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研究生: 王銘義
Wang, Ming-Yi
論文名稱: 以雷射誘發結晶在旋轉塗佈法中來提升鹵化物全無機鈣鈦礦發光二極體之效率
Enhancement of the Efficiency of Halide Perovskite Light-Emitting Diodes by Laser-Induced Nucleation in the Spin-Coating Process
指導教授: 陳賜原
Chen, Szu-Yuan
林皓武
Lin, Hao-Wu
李君婷
Li, Chun-Ting
學位類別: 碩士
Master
系所名稱: 化學系
Department of Chemistry
論文出版年: 2020
畢業學年度: 108
語文別: 中文
論文頁數: 85
中文關鍵詞: 鈣鈦礦發光二極體全無機金屬鹵化物鈣鈦礦溶液製程反溶解度旋轉塗佈法
英文關鍵詞: Perovskite light-emitting diodes, All-inorganic metal halide perovskite, Spin coating, Solution process, Inverse solubility
DOI URL: http://doi.org/10.6345/NTNU202001430
論文種類: 學術論文
相關次數: 點閱:67下載:13
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  • 鈣鈦礦發光二極體具有製作成本低廉、製作快速、高量子效率、色域寬廣且放光波長固定等優點,再加上其外部量子效率的發展在十年間與其他發光二極體達到相同技術水準,使得鈣鈦礦發光二極體有機會取代其他技術,應用在新一代照明與顯示器。本研究透過鈣鈦礦的反溶解度特性,在旋轉塗佈法的過程中引入雷射,試圖透過雷射豐富的可控制參數,讓底部ITO (Indium tin oxide) 能在特定時間升溫、結晶,以解決過往在旋轉塗佈法中不易控制的成膜與結晶問題,改變鈣鈦礦形貌與結晶性,進而提升發光二極體之亮度與效率。本研究使用各種添加物找出其對鈣鈦礦的影響,並優化發光二極體各層之形成條件,解決過去實驗漏電流與低發光亮度的問題,接著找出部分造成元件不穩定的因素,最後在優化過的雷射條件下,使鈣鈦礦發光二極體發光亮度最多提升至4倍,而相較於實驗室學長的實驗結果,最大亮度也上升20~50倍。

    Perovskite light-emitting diodes (PeLEDs) have the advantage of low-cost, wide color gamut, narrow emission line-widths, and high quantum efficiency. PeLEDs have promising potential owing to their external quantum efficiency reach the same level as other LED within a decade. To enhance the performance of PeLEDs, we overcome the issue of morphology controlling in the spin coating process. Specifically, based on the inverse solubility of the perovskite, we use a laser as a heating source to control the nucleation and crystallization. Furthermore, we optimized the preparation condition in each layer of the PeLEDs to solve the problem of low brightness and leakage current. In summary, the luminance of PeLEDs increased up to 3~4 times comparing to the light-emitting diodes without a laser. Maximum luminance of deivice increased up to 20~50 times comparing with the result made by the senior in our lab.

    第1章、緒論 1 1.1、照明光源的進展 1 1.2、發光二極體 2 1.3、鈣鈦礦的發展與目標 2 1.4、鈣鈦礦發光二極體 4 1.4.1、鈣鈦礦發光二極體的優勢與挑戰 4 1.4.2、鈣鈦礦發光二極體重要文獻回顧 7 1.5、研究目標 11 第2章、實驗材料、量測與元件製程 12 2.1、元件設計 12 2.2、鈣鈦礦層製作方法 14 2.3、實驗材料 15 2.4、實驗儀器 18 2.4.1、近紅外光光纖雷射 (Fiber laser) 18 2.4.2、手套箱 (Glove box) 19 2.4.3、旋轉塗佈機 20 2.4.4、氧電漿機 (O2 plasma) 23 2.4.5、紫外光/臭氧 改質 (UV/O3 reforming ) 23 2.4.6、X射線繞射儀 (X-ray diffractometer,XRD) 24 2.4.7、掃描式電子顯微鏡 (Scannning electron microscopy,SEM) 25 2.4.8、真空蒸鍍機 (Thermal evaporation coater) 26 2.4.9、聚焦離子束 (Focus ion beam,FIB) 27 2.4.10、穿透式電子顯微鏡 (Transmission electron microscope,TEM) 28 2.6、元件製程與封裝 29 2.6.1、配置溶液 30 2.6.2、清洗基板 30 2.6.3、基板改質與PEDOT:PSS成膜 32 2.6.4、定義主動層與熱退火 33 2.6.5、主動層成膜(包含鈣鈦礦層、絕緣層與電子傳輸層) 33 2.6.6、陰極蒸鍍 35 2.6.7、元件封裝 35 2.7、元件性質量測 36 第3章、實驗結果與討論 38 3.1、各層優化與趨勢 38 3.1.1、優化純鈣鈦礦 38 3.1.2、優化TPBi 41 3.1.3、氧電漿處理PEDOT:PSS 46 3.1.4、清潔與定義主動區優化 49 3.2、鈣鈦礦層實驗結果 51 3.2.1、以MABr與BABr作為添加物 51 3.2.2、使用PMMA作為絕緣層 54 3.3、雷射對於鈣鈦礦層之影響 56 3.3.1、雷射加熱法:改變雷射加入鈣鈦礦的時機 58 3.3.2、雷射加熱法:改變雷射Intensity 60 3.3.3、雷射併用添加物 61 3.4、討論 66 3.4.1、鈣鈦礦不穩定 66 3.4.2、亮度隨著量測次數而逐漸上升 66 3.4.3、發光範圍不均之問題 67 第4章、 結論與未來展望 72 參考文獻 75 附錄A-1 80 附錄A-2 82 附錄A-3 83 附錄B:量測元件效能之Labview程式 85

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