研究生: |
馬康耀 Ma, Kang-Yao |
---|---|
論文名稱: |
利用雷射對富勒烯/二硫化鉬異質結構的效應雕製微觀圖形 Laser-induced effects in C60/MoS2 heterostructure: desorption and patterned photo-luminance |
指導教授: |
林文欽
Lin, Wen-Chin |
學位類別: |
碩士 Master |
系所名稱: |
物理學系 Department of Physics |
論文出版年: | 2020 |
畢業學年度: | 108 |
語文別: | 中文 |
論文頁數: | 51 |
中文關鍵詞: | 富勒烯 、拉曼 、雷射 、二硫化鉬 |
英文關鍵詞: | Desorption |
DOI URL: | http://doi.org/10.6345/NTNU202001255 |
論文種類: | 學術論文 |
相關次數: | 點閱:154 下載:7 |
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本次實驗的內容主要在探討,成長於二氧化矽(SiO2)基板上的二硫化鉬(MoS2)與C60組合而成的樣品,在綠光雷射下的拉曼效應(Raman effect)以及光致發光(Photoluminescence PL)的結果,以及其表面形貌;並且藉由改變不同雷射功率,觀察C60的脫附現象(desorption)。
樣品的製備為利用化學氣象沉積(CVD)在二氧化矽(SiO2)基板上沉積出二硫化鉬(MoS2)薄膜,再利用超高真空鍍膜技術將C60鍍上;利用原子力顯微鏡(AFM)與拉曼效應、光致發光光譜分析對C60/MoS2樣品的表面結構以及半導體性質進行量測。實驗結果發現,改變不同的雷射功率,以及照射時間,可以對C60的光致發光特徵峰造成影響,進而探討雷射對C60造成的脫附現象;實驗中發現使用波長532 nm功率 5 mW的雷射以1分鐘與6分鐘的照射時間,分別可以使樣品造成
C60的PL峰值以及MoS2的PL峰值的下降,並利用此現象對C60/MoS2異質結構進行微觀圖形的雕製。
In this study, we deposited C60 films on MoS2 flakes, and investigated the morphology, Raman spectrum and photoluminescence spectrum to study the laser-induced desorption effect on the C60/MoS2 heterostructure. The MoS2 flakes were fabricated on SiO2/Si(100) substrates by using chemical vapor deposition, and the C60 thin film was deposited on the MoS2 flakes by e-beam evaporation.
By atomic force microscope We found the relationship between the laser power and the surface height of both MoS2 flakes and C60/MoS2 heterostructure. Furthermore, we found that a hole formed on the C60 surface by laser-induced desorption effect. In the photoluminescence spectroscopy analysis, the characteristic peak of C60 also decreased by Increasing the laser irradiation time.
Finally, through using laser-induced desorption effect, we chose 532 nm laser with power of 5 mW( irradiation time is 1 and 6 min), And we can make the patterns with 4 kinds of photoluminescence waveform on the MoS2/C60 heterostructure.
參考文獻
[1] Wikipedia-Graphene
https://en.wikipedia.org/wiki/Graphene
[2] Gianluca Fiori, Francesco Bonaccorso, Giuseppe Iannaccone, Tomás Palacios, Daniel Neumaier, Alan Seabaugh, Sanjay K. Banerjee & Luigi Colombo. “Electronics based on two-dimensional materials “ Nature Nanotechnology volume 9,768-779 (2014)
[3] Zong-You Lin “Magnetic decoupling of ferromagnetic coverage across atomic step of MoS2 flakes on SiO2 surface” 國立臺灣師範大學 (2018)
[4] G. Chen, R. G. Cookscor, E. Corpuz & L. T. Scott “Estimation of the electron affinities of C60, corannulene, and coronene by using the kinetic method” Journal of the American Society for Mass Spectrometry volume 7, 619–627 (1996)
[5] 徐凱霖 “Hybridization-Induced XMCD of Carbon in Fe-C60 Composite Thin Films” 國立臺灣師範大學 (2017)
[6] R.W. Lof, M.A. Vanveenendaal, B. Koopmans, H.T. Jonkman, G.A. Sawatzky, “Band-gap, excitons, and Coulomb interaction in solid C60” Phys. Rev. Lett. 68
3924–3927 (1992)
[7] A. Castellanos-Gomez, M. Barkelid, A. M. Goossens, V. E. Calado, H. S. J. van der Zant, and G. A. Steele. “Laser-Thinning of MoS2: On Demand Generation of a Single-Layer Semiconductor” Nano Lett. 12, 6, 3187–3192 (2012)
[8] Science - Buckminsterfullerene Diamond-like Carbon Carbon Nanotube https://favpng.com/png_view/science-buckminsterfullerene-diamond-like-carbon-carbon-nanotube-png/3zrhpcxQ
[9] Shabbir Muhammad, Hong-Liang Xu, Rong-Lin Zhong, Zhong-Min Su, Abdullah G. Al-Sehemi and Ahmad Irfan. “Quantum chemical design of nonlinear optical materials by sp2-hybridized carbon nanomaterials: issues and opportunities” J. Mater. Chem. C, 1, 5439-5449 (2013)
[10] Chuan-Che Hsu, Zong-You Lin, Po-Chun Chang, Hsiang-Chih Chiu, Hsiao-Wen Chen, Hsiang-Lin Liu, Francesco Bisio and Wen-Chin Lin. “Magnetic decoupling of Fe coverage across atomic step of MoS2 flakes on SiO2 surface” J. Phys. D: Appl. Phys. 50 415001 (2017)
[11] Ossila Molybdenum Disulfide Powders and Solutions
https://www.ossila.com/products/molybdenum-disulfide-powders-and-solutions?variant=30651324225
[12] Wikipedia-Vacuum
https://en.wikipedia.org/wiki/Vacuum
[13] Wikipedia-Raman spectroscopy https://en.wikipedia.org/wiki/Raman_spectroscopy
[14] Wikipedia-Photoluminescence https://en.wikipedia.org/wiki/Photoluminescence
[15] 中文百科-間接帶隙半導體https://www.newton.com.tw/wiki/%E9%96%93%E6%8E%A5%E5%B8%B6%E9%9A%99%E5%8D%8A%E5%B0%8E%E9%AB%94
[16] Felix Nworie (Ebonyi State University • Department of Industrial Chemistry)
https://www.researchgate.net/figure/Diagram-of-Raman-spectrophotometer-Adapted-from-24b_fig1_282422385
[17] AFM - Atomic Force Microscope Physics 111B: Advanced Experimentation Laboratory University of California, Berkeley http://experimentationlab.berkeley.edu/sites/default/files/writeups/AFM.pdf
[18] Renata Lewandowska “Number of layers of MoS2 determined using Raman Spectroscopy” HORIBA Scientific, 231,59650
[19] M. J. Matthews, M. A. Pimenta, G. Dresselhaus, M. S. Dresselhaus, and M. Endo “Origin of dispersive effects of the Raman D band in carbon materials” Phys. Rev. B 59, R6585 (1999)
[20] Franco Cataldo, Giovanni Strazzulla, Susana Iglesias-Groth, “Stability of C60 and C70 fullerenes toward corpuscular and γ radiation” Monthly Notices of the Royal Astronomical Society. 394,615 (2009)
[21] Fei Chen, Lei Wang, Ting Wang, and Xiaohong Ji “Enhanced local photoluminescence of a multilayer MoS2 nanodot stacked on monolayer MoS2 flakes” Optical Materials Express 7,1365-1373 (2017)
[22] Bowen Liu,Zhe Zhang, Kan Liao, Rong Wu , Chao Zhu , Hongguang Xie , Chenyang Zha , Yao Yin , Xiaohong Jiang , Sichen Qin, Wei Wang, Gang Ouyang, Tianshi Qin , Lin Wang, Wei Huang “Tuning optical properties of monolayer MoS2 through the 0D/2D interfacial effect with C60 nanoparticles” Applied Surface Science 523, 146371 (2020)