研究生: |
蕭靜瑜 Hsiao, Ching-Yu |
---|---|
論文名稱: |
披覆不同貴金屬對單原子針發射電子束的研究 Study of emission electron beams in single atom tips depositing different noble metals |
指導教授: |
傅祖怡
Fu, Tsu-Yi 黃英碩 Hwang, Ing-Shouh |
學位類別: |
碩士 Master |
系所名稱: |
物理學系 Department of Physics |
論文出版年: | 2018 |
畢業學年度: | 106 |
語文別: | 中文 |
論文頁數: | 51 |
中文關鍵詞: | 場發射 、單原子針 、同調電子束 |
英文關鍵詞: | Field emission, single-atom tip, coherent electron beams |
DOI URL: | http://doi.org/10.6345/THE.NTNU.DP.017.2018.B04 |
論文種類: | 學術論文 |
相關次數: | 點閱:131 下載:17 |
分享至: |
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報 |
單原子針可應用在同調繞射電子顯微鏡。本研究針對鋪覆金、銥、鉑、銠、鈀五種貴金屬單原子針的場發射電子電流的大小及電流穩定性進行比較研究發現,以覆銥鎢針的場發射電流最大。在外加負高壓下可測量到超過1nA的電子電流,在1nA的電子電流下做電流對時間的穩定測量,其不穩定性大約10%;在1nA以下的電流不穩定性皆低於1%。 以覆銥鎢針場發電流大且穩定的優點,最適合進一步應用使用。
從Fowler-Nordheim分析中討論場發射特性,雖然覆鉑鎢針Fowler-Nordheim plot的斜率較小,但其場發射電流小且不穩定,在目前狀況下不適合往後的實驗研究中使用。本實驗也針對鋪覆貴金屬鎢針做照射綠光雷射的探討,初步結果顯示照射雷射並不會使場發射電流更大或更穩定。
The single-atom tip is a good candidate for coherence diffraction electron microscope. This research compared the field emission electron current, and current stability of noble metals deposition on single-atom tips, specifically those of gold (Au), iridium (Ir), platinum (Pt), rhodium (Rh), and palladium (Pd). At negative high voltage, the field emission current of Ir deposited W tip was the largest. The current instability is about 10% with emission current of over 1nA; below 1nA the instability was less than 1%. In the presence of Ir deposits, the slope of Fowler-Nordheim plot was noticeably reduced. Furthermore, its emission current was large and stable, which promotes its suitability for further application. Based on the Fowler-Nordheim analysis, the Pt-deposited W tip had the gentler slope. Due to its small and unstable field emission current, it is not suitable for use in future experimental studies. This research also investigated the effect of laser on single-atom tips with different noble metal deposits. Initial result showed that irradiation did not make the field emission current larger or more stable.
[1]Jianwei Miao, Tetsuya Ishikawa, Ian K. Robinson, Margaret M. Murnane,Beyond crystallography: Diffractive imaging using coherent x-ray light sources, Science 348, 530 (2015)
[2]郭鴻曦、黃英碩、傅祖怡、鄭天佐,物理雙月刊29(2007)1
[3]單原子電子源與離子源之應用,科儀新知31(2009)2
[4]郭鴻曦、黃英碩、張哲誠、鄭天佐傅祖怡、吳俊毅,修正數理科學18(2005)1-31
[5]T. Y. Fu, C. Cheng, C. H. Nien, and T. T. Tsong, Phys. Rev. B, 64(2001) 113401
[6]H.S. Kuo, I. S.Hwang, T. Y. Fu, J. Y. Wu, C. Chang, and T. T. Tsong, Nano Lett.,4 (2004)2379
[7]E. Rokuta, T. Itagaki,D. Miura,T. Moriyama,T. Ishikawa,B.L. Cho,T.Y. Fu,T.T. Tsong, C.Oshima“Atomic-scale field emitter with self-repairable function and thermodynamically stable structure: FEM study on Pd-covered nanopyramids on W tips” Applied Surface Science 251 (2005) 205
[8]Chang C-C, Kuo H-S, Tsong T T and Hwang I-S , “A fully coherent electron beam from a noble-metal covered W(111)single-atom emitter” , Nanotechnology.20 (2009) 115401
[9] I. S. Hwang, H. S. Kuo, C. C. Chang, and T. T. Tsong, Noble-Metal Covered W(111) Single-Atom Electron Sources, 157(2010)7
[10] Fowler, Ralph Howard, and L. Nordheim. “Electron emission in intense electric fields.”Proceedings of the Royal Society of London. Series A, Containing Papers of a Mathematical and Physical Character (1928)
[11]Che, J. G., et al. “Faceting induced by ultrathin metal films: A first principles study.” Phys. Rev. Lett.79 (1997) 21
[12]Szczepkowicz, Andrzej, et al. “A comparison of adsorbate-induced faceting on flat and curved crystal surfaces.”Surface science 599 (2005) 1
[13]Tsong, Tien T. “Atom-Probe Field Ion Microscopy: Field Ion Emission, and Surfaces and Interfaces at Atomic Resolution.”Cambridge University Press,(2005)
[14]侯勁龍,“覆鈀鉭針之皺化結構研究.” 國立台灣師範大學碩士論文(2008)
[15] 陳晏清,“鋪覆超薄膜於針狀金屬表面之現象研究”,國立台灣師範大學碩士論文(2011)
[16]林砡君,“覆銠、銥於鎢針上產生的皺化行為及其相關研究”,國立台灣師範大學碩士論文(2005)
[17]白家瑞,“以場離子顯微鏡進行覆鉑及覆鈀單原子級針尖的研究”,國立台灣師範大學碩士論文(2011)
[18] E. W. Müller, T. T. Tsong, “Field Ion Microscopy Principles and Applications”,American Elsevier Publishing Company(1969)
[19]蘇冠宇,“場離子顯微鏡研究(1)量測覆銥單原子針場發射與場離子電流(2)鈮(100)表面觀察.”國立台灣師範大學碩士論文(2011)
[20]李育賢,“以蝕刻吸附法備製覆銥鎢單原子級針尖與場發射電子電流量測.”國立台灣師範大學碩士論文(2009)
[21]M.K. Miller, G.D.W. Smith, Atom Probe Microanalysis (Published by the Materials Research Society, Pittsburgh,Pennsylvania,1989)
[22]J.P.Ibe, P.P.Bey, S.L.Brandow, R.A.Brizzolara, N.A.Burnham, D.P.DiLella, K.P.Lee, Richard J Colton, and C.R.K.Marrian, On the electrochemical etching of tips for scanning tunneling microscopy, J.Vac.Sci. Technol. A,8,3570(1990)
[23]游宇豐, “吸附氣體在鈮(100)切面上功函數與場發射電流穩定性的量測.”國立台灣師範大學碩士論文(2015)
[24] G. Schütz, A. Rembold, A. Pooch, S. Meier, P. Schneeweiss, A. Rauschenbeutel, A. Günther, W.T. Chang, I.S. Hwang, A. Stibor, Ultramicroscopy 141 (2014) 9
[25]H.S. Kuo, I.S. Hwang, T.Y. Fu, Y.C. Lin, C.C. Chang, T.T. Tsong, Jpn. J. Appl. Phys. 45 (2006) 8972
[26] Ultrafast Electron Emission from a Sharp Metal Nanotaper Driven by Adiabatic Nanofocusing of Surface Plasmons, Nano Lett.(2015)