Author: |
陳永昌 Chen, Yung-Chang |
---|---|
Thesis Title: |
I. 經有機膦催化誘導4-亞芳基吡唑酮和5-亞芳基噻唑酮的β-醯化反應
II. 鹼催化2-羥基亞胺葉立德與2-羥基亞芳基噻唑酮經由1,3-偶極體環化/分子內環化反應合成螺環𠳭酮[3,4-b]吡咯啶 I. Organophosphane-Catalyzed Direct β-Acylation of 4-Arylidene Pyrazolones and 5-Arylidene Thiazolones with Acyl Chlorides II. Base-Catalyzed Construction of Spirochromeno[3,4-b]pyrrolidines via 1,3-Dipolar Cycloaddition/Intramolecular Annulation of 2-Hydroxy Azomethine Ylides with 2-Hydroxyarylidene Thiazolones |
Advisor: |
林文偉
Lin, Wen-Wei |
Committee: |
陳焜銘
Chen, Kwun-Min 劉維民 Liu, Wei-Min |
Approval Date: | 2021/06/24 |
Degree: |
碩士 Master |
Department: |
化學系 Department of Chemistry |
Thesis Publication Year: | 2021 |
Academic Year: | 109 |
Language: | 中文 |
Number of pages: | 329 |
Keywords (in Chinese): | β-碳醯化反應 、非金屬有機膦催化反應 、立體專一性 、一鍋化反應 、4-亞芳基吡唑酮 、5-亞芳基噻唑酮 、螺環𠳭酮[3,4-b]吡咯啶 、有機鹼催化反應 、1,3-偶極體環化加成反應 、連鎖反應 、2-羥基亞胺葉立德 、2-羥基亞芳基噻唑酮 |
Keywords (in English): | Beta-C-acylation, organophosphane catalysis, stereospecificity, one-pot reaction, 4-arylidene pyrazolones, 5-arylidene thiazolones, thiazolone spirochromeno[3,4-b]pyrrolidines, organobase-catalyzed, cascade 1,3-dipolar cycloaddition, lactonization, 2-hydroxyl azomethine ylides, 2-hydroxyarylidene thiazolones |
Research Methods: | 實驗設計法 、 行動研究法 、 準實驗設計法 、 參與觀察法 、 觀察研究 、 現象分析 |
DOI URL: | http://doi.org/10.6345/NTNU202100692 |
Thesis Type: | Academic thesis/ dissertation |
Reference times: | Clicks: 110 Downloads: 0 |
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