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研究生: 蔡明甫
Tasi Ming Fu
論文名稱: 電沉積法應用於TiO2光觸媒薄膜最佳化參數製程之研究
Electrodeposition applied on Optimum Manufacture process of Titanium Dioxide Photocatalytic Film
指導教授: 李景峰
Li, Jeen-Fong
學位類別: 碩士
Master
系所名稱: 工業教育學系
Department of Industrial Education
論文出版年: 2014
畢業學年度: 103
語文別: 中文
論文頁數: 52
中文關鍵詞: 電沉積法二氧化鈦薄膜光催化特性
英文關鍵詞: electrodeposition, titanium dioxide thin films, photocatalytic properties
論文種類: 學術論文
相關次數: 點閱:132下載:4
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  • 本研究為使用電沉積法 (electro-deposition process) 於不鏽鋼板上製作二氧化鈦(TiO2)光觸媒薄膜,以進行開發光觸媒產品的基礎研究。電沉積製程所使用的工作流體是採用溶膠凝膠法混合酒精稀釋製成過氧鈦酸鍍液,再藉由電沉積反應將二氧化鈦沉積在304SS不鏽鋼板上,以製成奈米光觸媒薄膜。並檢測其表面形貌、光催化特性與親水性等理化特性。利用XRD、HR-FESEM、表面輪廓儀等儀器進行量測並分析製成參數與薄膜特性關係,選出適合的鍍膜參數,作為後續研究的參考範本。在電沉積製程方面,針對不同電壓與沉積時間的參數、沉積薄膜的表面特性與材質進行討論,並經由退火方式觀察其結晶變化情形。在光催化研究中,分析光觸媒照紫外光前後改質的情形,並探討照光後接觸角的變化。研究結果顯示,在控制電壓與沉積時間的條件下,可以得到沉積薄膜,但經由SEM觀看後,表面並不完整。而經由退火過程,可得明顯的結晶粒子。而鍍膜試片在光催化實驗中,顯示照光後的反射率有減少,顯示鍍膜的抗紫外線特性有增加;而在接觸角量測方面,未照紫外光時可以達到41.91度,證明製備的TiO2薄膜還具有疏水性。本研究期望能在未來提供製作在規格304SS不鏽鋼板上的TiO2光觸媒薄膜之參考,並能應用在空調系統設置不鏽鋼濾網上,以增進其除汙抑菌效果。

    In this research, the titanium dioxide (TiO2) photocatalyst film deposited on stainless steel plates by electrodeposition technique , and it is useful for photocatalyst products development. Electrodeposition processes used by the working fluid mixing with diluted alcohol to produce peroxotitanic acid bath by sol-gel method , so titanate ions deposited on the 304SS stainless steel plates that made of nano photocatalyst film, and then it would strengthen crystallization in the photocatalyst film by annealing, detection the surface morphology、Photocatalytic and hydrophilic properties such as hydrophilicity .
    Using XRD, HR-FE SEM, surface profiler and other equipment to performed made from the parameters measured and analyzed the relationship between film properties, chosen a suitable coating parameters, used as following research of the reference.
    In the electrodeposition process, for the parameters of different voltage and deposition tim、surface properties of the deposited films and materials to discussion,then using annealing method to observe changes in the crystal case. In photocatalytic , analysis of the situation before and after the modification of the photocatalyst as UV, discussion after irradiation with UV light contact angle changes.The results showed, under the control of voltage and deposition time conditions, the deposited film can be obtained, but the watch by SEM, the surface is not complete.rather through annealing process, we can get a clear crystal particles. rather test pieces in the photocatalytic coating experiments, according to displayed after the light the reflectance a decrease, the display characteristics of the anti-UV coating increase.
    While in terms of the contact angle measurements, when not as ultraviolet light can reach 41.91 degrees, TiO2 thin films prepared also prove a hydrophobic
    The research can provide the future production of the titanium dioxide (TiO2) photocatalyst film deposited on 304SS stainless steel plates to reference and set with stainless steel strainer in air conditioning systems to improve their antimicrobial decontamination capabilities.

    摘要............................................................................................................................... i 目錄.............................................................................................................................iii 表目錄.......................................................................................................................... v 圖目錄......................................................................................................................... vi 第一章 緒論 ............................................................................................................ 1 1.1 研究背景與動機............................................................................................ 1 1.2 文獻回顧........................................................................................................ 2 1.3 研究目的........................................................................................................ 5 1.4 研究方法........................................................................................................ 5 1.5 論文架構........................................................................................................ 7 第二章 理論基礎與背景 ........................................................................................ 8 2.1 奈米光觸媒之簡介........................................................................................ 8 2.2 二氧化鈦之材料性質.................................................................................. 11 2.3 製備二氧化鈦的方式.................................................................................. 19 2.4 電沉積法的原理.......................................................................................... 22 第三章 實驗設計與實驗程序 .............................................................................. 24 3.1 實驗設備...................................................................................................... 24 3.2 量測設備...................................................................................................... 26 3.3 實驗架構...................................................................................................... 30 3.4 實驗流程...................................................................................................... 31 3.5 實驗參數設計.............................................................................................. 35 第四章 實驗結果與討論 ...................................................................................... 36 4.1 製程參數對 TiO2 薄膜分析結果.............................................................. 36 4.2 TiO2 薄膜光催化結果討論........................................................................ 43 4.3 TiO2 薄膜疏水特性量測結果.................................................................... 45 第五章 結論與建議 .............................................................................................. 47 5.1 結論.............................................................................................................. 47 5.2 建議.............................................................................................................. 47 參考文獻.................................................................................................................... 48 附錄............................................................................................................................ 52

    [1]. Loannis, K., and A. Triantafyllos. "TiO2-assisted photocatalytic degradation of
    azo dyes in aqueous solution: kinetic and mechanistic investigations." J. Appl.
    Catal. B 49.1 (2004): 1-14.
    [2]. Tang, W. Z., et al. "TiO2/UV photodegradation of azo dyes in aqueous
    solutions." Environmental technology 18.1 (1997): 1-12.
    [3]. Yu, Jiaguo, and Xiujian Zhao. "Effect of substrates on the photocatalytic
    activity of nanometer TiO2 thin films." Materials Research Bulletin 35.8 (2000):
    1293-1301.
    [4]. Evans, P., and D. W. Sheel. "Photoactive and antibacterial TiO2 thin films on
    stainless steel." Surface and Coatings Technology 201.22 (2007): 9319-9324.
    [5]. Zhang, Shao Hua, et al. "Preparation of titania film by pyrolysis of chelated
    tetrabutyl titanate." Key Engineering Materials 368 (2008): 1468-1470.
    [6]. Sirghi, L., T. Aoki, and Y. Hatanaka. "Hydrophilicity of TiO2 thin films
    obtained by radio frequency magnetron sputtering deposition." Thin Solid
    Films 422.1 (2002): 55-61.
    [7]. 游政家, and 葉翳民. "以電沉積法製作大面積氧化鋅薄膜與奈米柱陣列" ,
    Journal of Technology 24.3 (2009): 191-196.
    [8]. Guo, Min, et al. "Effects of preparing conditions on the electrodeposition of
    well-aligned ZnO nanorod arrays." Electrochimica Acta 53.14 (2008):
    4633-4641.
    [9]. 黃昇章、何詠碩、楊文都、黃芳榮, "溶膠凝膠法與電沉積法製備晶種層對
    氧化鋅薄膜性質的影響", 2010.
    [10].Feng, Zhe-Sheng, et al.,Formation of Al O3–TiO2 composite oxide films on
    aluminum foil by cathodic electrodeposition and anodizing",Ceramics
    International 38.3, pp. 2501-2505, 2012.
    [11].Chen, Zhi, Limei Hao, and Changle Chen. "A fast electrodeposition method for
    fabrication of lanthanum superhydrophobic surface with hierarchical
    micro-nanostructures." Colloids and Surfaces A: Physicochemical and
    Engineering Aspects 401 (2012): 1-7.
    [12]. Łosiewicz, Bożena. "Experimental design in the electrodeposition process of
    porous composite Ni–P
    + TiO2 coatings." Materials Chemistry and
    Physics 128.3 (2011): 442-448.
    [13].Bhattacharyya, D., Sahoo, N. K., Thakur, S., & Das, N. C. "Spectroscopic
    ellipsometry of TiO2 layers prepared by ion-assisted electron-beam
    evaporation." Thin Solid Films360.1 (2000): 96-102.
    [14].Vishwas, M., Sharma, S. K., Rao, K. N., Mohan, S., Gowda, K. V., &
    Chakradhar, R. P. S.. "Influence of surfactant and annealing temperature on
    optical properties of sol–gel derived nano-crystalline TiO2 thin
    films."Spectrochimica Acta Part A: Molecular and Biomolecular
    Spectroscopy 75.3 (2010): 1073-1077.
    [15].Natarajan, C., N. Fukunaga, and G. Nogami. "Titanium dioxide thin film
    deposited by spray pyrolysis of aqueous solution." Thin Solid Films 322.1
    (1998): 6-8.
    [16].Lei, C. X., et al. "Liquid phase deposition (LPD) of TiO2 thin films as
    photoanodes for cathodic protection of stainless steel." Journal of Alloys and
    Compounds 513 (2012): 552-558.
    [17].朱家和、 潘寶慧、連水養, “超親水性TiO2光觸媒薄膜製備及特性之研究,”
    2010.
    [18].Mardare, Diana, and G. I. Rusu. "The influence of heat treatment on the optical
    properties of titanium oxide thin films." Materials Letters 56.3 (2002):
    210-214.
    [19].Yin, Wenzong., Wang, W., Zhou, L., Sun, S., & Zhang, L. "CTAB-assisted
    synthesis of monoclinic BiVO4 photocatalyst and its highly efficient
    degradation of organic dye under visible-light irradiation." Journal of
    hazardous materials 173.1 (2010): 194-199.
    [20].Brezova, V., Blažková, A., Karpinský, Ľ., Grošková, J., Havlinova, B., Jorik, V.,
    & Čeppan, M. "Phenol decomposition using Mn+
    /TiO2 photocatalysts
    supported by the sol-gel technique on glass fibres."Journal of Photochemistry
    and Photobiology A: Chemistry 109.2 (1997): 177-183.
    [21].葉雲友. "以射頻磁控濺鍍法製備二氧化鈦光觸媒玻璃之製程參數與特性
    研究." 臺灣師範大學工業教育學系學位論文 (2011): 1-114.
    [22].Yin, S, Zhnag, P., Liu, B., Liu, X., Sato, T., Xue, D., & Lee, S. W.."Microwave-assisted hydrothermal synthesis of monoclinic nitrogen-doped
    titania photocatalyst and its DeNOx ability under visible LED light
    irradiation." Research on Chemical Intermediates 36.1 (2010): 69-75.
    [23].Ochiai, T., Nakata, K., Murakami, T., Fujishima, A., Yao, Y., Tryk, D. A., &
    Kubota, Y. "Development of solar-driven electrochemical and photocatalytic
    water treatment system using a boron-doped diamond electrode and TiO2
    photocatalyst." Water research 44.3 (2010): 904-910.
    [24].Carp, Oana, Carolien L. Huisman, and Armin Reller. "Photoinduced reactivity
    of titanium dioxide." Progress in solid state chemistry 32.1 (2004): 33-177.
    [25].垰田博史著,張晶、楊健譯,光觸媒圖解, 商周出版,(2003).
    [26].呂宗昕、吳偉宏, “奈米科技與二氧化鈦光觸媒,” [線上]. Available:
    http://203.145.193.110/NSC_INDEX/Journal/EJ0001/9304/9304-10.pdf.
    [27].Grätzel, Michael. "Photoelectrochemical cells." Nature 414.6861 (2001):
    338-344.
    [28].Miyauchi, Masahiro, et al. "Photocatalysis and photoinduced hydrophilicity of
    various metal oxide thin films." Chemistry of Materials 14.6 (2002):
    2812-2816.
    [29].Fu, H., Xu, T., Zhu, S., & Zhu, Y. "Photocorrosion inhibition and enhancement
    of photocatalytic activity for ZnO via hybridization with C60." Environmental
    science & technology42.21 (2008): 8064-8069.
    [30].Yu, J. C., Yu, J., Ho, W., & Zhao, J. "Light-induced super-hydrophilicity and
    photocatalytic activity of mesoporous TiO2 thin films." Journal of
    Photochemistry and photobiology A: Chemistry 148.1 (2002): 331-339.
    [31].Fujishima, Akira, Tata N. Rao, and Donald A. Tryk. "Titanium dioxide
    photocatalysis." Journal of Photochemistry and Photobiology C:
    Photochemistry Reviews 1.1 (2000): 1-21.
    [32].呂怡萱. "二氧化鈦奈米管於染料敏化太陽能電池之探討." 中央大學化學系
    學位論文 (2006): 1-161.
    [33].高濂、鄭珊、張青红, 奈米光觸媒, 台北市:五南圖書出版股份有限公司,
    (2004).
    [34]. Watson, S. S., Beydoun, D., Scott, J. A., & Amal, R. "The effect of preparation
    method on the photoactivity of crystalline titanium dioxide
    particles." Chemical Engineering Journal 95.1 (2003): 213-220.
    [35].Mills, Andrew, Soo-Keun Lee, and Anne Lepre. "Photodecomposition of ozone
    sensitised by a film of titanium dioxide on glass." Journal of Photochemistry
    and Photobiology A: Chemistry 155.1 (2003): 199-205.
    [36].Hoffmann, M. R., Martin, S. T., Choi, W., & Bahnemann, D. W.
    "Environmental applications of semiconductor photocatalysis." Chemical
    reviews 95.1 (1995): 69-96.
    [37].Chakrabarti, Sampa, and Binay K. Dutta. "Photocatalytic degradation of model
    textile dyes in wastewater using ZnO as semiconductor catalyst." Journal of
    Hazardous Materials 112.3 (2004): 269-278.
    [38].Sleiman, M., Vildozo, D., Ferronato, C., & Chovelon, J. M. "Photocatalytic
    degradation of azo dye Metanil Yellow: optimization and kinetic modeling
    using a chemometric approach."Applied Catalysis B: Environmental 77.1
    (2007): 1-11.
    [39].田民波. 薄膜技術與薄膜材料, 台北市: 五南圖書出版股份有限公司
    (2007).
    [40].白木, 靖寬, 吉田, 真史, 金原粲, & 王建義. 薄膜工程學. 全華科技出版
    社, 台灣. (2004).
    [41].陳光華、鄧金祥, 奈米薄膜技術與應用, 台北市: 五南圖書出版股份有限公
    司, (2005).
    [42].Hague, Douglas C., and Merrilea J. Mayo. "Controlling crystallinity during
    processing of nanocrystalline titania." Journal of the American Ceramic
    Society77.7 (1994): 1957-1960.
    [43].柯賢文, 表面與薄膜處理技術, 台北市: 全華圖書, (2008).
    [44].林國海,“以水熱法探討奈米級α-Al2O3 披覆氫氧基之研究,”成功大學資
    源工程學系學位論文 , pp. 1-63, 2005.
    [45].葉翳民,“電沉積光電薄膜與檢測,校外講師課程,”[線上]. Available:
    http://wenku.baidu.com/view/d02b92d8a58da0116c174903.html. [存取日期: 13 05 2014].

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