝膠程序”, 國立臺灣工業技術學院工程技術研究所化學工程組碩士論文,1987
    10. K. Kudaka,K. Iizumi, K. Sasaki,“Preparation of Stoichiometric Barium Titanyl Tetahydrate”, J. Am. Ceram. Soc.,Bull,61〔11〕1236 (1982)
    11. K.S. Mazdiyasni, L.M.Brown“Synthesis of Nb2O5-Doped with BaTiO3 Improved Electrical Properties” J. Am. Ceram. Soc.,55〔12〕633-34(1972)
    12. K.S. Mazdiyasni,“Fine Particle Peroveskite Processing”, J. Am. Ceram. Soc.,Bull,63〔4〕591-94 (1984)
    13. Kirby,K.W. and Wechsler B.A.,“Phase Relations in Barium Titanate –Titanium Oxide System ”,J.Am.Ceram.Soc.,74 1841-1846(1991)
    14. S.BHATTACHARJEE, M. K. PARIA, H. S. MAITI,“Polyvinyl butyral as a dispersant for barium titanate in a non-aqueous suspension”, JOURNAL OF MATERIALS SCIENCE 28(1993)6490-6495
    15. M.C. Blanco-Lopez, B. R. L. Riley,“The Properties of Aqueous Phase Suspensions of Barium Titanate”, Journal of the European Ceramic Society 17 (1997) 281-287
    16. U. Paik,V. Hackley, S. Chio, Y. Jung,“The effect of electrostatic repulsive forces on the stability of BaTiO3 particles suspended in non-aqueous media ” Colloids and Surfaces A: Physicochemical and Engineering Aspects 135 (1998)77-88
    17. J. Jean, H.Wang, “Dispersion of Aqueous Barium Titanate Suspensions with Ammonium Salt of Poly(methacrylic acid)”,J.Am Ceram.Soc.,81〔6〕1589-99(1998)
    18. D.Völtzke, H.P. Abicht,J. Woltersdorf,E. Pippel,“Surface modification of pre-sintered BaTiO3 particles” Materials Chemistry and Physics73 (2002) 274-280
    19. W. Tseng, S. Li,“Rheology of colloidal BaTiO3 suspension with ammonium polyacrylate as a dispersant”, Materials Science and Engineering A333 (2002) 314-319
    20. Y. Hu, S. Gong,D. Zhou,“Stability of BaTiO3 aqueous suspensions with PVA-b-COOH ”, Materials Science and
    Engineering B99 (2003) 520-522
    21. S. Kumar, V.S. Raju,T. R.N. Kutty,“Investigation on the chemical states of sintered barium titanate by X-ray photoelectron spectroscopy”, Applied Surface Science 206 (2003) 250-261
    22. W. Tseng, C. Lin,“Effect of dispersants on rheological behavior of BaTiO3 powders in ethanol-isopropanol mixtures”Materials Chemistry and Physics 80 (2003) 232-238
    23. J.Cesarano, I. A. Aksay, “Stability of Aqueous α-Al2O3 Suspensions with Poly(methacrylic acid)Polyelectrolyte
    ”, J.Am.Ceram.Soc.,71〔4〕250-55(1988)
    24. J.Cesarano, I. A. Aksay,“Processing of Highly Concentrated Aqueous α-Alumina Suspensions Stabilized with Polyelectrolytes”, J. Am. Ceram. Soc.,71〔12〕1062-67(1988)
    25. W. J. Wei, S. J. Lu, B. Yu,“Characterization of Submicron Alumina Dispersions with Poly(methacrylic acid) Polyelectrolyte”
    Journal of the European Ceramics Society 15 (1995) 155-164
    26. E.Luther,J.Yanez,G.Franks,F.Lange,D.Pearson,“Effect of Ammonium Citrate on the Rheology and Particle Packing of Alumina Slurries”, J. Am. Ceram. Soc.,78〔6〕1495-500(1995)
    27. R.Moreno, A. Salomoni, I. Stamenkovic, “Influence of Slip Rheology on Pressure Casting of Alumina”, Journal of the European Ceramics Society 17(1997)327-331
    28. S. Baklouti, C. Pagnoux, T. Chartier& J. F. Baumard, “Processing of Aqueous α-Al2O3, α-SiO2 andα-SiC Suspensions with Polyelectrolytes”, Journal of the European Ceramics Society 17(1997)1387-1392
    29. H. Kamiya, Y.Fukuda, Y. Suzuki, M. Tsukada,“Effect of Polymer Dispersant Structure on Electrosteric Interaction and Dense Alumina Suspension Behavior”, J. Am. Ceram. Soc.,82〔12〕3407-12(1999)
    30. D. Santhiya, G. Nandini, S. Subramanian, K. A. Natarajan , S.G. Malghan,“Effect of polymer molecular weight on the adsorption of polyacrylic acid at the alumina-water interface” Colloids and Surfaces A: Physicochemical and Engineering Aspects 133 (1998)157-163
    31. R. M. Anklekar, S.A. Borkar, S. Bhattacharjee, C. H. Page, A. K. Chatterjee,“Rheology of concentrated alumina suspension to improve the milling output in production of high purity alumina powder”, Colloids and Surfaces A: Physicochemical and Engineering Aspects 133 (1998)41-47
    32. D. Santhiya, S. Subramanian, K. A. Natarajan, S. G. Malghan, “Surface Chemical Studies on the Competitive Adsorption of Poly(acrylic acid) and Poly(vinyl alcohol) onto Alumina”, Journal of Colloid and Interface Science 216, 143-153 (1999)
    33. Y. Liu,L. Gao, L. Yu, J. Guo,“Adsorption of PBTCA on Alumina Surfaces and Its influence on the Fractal Characteristics of Sediments”Journal of Colloid and Interface Science 227, 164-170 (2000)
    34. J.Davies and J.G.P. Binner,“Coagulation of electrosterically dispersed concentrated alumina suspensions for paste production”, Journal of the European Ceramics Society 20 (2000) 1555-1567
    35. Z. Yuping, J. Dongliang, P. Greil,“Tape casting of aqueous Al2O3 slurries” Journal of the European Ceramics Society 20 (2000) 1691-1697
    36. S. Mei, J. Yang, J. M. F. Ferreira,“Effect of Dispersant Concentration on Slip Casting of Cordierite-Based Glass Ceramics”, Journal of Colloid and Interface Science 241, 417-421 (2001)
    37. A.Dakskobler, T. Kosmac,“Destabilisation of an alkaline aqueous alumina suspension by the addition of magnesium acetate” Colloids and Surfaces A: Physicochemical and Engineering Aspects 195 (2001)197-203
    38. J. Tsubaki, M. Kato, M. Miyazawa, T. Kuma, H. Mori,“The effects of the concentration of a polymer dispersant on apparent viscosity and sedimentation behavior of dense slurries ”,Chemical Engineering Science 56 (2001) 3021-3026
    39. X.Zhu, D. Jiang, S. Tan, Z. Zhang,“Dispersion properties of alumina powders in silica sol ” Journal of the European Ceramics Society 21 (2001)2879-2885
    40. L. Jiang, L. Gao, Y. Liu,“Adsorption of salicylic acid, 5-sulfosalicylic acid and Tiron at the alumina-water interface”, Colloids and Surfaces A: Physicochemical and Engineering Aspects 211 (2002) 165-172
    41. C.Ha, Y. Jung , J. Kim, C. Jo, U. Paik,“Effect of particle size on gelcasting process and green properties in alumina”, Materials Science and Engineering A337 (2002) 212-221
    42. G. Bertrand , C. Filiatre, H. Mahdjoub, A. Foissy, C. Coddet, “Influence of slurry characteristics on the morphology of spray-dried alumina powders”, Journal of the European Ceramics Society 23 (2003) 263-271
    43. Y.Yang, W. Sigmund,“A new approach to prepare highly loaded aqueous alumina suspensions with temperature sensitive rheological properties ” Journal of the European Ceramics Society 23 (2003)253-261
    44. S. Baklouti, M. R. B. Romdhane, S. Boufi, C. Pagnoux, T. Chartier, J. F. Baumard,“Effect of copolymer dispersant structure on the properties of alumina suspensions”, Journal of the European Ceramics Society 23 (2003) 905-911
    45. B.Baron, C. S. Kumar, G. L. Gonidec, S. Hampshire,“Comparison of different alumina powders for the aqueous processing and pressureless sintering of Al2O3-SiC nanocomposites” Journal of the European Ceramics Society 22 (2002)1543-1552
    46. L.A.Timms,C. B. Ponton, M. Strangwood,“Processing of Al2O3/SiC nanocomposites-part2: green body formation and sintering” Journal of the European Ceramics Society 22 (2002)1569-1586
    47. A. Pettersson, G. Marino, A. Pursiheimo, J. B. Rosenholm,“Electrosteric Stabilization of Al2O3,ZrO2,and 3Y-ZrO2 Suspensions: Effect of Dissociation and Type of Polyelectrolyte”, Journal of Colloid and Interface Science 228, 73-81 (2000)
    48. F. Shojai, A.B.A. Pettersson, T. Mäntylä, J.B Rosenholm, “Electrostatic and electrosteric stabilization of aqueous slips of 3Y-ZrO2 powder”, Journal of the European Ceramics Society 20(2000) 277-283
    49. J. Wang and L. Gao,“Surface and electrokinetic properties of Y-TZP suspensions stabilized by polyelectrolytes ”, Ceramics International 26 (2000) 187-191
    50. Y. Liu and L. Gao,“Deflocculation study of aqueous nanosized Y-TZP suspensions”, Materials Chemistry and Physics 78 (2002) 480-485
    51. Q. Tan, Z. Zhang, Z. Tang, S. Luo, K. Fang,“Influence of polyelectrolyte dispersant on slip preparation of nano-sized tetragonal polycrystals zirconia for aqueous-gel-tape-casting process”, Materials Chemistry and Physics 80 (2003) 615-619
    52. D.Guo, K. Cai, L. Li,Z. Gui,“Application of gelcasting to the fabrication of piezoelectric ceramic parts”, Journal of the European Ceramics Society 23 (2003)1131-1137
    53. H. Mahdjoub, P. Roy, C. Filiatre, G. Bertrand, C. Coddet,“The effect of the slurry formulation upon the morphology of spray-dried yttria stabilized zirconia particles ” Journal of the European Ceramics Society 23(2003) 1637-1648
    54. S. Chibowski and M. Wiśniewska, “Study of electrokinetic properties and structure of adsorbed layers of polyacrylic acid and polyacrylamide at Fe2O3-polymer solution interface”, Colloids and Surfaces A: Physicochemical and Engineering Aspects 208 (2002)131-145
    55. V. A. Hackley, “Colloidal Processing of Silicon Nitride with Poly(acrylic acid): I, Adsorption and Electrostatic Interactions”, J. Am. Ceram. Soc.,80〔9〕2315-25(1997)
    56. U. Paik, V. Hackley, H. Lee,“Dispersant –Binder Interactions in Aqueous Silicon Nitride Suspensions ”, J. Am. Ceram. Soc.,82〔4〕833-40(1999)
    57. C. Shih and M. Hon, “Stability of colloidal silicon nitride suspension with poly-electrolyte”, Ceramics International 26 (2000) 47-55
    58. X. Xu, M. I.L.L. Oliveira, R. Fu, J. M.F. Ferreira,“Effect of dispersant on the rheological properties and slip casting of concentrated sialon precursor suspensions”, Journal of the European Ceramics Society 23(2003) 1525-1530
    59. X. Xu, M. I.L.L. Oliveira, R. Fu, J. M.F. Ferreira,“Effect of dispersant on the rheological properties and slip casting of concentrated sialon precursor suspensions”, Journal of the European Ceramics Society 23(2003) 1525-1530
    60. P. Kuo, T. Chang, L. Lu,“Functional Polymers for Colloidal Applications.Ⅰ. Structural Effects of Lipophile-Modified Polyacrylates on Adsorption and Dispersion Ability”,Journal of Applied Polymer Science, Vol. 44, 859-867(1992)
    61. D. Liu,and C. Fu,“Effect of Rheological Behavior on Properties of Cast and Sintered Silicon Carbide”, Ceramics International 22 (1996) 101-106
    62. J. Sun and L. Gao,“Dispersing SiC powder and improving its rheological behaviour”, Journal of the European Ceramics Society 21 (2001) 2447-2451
    63. R. Zhou, Y. Jiang, Y. Liang, F. Zheng, Yuanzi Chen“Dispersion behaviour of laser-synthesized nanometric SiC powders in aqueous medium with ammonium polyacrylate”, Ceramics International 28 (2002) 847-853
    64. M. Hashiba, H. Okamoto, Y. Nurishi, K. Hiramatsu,“Dispersion of ZrO2 particles in aqueous suspensions by ammonium polyacrylate ”,Journal of Materials Science 24 (1989) 873-876
    65. B. J. Briscoe, A. U. Khan, P. F. Luckham,“Stabilising Zirconia Aqueous Suspensions using Commercial Polyvalent Electrolyte Solutions ”, Journal of the European Ceramics Society 18(1998) 2169-2173
    66. I. M. G. d. Santos,A.G.d. Souza,F. R. Sensato,E.R. Leite,E. Longo, J. A. Varela,“Rheological properties of tin oxide suspensions”, Journal of the European Ceramics Society 22 (2002) 1297-1306
    67. C. Shih, B.Lung, M.Hon,“Colloidal processing of titanium nitride with poly-(methacrylic acid) polyelectrolyte”,Materials Chemistry and Physics 60 (1999) 150-157
    68. L. Jiang and L. Gao, “Effect of Tiron adsorption on the colloidal stability of nano-sized alumina suspension”, Materials Chemistry and Physics 80 (2003) 157-161
    69. J. Sun, L. Bergström, L. Gao,“Effect of Magnesium Ions on the Adsorption of Poly(acrylic acid) onto Alumina”, J. Am. Ceram. Soc.,84〔11〕2710-12(2001)
    70. A. C. Caballero, J. F. Fernández, C. Moure& P. Durán,“ZnO-Doped BaTiO3 : Microstructure and Electrical Properties”, Journal of the European Ceramic Society 17 (1997) 513-523
    71. E. Brzozowski, M.S. Castro, C.R. Foschini, B.Stojanovic,“Secondary phases in Nb-doped BaTiO3 ceramics”, Ceramics International 28 (2002) 773-777
    72. C. Miot,C. Proust, E. Husson,“Dense Ceramics of BaTiO3 Produced from Powders Prepared by a Chemical Process”, Journal of the European Ceramics Society 15(1995)1163-1170
    73. G.Arlt,D.Hennings,G.de with,“Dielectric properties of Fined-Grained Barium Titanate ,”J.Appl.Phys,58,p1619-1625(1985)
    74. 陳龍賓，“分散劑的合成以及對於鈦酸鋇漿體分散性能的評估” 國立台灣師範大學化學研究所碩士論文,2002
    75. 陸立美“聚丙烯酸系構造對其分散性之影響”國立成功大學碩士論文,1989
    76. V. Ramakrishnan,Pradip, S.G.Malghan,“The stability of alumina-zirconia suspensions” Colloids and Surfaces A: Physicochemical and Engineering Aspects 133 (1998)135-142
    77. 吳俊賢,“水系氧化鋁懸浮液之酸鹼度對沈降、流變行為與電泳披覆影響之研究”,中國文化大學材料科學與製造研究所碩士論文,2001
    78. A.J.SÁNCHEZ-HERENCIA,A.J. MILLÁN,M.I.NIETO, R.MORENO,“AQUEOUS COLLOIDAL PROCESSING OF NICKEL POWDER”Acta mater.49 (2001) 645-651
    79. 應國良，“鈦酸鋇漿體分散劑的合成與應用”國立台灣師範大學化學研究所碩士論文,2003
    80. R.Alberty and R.Silbey,“Physical Chemistry”
    81. 江家雯,“水系鈦酸鋇漿料中鋇溶解行為及其對粉體分散行為之影響”國立清華大學材料科學工程研究所碩士論文,2000
    82. 江禎斌,“鈣硼矽玻璃陶瓷粉末在水系漿料中的分散行為及溶解動力學研究 ”國立清華大學材料科學工程研究所碩士論文,2001
    83. Y. Fukuda, T. Togahi,Y. Suzuki, M, Naito, H. Kamiya, “Influence of additive content of anionic polymer dispersant on dense alumina suspension viscosity”,Chemical Engineering Science 56 (2001) 3005-3010
    84. L. Xuejian ,H. Liping, X. Xin, F. Xiren, G. Hongchen,“Optimizing the rheological behavior of silicon nitride aqueous suspensions”, Ceramics International 26 (2000) 337-340
    85. Z. Yuping, J. Dongliang, P. Greil,“Tape casting of aqueous Al2O3 slurries” Journal of the European Ceramics Society 20 (2000) 1691-1697
    86. Z.Chen, T.Ring, J.Lemaĭtre，“Stabilization and Processing of Aqueous BaTiO3 Suspension with Polyacrylic Acid”, J.Am.Ceram.Soc.,75〔12〕5201-208(1992)
    87. D.A.Anderson,J.H.Adair,D.Miller,J.V.Biggers,T.R.Shrout,“SURFACE CHEMISTRY EFFECTS ON CERAMIC PROCESSING OF BaTiO3 POWDER”Ceramic Transactions , Vol.1,Ceramic Powder Science ⅡA. The American Ceramic Society,OH,1988,pp.485-492
    88. Y.Hirata,A. Nitta,S. Sameshima, Y. Kamino,“Dielectric properties of barium titanate prepared by hot isostatic pressing ”,Materials Letters 29 (1996) 229-234
    89. P. Durán, D. Gutierrez, J. Tartaj, C. Moure“Densification behaviour，microstructure development and dielectric properties of pure BaTiO3 prepared by thermal decomposition of (Ba,Ti)-citrate polyester resins”,Ceramics International 28 (2002) 283-292
    90. P.Durán, J. Tartaj, C. Moure, “Sintering behaviour of Y2O3 powders prepared by the polymer complex solution method”, Ceramics International 28 (2002)791-803
    91. W. H. Tuan, S. K. Lin, “The microstructure-mechanical properties relationships of BaTiO3” Ceramics International 25 (1999) 35-40
    92. N. Mukherjee, R.D. Roseman, Q. Zhang, “Sintering behavior and PTCR properties of stoichiometric blend BaTiO3” Journal of Physics and Chemistry of Solids 63 (2002) 631-638
    93. 王宏仁,“鈦酸鋇在水溶液中的分散行為”, 國立清華大學材料科學工程研究所碩士論文,1997

    QR CODE