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Author: 呂沛儒
Lu, Pei-Ju
Thesis Title: 鋁金屬有機骨架在酸鹼溶液處理下晶態轉變之研究
Research on revealing the crystalline state transformation of Al-based metal organic frameworks under treatments of acidic and basic solutions
Advisor: 林嘉和
Lin, Chia-Her
Committee: 楊仲準
Yang, Chun-Chuen
蔡振彥
Tsai, Chen-Yen
蔡明剛
Tsai, Ming-Kang
林嘉和
Lin, Chia-Her
Approval Date: 2024/06/03
Degree: 碩士
Master
Department: 化學系
Department of Chemistry
Thesis Publication Year: 2024
Academic Year: 112
Language: 中文
Number of pages: 143
Keywords (in Chinese): 金屬有機骨架雙溶劑置換加熱抽真空
Keywords (in English): Metal-Organic Framework, Two Solvent Exchange, Heat Under Vacuum
Research Methods: 實驗設計法
DOI URL: http://doi.org/10.6345/NTNU202400703
Thesis Type: Academic thesis/ dissertation
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謝辭 i 摘要 ii Abstract iii 目次 v 表目次 vii 圖目次 ix 第一章 緒論 1 1-1 MOF介紹 1 1-2 MOF的自組裝 4 1-3 Al-MOF簡介 8 1-4 MOF缺陷、活化與結晶性 16 1-5 MOF在水相中的穩定度 23 1-6研究動機 25 第二章 實驗與儀器 27 2-1 實驗藥品 27 2-2 儀器設備 29 2-3 實驗合成方法 33 第三章 結果與討論 39 第一部分 MOF快速自組裝合成探討 39 3-1 MOF快速自組裝-粉末X光繞射(PXRD)鑑定 39 3-2 MOF快速自組裝-場發式掃描電子顯微鏡(FE-SEM)鑑定 44 3-3 MOF快速自組裝-比表面積及孔隙分析儀鑑定 47 3-4 MOF快速自組裝-熱穩定性(TGA)鑑定 63 第二部分 酸鹼水溶液下MOF的穩定度探討 67 3-5 浸泡酸鹼水溶液-粉末X光繞射(PXRD)鑑定 67 3-6 浸泡酸鹼水溶液-場發式掃描電子顯微鏡 (FE-SEM)鑑定 102 3-7 浸泡酸鹼水溶液-比表面積及孔隙分析儀鑑定 108 3-8 浸泡酸鹼水溶液-熱穩定性(TGA)鑑定 128 3-9 浸泡酸鹼水溶液-傅立葉轉換紅外線光譜儀(FTIR)鑑定 133 3-10 浸泡酸鹼水溶液-固態核磁共振光譜儀鑑定 134 第四章 結論 135 參考文獻 137 附錄 141

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