研究生: |
游宇豐 Yu, Yu-Fong |
---|---|
論文名稱: |
吸附氣體在鈮(100)切面上功函數與場發射電流穩定性的量測 Measurement of workfunction and instability of field emission current of adsorbing inert gas on Nb(100) |
指導教授: |
傅祖怡
Fu, Tsu-Yi 黃英碩 Hwang, Ing-Shouh |
學位類別: |
碩士 Master |
系所名稱: |
物理學系 Department of Physics |
論文出版年: | 2015 |
畢業學年度: | 103 |
語文別: | 中文 |
論文頁數: | 81 |
中文關鍵詞: | 場發射 、鋪覆氣體 、鈮針 |
英文關鍵詞: | field emission, adsorption gases, niobium |
論文種類: | 學術論文 |
相關次數: | 點閱:169 下載:3 |
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我們利用電化學蝕刻方法蝕刻純鈮針,製作出針徑接近50nm以內的針尖後置入超高真空中,經過反覆加熱退火處理得到一熱穩態結構,此結構為四個{310}皺化擠壓{100}切面。
我們利用惰性氣體(Xe、Ne)給予腔體不同的鋪覆環境,再量測由純鈮{100}切面發射出來的電流與施加的偏壓去繪出FN圖,再由FN圖上斜直線斜率經計算後得到鈮{100}的表面功函數。
發現鋪覆此兩種氣體後,鈮{100}切面的表面功函數會下降,下降幅度會隨著鋪覆的環境而變化,兩種氣體有所謂的最佳鋪覆環境,而在最佳鋪覆環境下的鈮{100}表面功函數會有最大的下降幅度,經過三次實驗的統計結果顯示在最佳鋪覆環境下,鈮{100}面鋪覆Xe後的表面功函數下降幅度比鋪覆Ne明顯。
並且我們量測純鈮{100}切面在最佳鋪覆環境下場發射電流三十分鐘後的穩定性,我們調控場偏壓、平均電流並觀察穩定性上的變化,發現純鈮{100}面的發射電流穩定性沒有比鋪覆Xe在最佳鋪覆環境下的電流穩定。
We fabricate a thermally stable pure niobium tip with a small (100) facet faceting structure surrounded by four {310} surfaces by thermal treatment in UHV.
We observe the thermally stable structure by field ion microscopy (FIM) and measure field emission current from the niobium (100) facet with a Faraday cup. After exposing the tips under various gas (Ne, Xe) environments(1 Langmuir), we measure the emission currents at various applied voltages. Variation of field-emission work functions due to different absorption gases can be observed from the illustrated F-N plots. We find Xe gas noticeably reduces the work function of the niobium (100) facet.
We measure stability of the field emission current from niobium {100} facet with Faraday cup in 30 minunits.
[1] 郭鴻曦、黃英碩、傅祖怡、鄭天佐,物理雙月刊29(2007)1
[2] 單原子電子源與離子源之應用,科儀新知31(2009)2
[3] 傅祖怡、吳俊毅、郭鴻曦、黃英碩、張哲誠、鄭天佐,修正數理科學18(2005)1-31
[4]T. Y. Fu, l. C. Cheng, C. H. Nien, and T. T. Tsong, Phys. Rev. B, 64(2001) 113401
[5] H.-S. Kuo, I.-S.Hwang, T. –Y. Fu, J. –Y. Wu, C.-C. Chang, and T. T. Tsong, NANO Lett.,4 (2004)2379
[6] Chang C-C, Kuo H-S, Tsong T T and Hwang I-S , “A fully coherent electron
beam from a noble-metal covered W(111)single-atom emitter” ,Nanotechnology Nanotechnology.20 (2009) 115401
[7] I.-S. Hwang,H.-S. Kuo, C.-C. Chang, and T. T. Tsong, Noble-Metal Covered W(111) Single-Atom Electron Sources, 157(2010)7-12
[8]Gadzuk, J. W. “Many-body tunneling-theory approach to field emission of electrons from solids,Surface Science”15(1969) 3
[9] K. Nagaoka, T. Yamashita, M. Yamada, H. Fujii, R. Seo, K. Matsuda,S. Uchiyama, C. Oshima , Field emission energy spectra from superconducting and normal states of a niobium tip ,Ultramicroscopy 79 (1999) 51-57
[10] Y. Uehara , T. Fujita, M. Iwami, S. Ushioda , Single NbO nano-crystal formation on low temperature annealed Nb(0 0 1) surface , Surface Science 472 (2001) 59-62
[11] Ryota Shimizu, Taro Hitosugi, Tomihiro Hashizume, Noritaka Fukuo, and Tetsuya Hasegawa ,Preparation of Superconducting Niobium Tips for Atomic-ResolutionScanning Tunneling Microscopy/Spectroscopy,
Japanese Journal of Applied Physics 49 (2010) 028004
[12] Nagaoka, T. Yamashita, S. Uchiyama, M. Yamada, H. Fujii & C. Oshima, Monochromatic electron emission from the macroscopic quantum state of a superconductor,K,Nature 396 (1998) 557-559
[13] G.Oxinos and A.Modinos ,The polarization of physisorbed inert atoms due to the short range interaction with the metal substrate , , Surface Science 89 (1979) 292-303
[14] Fowler, Ralph Howard, and L. Nordheim. “Electron emission in intense electric fields.”Proceedings of the Royal Society of London. Series A, Containing Papers of a Mathematical and Physical Character (1928)
[15] Che, J. G., et al. “Faceting induced by ultrathin metal films: A first principles study.” Physical review letters 79 (1997) 21
[16] 陳晏清,“鋪覆超薄膜於針狀金屬表面之現象研究”,國立台灣師範大學碩士論文(2011)
[17] E. W. Müller , T. T. Tsong, “Field Ion Microscopy Principles and Applications”,American Elsevier Publishing Company(1969)
[18] Szczepkowicz, Andrzej, et al. “A comparison of adsorbate-induced faceting on flat and curved crystal surfaces.”Surface science 599 (2005) 1
[19] Tsong, Tien T. “Atom-Probe Field Ion Microscopy: Field Ion Emission, and Surfaces and Interfaces at Atomic Resolution.”Cambridge University Press,(2005)
[20] 侯勁龍,“覆鈀鉭針之皺化結構研究.” 國立台灣師範大學碩士論文(2008)
[21] 林砡君,“覆銠、銥於鎢針上產生的皺化行為及其相關研究”,國立台灣師範大學碩士論文(2005)
[22] Che, J. G., et al. “Faceting induced by ultrathin metal films: A first principles study.” Physical review letters 79 (1997) 21
[23] Tsong, Tien T. “Field Ion Emission, and Surfaces and Interfaces at Atomic Resolution.”Cambridge University,(2005)
[24] 蘇冠宇,“場離子顯微鏡研究(1)量測覆銥單原子針場發射與場離子電流(2)鈮(100)表面觀察.”國立台灣師範大學碩士論文(2011)
[25] E. W. Muller, T. T. Tsong, “Field Ion Microscopy Principles and Applications”,American Elsevier Publishing Company(1969)
[26] Nakamura, Shogo,“Field Evaporation of Metals in Field Ion Microscope.”Journal of Electron Microscopy 15 (1966) 4
[27] 李育賢,“以蝕刻吸附法備製覆銥鎢單原子級針尖與場發射電子電流量測.”國立台灣師範大學碩士論文(2009)
[28] 石智強,“溫度與吸附氣體對鈮針場發射特性的影響.”國立台灣師範大學碩士論文(2014)
[29]GH.T ahmasebipour. Y.Hojjat, V. Ahmadi.and A.Abduallah, Scanning,31(2009)2
[30] J.C. Slater, 《化學物理期刊》(J. Chem. Phys)41(1964)3199
[31] E. Clementi, D.L.Raimondi, 和 W.P. Reinhardt, 《化學物理期刊》(J. Chem. Phys)38(1963)2686