簡易檢索 / 詳目顯示

回結果列表
研究生： 林世弘
論文名稱： 電致色變氧化鎢薄膜結構與熱隔絕效益分析
The film characterization and heat obstructing effect of tungsten oxide electrochromic devices
指導教授： 程金保
學位類別： 碩士
Master
系所名稱： 機電工程學系
Department of Mechatronic Engineering
論文出版年： 2008
畢業學年度： 96
語文別： 中文
論文頁數： 100
中文關鍵詞： 電致色變 、濺鍍法 、氧化鎢薄膜 、拉曼散射光譜 、熱隔絕效益
論文種類： 學術論文
相關次數： 點閱：206  下載：7 
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報

    • 電致色變材料所運用的層面相當廣泛，除了用於建築節能窗材調節照明與空調之負擔以外，更可以延伸應用於光學用品、交通工具之特殊玻璃及各類數位顯示器上，其擁有良好的穿透率控制性、記憶效應、反應速度快及穿透率變化之有效光譜範圍廣等應用上的優點。
    本研究採用射頻磁控濺鍍法在ITO玻璃基板上以不同氬氧比氣體通量製備氧化鎢及氧化鎳薄膜，且將製備完成之薄膜在不同溫度下做退火處理，並對氧化鎢薄膜作表面微結構、電化學、響應時間及分光光譜穿透率與反射率等分析。除此之外，再對薄膜進行微拉曼散射光譜分析，透過分析結果進而瞭解氧化鎢薄膜的變色機制。最後，將氧化鎳薄膜做為輔助變色層，結合氧化鎢薄膜以固態電解質封裝成互補式之電致色變元件，將元件做分光光譜分析，並將分析所得之數據帶入各標準試驗法，進而分析其實際運作時之熱隔絕效益與所能提供之保護係數。
    實驗結果顯示氧化鎢薄膜在氬氧比氣體通量為9:3時，在波長550 nm與1650 nm時皆擁有最大的ΔT值及ΔOD值，ΔT各為64.79 %及31.04 %，ΔOD各為1.2835及1.7236。以氧化鎳薄膜做為輔助變色層以固態電解質封裝成互補式之電致色變元件時，可見光部分在電致色變元件去色時可以維持66.6 %的穿透率，在著色的時候，元件穿透率下降至3.8 %；而在太陽熱能的部分，元件在去色時可允許58 %的太陽熱能穿過元件，著色時太陽熱能穿透率只剩下2.99 %，顯示出元件有相當良好的熱隔絕效益。

    第一章 序論…………………………………………….……………...………..1 1-1 前言………………………………………………….……………......…..1 1-2 節能窗材……………………………………………………………...…..2 1-3 研究動機與目的……………………………………………………….....5 第二章 文獻回顧……………………...……………………….……………......8 2-1 電致色變之簡介…..……………...…………….…………….…………..8 2-2 電致色變元件……………………...……….……………...……………10 2-3 氧化鎢之結構與電致色變機制……...………….……………………...13 2-4互補式電致色變元件之熱隔絕效益評估……………............................18 第三章 實驗方法與步驟……………………………….………………...……21 3-1 實驗材料…..………………………………………………………...…..22 3-2 基材前處理……..……………………...……………………………......22 3-3 實驗設備………………………………………………………………...23 3-4 氧化鎢與氧化鎳之製備…………………...……………………………23 3-5電解質之調製………………………….……...…………………………28 3-6 元件之封裝……………………………………………...………………28 3-7 薄膜的分析與量測………………….......................................................30 3-7-1濺鍍速率之量測.……………………………...…….………………30 3-7-2 表面微結構之分析……………………………...….………………30 3-7-3 X-Ray 繞射分析…………………………………....………………30 3-7-4 微拉曼散射光譜分析.………………………….…...……...………31 3-7-5 UV/VIS/NIR分光光譜儀分析…...……………….…...……………31 3-7-5 電化學分析……………………………………….……...…………31 第四章 結果與討論………...…………...……………………….…………….35 4-1 氬氧比氣體通量對氧化鎢薄膜之影響..…...…….…...…….………….35 4-1-1 電漿濺鍍速率之分析..……….………………...……….………….35 4-1-2 表面微結構之分析..……….………………………...….………….35 4-1-3 薄膜晶體結構之分析..………………………….……....………….38 4-1-4 分光光譜分析..……….……….…………………………...……….38 4-1-5 響應時間分析..……….……….……………………………...…….43 4-2 退火製程對薄膜之影響..……….……….…………..……………...…..46 4-2-1表面微結構之分析..……….……….…………………………….....46 4-2-2 薄膜晶體結構之分析..……….……….…………….……………...46 4-2-3 循環伏安分析..……….………….…………………...…………….50 4-2-4 響應時間分析..……….……….………………………...………….53 4-3 微拉曼散射光譜之分析..……….……….……………………...………56 4-3-1氬氧比對氧化鎢薄膜之影響..……….……….……………...……..56 4-3-2 退火製程分析..……….……………………………….………...….59 4-3-3 不同驅動電壓..……….……………………………….……...…….62 4-3-4 循環耐久性分析..……….…………………………….…...……….63 4-4 電致色變元件之熱隔絕效益分析..……….………………………...….67 4-4-1 分光光譜分析..……….……….…………………………………....67 4-4-2平板玻璃透射率、反射率及日光輻射熱取得率試驗法…...………72 4-4-3 SMPF,SSPF與ISO制可見光穿透率試驗法..………...……...…….75 第五章 結論與未來展望…....………...………………………….………...….78 參考文獻………………………………………………………………………..81 附表一 可見光透射率及反可見光射率計算之Dλ．Vλ係數…………………86 附表二 日光透射率、日光反射率及日光吸收率計算之Eλ．Δλ係數………87 附表三 Normalized relative spectral distribution factors for the calculation of the SMPF…………………………………………………………....88 附表四 Normalized relative spectral distribution factors for the calculation of the SSPF……………………………….…………………………....89 附表五 Normalized relative spectral distribution DλV(λ)Δλ for the calculation of the visible solar transmittance (Tvis) …………...……....90

    1. 塗逢祥，節能窗技術，中國建築工藝出版社，(2003)，頁1-2。
    2. M. Santamouris, in: J. Gordon (Ed.), "Solar Energy: The State of the Art", James & James Science Publishers, London, UK, (2001)..
    3. http://china5.nikkeibp.co.jp/china/news/news/mech200706280125.html
    4. 何國川，電化學與無窗時代，化工，第37卷第3期，(1990)，頁32-42。
    5. http://windows.lbl.gov/comm_perf/Electrochromic/electroSys-cec.htm
    6. C.G. Granqvist, "Oxide electrochromics: Why, how, and whither", Solar Energy Materials & Solar Cells, 92, (2008), 203–208.
    7. http://www7.big.or.jp/~cgi19786/ngf/nglass/ng13.html
    8. http://www.yet2.com/app/insight/techofweek/27692?sid=200
    9. Satyen K. Deb, " Opportunities and challenges in science and technology of WO3 for electrochromic and related applications", Solar Energy Materials & Solar Cells, 92, (2008), 245–258.
    10. M. Moller, S. Asaftei, D. Corr, M. Ryan, L. Walder, "Switchable Electrochromic Images Based on a Combined Top-Down Bottom-Up Approach", Advanced Materials, 16(17), (2004), 1558-1562.
    11. E. Washizu, A. Yamamoto, Y. Abe, M. Kawamura, K. Sasaki, "Optical and electrochromic properties of RF reactively sputtered WO3 films", Solid State Ionics, 165, (2003), 175– 180.
    12. S. Yueyan, Z. Zhiyang, Y. Xiaoji, "Electrochromic properties of NiOxHy thin films", Solar Energy Materials & Solar Cells, 71, (2002), 51–59.
    13. 蔡侑東，互補式全固態電致色變元件之製作及特性分析，國立台灣師範大學機電科技學系碩士論文，民國九十六年。

    14. Y. Wang, X. Cheng, Z. Lin, C. Zhang, F. Zhang, 「Optimization of PECVD silicon oxynitride films for anti-reflection coating,」 Vacuum, 72 (2004), 345–349.
    15. C. G. Granqvist, A. Azens, A. Hjelm, L. Kullman, G. A. Niklasson, D.Ronnow, M. Strømme Mattsson, M. Veszelei, G. Vaivars, "Recent advances in electrochromic for smart windows applications", Solar Energy, Vol.63, No. 4, (1998), 199-216
    16. 謝育忠，電漿濺鍍電致色變氧化鎳薄膜特性研究與節能評估，中原大學化學工程系碩士論文，民國九十一年。
    17. C. G. Granqvist, A. Azens, J. Isidorsson, M. Kharrazi, L. Kullman, T.Lindstrom, G.A. Niklasson, C.-G. Ribbing, D. Ronnow, M. Stromme Mattson, M. Veszelei, "Towards the smart windows: progress in electrochromics", Journal of Non-Crystalline Solids, Vol.218, (1997), 273-279.
    18. B. W. Faughnan, R. S. Crandall, P. M. Heyman, "Electrochromism in WO3 Amorphous Films", RCA Review, Vol 36, (1975), 177-197.
    19. 林巧芬，以紫晶搭配普魯士藍電致色變元件之研究，國立台灣大學化學工程研究所碩士學位論文，民國九十二年。
    20. S. K. Deb, "A Novel Electrophotographic System", Appl. Optics, Suppl. 3, (1969), 192.
    21. K. Bange, "Colouration of tungsten oxide films: A model for optically active coatings", Solar Energy Materials & Solar Cells, Vol.58, (1999), 1-131.
    22. C.G. Granqvist, "Electrochromic tungsten oxide films Review of progress 1993–1998", Solar Energy Materials & Solar Cells, (2000), 201 – 262.

    23. S.H. Lee, H. M. Cheong, J. G. Zhang, A. Mascarenhas, D. K. Benson, S. K. Deb, "Electrochromic mechanism in a-WO3-y thin films", Appl. Phys. Letters, (1999), 242 – 244.
    24. J.M. Honig, in: S. Trasatti (Ed), "Electrodes of Conductive Metallic Oxides", Elsevier, Amsterdam, (1980).
    25. S. K. Deb, "Optical and photoelectric properties and color centers in thin films of tungsten oxide", Philosophical Magazine, Vol 27, No 4, (1973), 801-822.
    26. O. F. Schirmer, V. Wittwer, G. Baur, G. Brandt, "Dependence of WO3 electrochromic absorption on crystallinity", Journal of the Electrochemical Society, Vol.124, No.5, (1977), 749-753.
    27. 楊慧敏，氧化鎢與氧化釩單層膜與多層膜之製備與特性分析及其電致色變性質，國立東華大學材料科學與工程研究所碩士論文，民國九十一年。
    28. http://www.topbulb.com/find/images/spectrum.gif
    29. http://en.wikipedia.org/wiki/Image:Solar_Spectrum.png
    30. C.W. Ong, H.Y. Wong, G.K.H. Pang, K.Z. Baba-Kishi, and C.L. Choy, "Relationship between the microstructure and nanoindentation hardness of thermally evaporated and magnetron-sputtered electrochromic tungsten oxide films", J. Mater. Res., Vol.16(6), (2001), 1541-1548.
    31. 王武章，反應磁控濺鍍氧化鎢薄膜之電致色變性質研究，國立成功大學材料科學及工程研究所碩士論文，民國九十四年。
    32. D. Yang, L. Xue, "Structures and electrochromic properties of Ta0.1W0.9Ox thin films deposited by pulsed laser ablation", Thin Solid Films, Vol.469-470, (2004), 54-58.
    33. P.V. Ashrit, G. Bader, Vo-Van Truong, "Electrochromic properties of nanocrystalline tungsten oxide thin films", Thin Solid Films, Vol.320, (1998), 324-328.
    34. Atilla Cihaner, Fatih Alg, "A processable rainbow mimic fluorescent polymer and its unprecedented coloration efficiency in electrochromic device", Electrochimica Acta 53, (2008) , 2574–2578
    35. Yoshiaki Suda, Hiroharu Kawasaki, Tamiko Ohshima, Yoshihito Yagyuu, "Characteristics of tungsten oxide thin films prepared on the flexible substrates using pulsed laser deposition", Thin Solid Films, (2007).
    36. Se-Hee Lee, Hyeonsik M. Cheong, C. Edwin Tracy, Angelo Mascarenhas, David K. Benson, Satyen K. Deb, "Raman spectroscopic studies of electrochromic a-WO3", Electrochimica Acta, Vol.44, (1999), 3111-3115.
    37. T. Ivanova, K.A. Gesheva, M. Kalitzova, B. Marsen, B. Cole, E.L. Miller, "Electrochromic behavior of Mo/W oxides related to their surface morphology and intercalation process parameters", Materials Science and Engineering, B 142, (2007), 126–134.
    38. Yin-Song Huang, Yu-Zhi Zhang, Xian-Ting Zeng, Xing-Fang Hu, "Study on Raman spectra of electrochromic c-WO3 films and their infrared emittance modulation characteristics", Applied Surface Science, Vol.202, (2002), 104-109.
    39. Yuna Kim, Eunkyoung Kim, "Complementary electrochromic windows with conductive nano-composite thin films", Current Applied Physics 8, (2008), 752–754
    40. CNS12381-R3161: Method of test on transmittance and reflectance for dayligt and solar radiation and solar heat gain coefficient of flat glass.

    41. ISO/FDIS 9050:2003(E), Glass in building—determination of light transmittance, solar direct transmittance, total solar energy transmittance, ultraviolet transmittance and related glazing factors, (2003).
    42. ISO 9845–1:1992(E), Solar energy—reference solar spectral irradiance at the ground at different receiving conditions—Part 1: direct normal and hemispherical solar irradiance for air mass 1.5, (1992).

    下載圖示
    QR CODE