1. Spitzer, F.; Sierka, M.; Latronico, M.; Mastrorilli, P.; Virovets, A. V.; Scheer, M. Angew. Chem., Int. Ed. 2015, 54, 4392–4396.
2. (a) Cossairt, B. M.; Cummins, C. C. J. Am. Chem. Soc. 2009, 131, 15501–15511. (b) Mirabello, V.; Caporali, M.; Gallo, V.; Gonsalvi, L.; Gudat, D.; Frey, W.; Ienco, A.; Latronico, M.; Mastrorilli, P.; Peruzzini, M. Chem. - Eur. J. 2012, 18, 11238–11250.
3. (a) Heinl, S.; Peresypkina, E. V.; Timoshkin, A. Y.; Mastrorilli, P.; Gallo, V.; Scheer M. Angew. Chem. Int. Ed. 2013, 52, 10887–10891. (b) Schwarzmaier, C.; Timoshkin, A. Y.; Scheer, M. Angew. Chem., Int. Ed. 2013, 52, 7600–7603.
4. (a) Santiso-Quiñones, G.; Reisinger, A.; Slattery, J.; Krossing, I. Chem. Commun., 2007, 5046–5048. (b) Schwarzmaier, C.; Sierka, M.; Scheer, M. Angew. Chem. Int. Ed. 2013, 52, 858–861.
5. Borger, J. E.; Bakker, M. S.; Ehlers, A. W.; Lutz, M.; Chris Slootwega, J.; Lammertsma, K. Chem. Commun., 2016, 52, 3284–3287.
6. (a) Peng, Y.; Fan, H.; Zhu, H.; Roesky, H. W.; Magull, J.; Hughes, C. E. Angew. Chem. Int. Ed. 2004, 43, 3443–3445. (b) Prabusankar, G.; Doddi, A.; Gemel, C.; Winter, M.; Fischer, R. A. Inorg. Chem. 2010, 49, 7976–7980.
7. Ganesamoorthy, C.; Krüger, J.; Wölper, C.; Nizovtsev, A. S.; Schulz, S. Chem. - Eur. J. 2017, 23, 2461–2468.
8. Dütsch, L.; Fleischmann, M.; Welsch, S.; Balázs, G.; Kremer, W.; Scheer, M. Angew. Chem. Int. Ed. 2018, 57, 3256–3261.
9. (a) CRITCHLOW, S. C.; CORBETT, J. D. Inorg. Chem. 1984, 23, 770–774. (b) Martin, T. M.; Schimek, G. L.; Pennington, W. T.; Kolis,Kolis, J. W. J. Chem. Soc., Dalton Trans. 1995, 501–502.
10. Whitmire, K. H. J. Am. Chem. Soc. 1985, 107, 1056–1057.
11. (a) Foust, A. S.; Dahl, L. F. J. Am. Chem. Soc. 1970, 17, 7337–7341. (b)
Konchenko, S. N.; Virovets, A. V.; Apenina, S. A.; Tkachev, S. V. Inorg. Chem. 1999, 2, 555–557.
12. Cherng, J.-J.; Lee, G.-H.; Peng, S.-M.; Ueng, C.-H.; Shieh, M. Organometallics 2000, 19, 213–215.
13. 謝明惠，李昱輝，未發表之結果。
14. (a)Dgtsch, L.; Fleischmann, M.; Welsch, S.; Balázs, G.; Kremer, W.; Scheerm, M. Angew. Chem. Int. Ed. 2018, 57, 3256–3261. (b)Mantina, M.; Chamberlin, A. C.; Valero, R.; Cramer, C. J.; Truhlar, D. G. J. Phys. Chem. A 2009, 113, 5806–5812.
15. Pipek, J.; Mezey, P. G. J. Chem. Phys.1989, 90, 4916–4926.
16. In Atoms in Molecules A Quantum Theory. Bader, R. F. W.; International Series of Monographs on Chemistry. 1994.
17. (a) Evans, D. F.; Fazakerley, G. V. and Phillips R. F. J. Chem. Soc. A, 1971, 0, 1931–1934. (b)http://www.wilmadlabglass.com/Support//NMR-and-EPR-Technical-Reports/NMR-007--Coaxial-Inserts-in-NMR-Studies/
18. Yea, D.-X.; Pimanpanga, S.; Jezewskib, C.; Tanga, F.; Senkevicha, J. J.; Wanga, G.-C.; Lua, T.-M. Thin Solid Films. 2005, 485, 95–100.
19. Anderson, P. W. Phys. Rev. 1950, 79, 350.
20. Mantina, M.; Chamberlin, A. C.; Valero, R.; Cramer, C. J.; Truhlar, D. G. J. Phys. Chem. A 2009, 113, 5806─5812.
21. In The Manipulation of Air-Sensitive Compounds; Shriver, D. F., Drezdon, M. A., Eds.; Wiley-VCH: New York, 1986.
22. (a) Kubas, G. J. Inorg. Synth. 1979, 19, 90. (b) Simmons, M. G.; Merrill, C. L.; Wilson, L. J.; Bottomley, L. A.; Kadish, K. M. J. Chem. Soc., Dalton Trans. 1980, 1827‒1837.
23. Devasagayaraj, A.; Periasamy, M. Transition Met. Chem., 1991, 16, 503‒504.
24. Sheldrick, G. M. A Short History of SHELX. Acta Cryst. 2008, A64, 112−122.
25. SADABS; Bruker AXS Inc.: Madison, WI, 2003.
26. Kubelka, P.; Munk, F. Ein Beitrag zür Optik der Farbanstriche. Z. Tech. Phys. 1931, 12, 593−601. (b) Tauc, J. Mater. Res. Bull. 1970, 5, 721−729.
27. Moulder, J. F., Stickle, W. F., Sobol, P. E., Bomben, K. D. Handbook of X-ray Photoelectron Spectroscopy; Chastin, J., King, R. C. Jr., Eds.; Physical Electronics:  Eden Prairie, MN, 1992.
28. Becke, A. D. Phys. Rev. A 1988, 38, 3098–3100. (b) Perdew, J. P. Phys. Rev. B 1986, 33, 8822–8824.
29. Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Scalmani, G.; Barone, V.; Petersson, G. A.; Nakatsuji, H.; Li, X.; Caricato, M.; Marenich, A. V.; Bloino, J.; Janesko, B. G.; Gomperts, R.; Mennucci, B.; Hratchian, H. P.; Ortiz, J. V.; Izmaylov, A. F.; Sonnenberg, J. L.; Williams-Young, D.; Ding, F.; Lipparini, F.; Egidi, F.; Goings, J.; Peng, B.; Petrone, A.; Henderson, T.; Ranasinghe, D.; Zakrzewski, V. G.; Gao, J.; Rega, N.; Zheng, G.; Liang, W.; Hada, M.; Ehara, M.; Toyota, K.; Fukuda, R.; Hasegawa, J.; Ishida, M.; Nakajima, T.; Honda, Y.; Kitao, O.; Nakai, H.; Vreven, T.; Throssell, K.; Montgomery, J. A.; Jr.,; Peralta, J. E.; Ogliaro, F.; Bearpark, M. J.; Heyd, J. J.; Brothers, E. N.; Kudin, K. N.; Staroverov, V. N.; Keith, T. A.; Kobayashi, R.; Normand, J.; Raghavachari, K.; Rendell, A. P.; Burant, J. C.; Iyengar, S. S.; Tomasi, J.; Cossi, M.; Millam, J. M.; Klene, M.; Adamo, C.; Cammi, R.; Ochterski, J. W.; Martin, R. L.; Morokuma, K.; Farkas, O.; Foresman, J. B.; Fox, D. J. Gaussian 16 , revision E.01; Gaussian, Inc., Wallingford CT, 2016.
30. Wiberg, K. B. Tetrahedron 1968, 24, 1083–1096.
31. Reed, A. E.; Weinstock, R. B.; Weinhold, F. Natural Population Analysis. J. Chem. Phys. 1985, 83, 735−746.
32. Weigend, F.; Ahlrichs, R. Phys. Chem. Chem. Phys. 2005, 7, 3297–3305.
33. Gorelsky, S. I. AOMix. http://www.sg-chem.net/.
1. (a) In Chemistry of Arsenic, Antimony and Bismuth; Norman, N. C., Ed.; Blackie Academic and Professional: London, 1998. (b) In Metal Clusters in Chemistry; Braunstein, P., Oro, L. A., Raithby, P. R., Eds.; Wiley-VCH: Weinheim, Germany, 1999. (c) In The Chemistry of Metal Cluster Complexes; Shriver, D. F., Kaesz, H. D., Adams, R. D., Eds.; Wiley: New York, 1990. (d) Jones, J. S.; Pan, B.; Gabbaï, F. P. In Molecular Metal-Metal Bonds: Compounds, Synthesis, Properties; Liddle, S. T., Ed.; Wiley-VCH: Weinheim, Germany, 2015; pp 519. (e) Whitmire, K. H. Coord. Chem. Rev. 2018, 376, 114−195 and references therein. (f) Gray, P. A.; Burford, N. Coord. Chem. Rev. 2016, 324, 1−16. (g) Raţ, C. I.; Silvestru, C.; Breunig, H. J. Coord. Chem. Rev. 2013, 257, 818−879. (h) Jones, C. Coord. Chem. Rev. 2001, 215, 151−169. (i) Schulz, S. Coord. Chem. Rev. 2001, 215, 1−37. (j) Balázs, L.; Breunig, H. J. Coord. Chem. Rev. 2004, 248, 603−621. (k) Balakrishna, M. S.; Eisler, D. J.; Chivers, T. Chem. Soc. Rev. 2007, 36, 650–664. (l) Turbervill, R. S. P.; Goicoechea, J. M. Chem. Rev. 2014, 114, 10807−10828. (m) Champness, N. R.; Levason, W. Coord. Chem. Rev. 1994, 133, 115−217. (n) Whitmire, K. H. Adv. Organomet. Chem. 1998, 42, 1−145 and references therein.
2. (a) Gudat, D. In Comprehensive Inorganic Chemistry II; Reedijk, J.; Poeppelmeier, K., Eds.; Elsevier: Oxford, 2013, Vol 1, pp 587−621. (b) Dostál, L. Coord. Chem. Rev. 2017, 353, 142–158 and references therein. (c) Ellis, B. D.; Macdonald, C. L. B. Coord. Chem. Rev. 2007, 251, 936–973. (d) Huttner, G.; Evertz, K. Acc. Chem. Res. 1986, 19, 406–413. (e) Breunig, H. J.; Balázs, L. Organometallics 2004, 23, 304–310. (f) Huttner, G. Pure Appl. Chem. 1986, 58, 585–596.
3. Waterman, R.; Tilley, T. D. Angew. Chem., Int. Ed. 2006, 45, 2926−2929. (b) Waterman, R.; Tilley, T. D. Chem. Commun. 2006, 4030–4032. (c) Vránová, I.; Alonso, M.; Jambor, R.; Růžička, A.; Erben, M.; Dostál, L. Chem. - Eur. J. 2016, 22, 7376–7380. (d) Kořenková, M.; Hejda, M.; Jirásko, R.; Block, T.; Uhlík, F.; Jambor, R.; Růžička, A.; Pöttgen, R.; Dostál, L. Dalton Trans. 2019, 48, 11912–11920. (e) Kořenková, M.; Kremláček, V.; Erben, M.; Jirásko, R.; de Proft, F.; Turek, J.; Jambor, R.; Růžička, A.; Císařová, I.; Dostál, L. Dalton Trans. 2018, 47, 14503–14514. (f) Kořenková, M.; Hejda, M.; Štěpnička, P.; Uhlík, F.; Jambor, R.; Růžička, A.; Dostál, L. Dalton Trans. 2018, 47, 5812–5822. (g) Vránová, I.; Kremláček, V.; Erben, M.; Turek, J.; Jambor, R.; Růžička, A.; Alonso, M.; Dostál, L. Dalton Trans. 2017, 46, 3556–3568. (h) Šimon, P.; Jambor, R.; Růžička, A.; Dostál, L. Organometallics 2013, 32, 239–248.
4. Cowley, A. H.; Norman, N. C.; Pakulski, M. J. Am. Chem. Soc. 1984, 106, 6844–6845. (b) von Seyerl, J.; Huttner, G. Angew. Chem., Int. Ed. 1978, 17, 843–844. (c) Opris, L. M.; Silvestru, A.; Silvestru, C.; Breunig, H. J.; Lork, E. Dalton Trans. 2004, 3575–3585. (d) Bringewski, F.; Huttner, G.; Imhof, W.; Zsolnai, L. J. Organomet. Chem. 1992, 439, 33–44. (e) Strube, A.; Huttner, G.; Zsolnai, L. J. Organomet. Chem. 1990, 399, 255–266. (f) Lombard, A.; Huttner, G.; Zsolnai, L. J. Organomet. Chem. 1988, 352, 295–302. (g) Balazs, G.; Breunig, H. J.; Lork, E. Z. Anorg. Allg. Chem. 2003, 629, 1937–1942. (h) Schiffer, M.; Johnson, B. P.; Scheer, M. Z. Anorg. Allg. Chem. 2000, 626, 2498–2504.
5. Huttner, G.; Weber, U.; Sigwarth, B.; Scheidsteger, O.; Lang, H.; Zsolnai, L. J. Organomet. Chem. 1985, 282, 331–348. (b) Sigwarth, B.; Weber, U.; Zsolnai, L.; Huttner, G. Chem. Ber. 1985, 118, 3114–3126.
6. Hoffmann, R. Angew. Chem., Int. Ed. 1982, 21, 711–724.
7. (a) Shieh, M.; Li, Y.-H. J. Chin. Chem. Soc. 2019, 66, 1008–1018 and references therein. (b) Shieh, M.; Yu, C.-C.; Hsing, K.-J.; Chang, W.-J. Chem. - Eur. J. 2017, 23, 11677–11683. (c) Shieh, M.; Cherng, J.-J.; Lai, Y.-W.; Ueng, C.-H.; Peng, S.-M.; Liu, Y.-H. Chem. - Eur. J. 2002, 8, 4522–4527. (d) Cherng, J.-J.; Lai, Y.-W.; Liu, Y.-H.; Peng, S.-M.; Ueng, C.-H.; Shieh, M. Inorg. Chem. 2001, 40, 1206–1212. (e) Cherng, J.-J.; Lee, G.-H.; Peng, S.-M.; Ueng, C.-H.; Shieh, M. Organometallics 2000, 19, 213–215.
8. Alvarez, S. Dalton Trans. 2013, 42, 8617–8636.
9. (a) Kaul, H.-A.; Greissinger, D.; Malisch, W.; Klein, H.-P.; Thewalt, U. Angew. Chem., Int. Ed. 1983, 22, 60–61. (b) Chitnis, S. S.; Carpenter, Y.-Y.; Burford, N.; McDonald, R.; Ferguson, M. J. Angew. Chem., Int. Ed. 2013, 52, 4863–4866. (c) Chitnis, S. S.; Robertson, A. P. M.; Burford, N.; Weigand, J. J.; Fischer, R. Chem. Sci. 2015, 6, 2559–2574. (d) Chitnis, S. S.; Peters, B.; Conrad, E.; Burford, N.; McDonald, R.; Ferguson, M. J. Cations. Chem. Commun. 2011, 47, 12331–12333. (e) Wielandt, J. W.; Kilah, N. L.; Willis, A. C.; Wild, S. B. Chem. Commun. 2006, 3679–3680. (f) Price, J. T.; Lui, M.; Jones, N. D.; Ragogna, P. J. Inorg. Chem. 2011, 50, 12810–12817. (g) Clegg, W.; Elsegood, M. R. J.; Graham, V.; Norman, N. C.; Pickett, N. L.; Tavakkoli, K. J. Chem. Soc., Dalton Trans. 1994, 1743–1751. (h) Kociok-Köhn, G.; Mahon, M. F.; Molloy, K. C.; Sudlow, A. L. Main Group Met. Chem. 2014, 37, 11–24. (i) Clegg, W.; Elsegood, M. R. J.; Norman, N. C.; Pickett, N. L. J. Chem. Soc., Dalton Trans. 1994, 1753–1757. (j) Chitnis, S. S.; Burford, N.; Weigand, J. J.; McDonald, R. Angew. Chem., Int. Ed. 2015, 54, 7828–7832. (k) Chitnis, S. S.; Burford, N.; McDonald, R.; Ferguson, M. J. Inorg. Chem. 2014, 53, 5359−5372. (l) Kilah, N. L.; Petrie, S.; Stranger, R.; Wielandt, J. W.; Willis, A. C.; Wild, S. B. Organometallics 2007, 26, 6106–6113. (m) Wielandt, J. W.; Petrie, S.; Kilah, N. L.; Willis, A. C.; Dewhurst, R. D.; Belaj, F.; Orthaber, A.; Stranger, R.; Wild, S. B. Aust. J. Chem. 2016, 69, 524–532.
10. (a) Jakubczyk, M.; Adamczyk-Woźniak, A.; Sporzyński, A. In Molecular receptors; Rybachenko, V. I. Ed.; East Publisher House: Donetsk, 2011, pp 53−68. (b) Mayer, U.; Gutmann, V.; Gerger, W. Monatsh. Chem. 1975, 106, 1235–1257. (c) Sivaev, I. B.; Bregadze, V. I. Coord. Chem. Rev. 2014, 270–271, 75–88. (d) Britovsek, G. J. P.; Ugolotti, J.; White, A. J. P. Organometallics 2005, 24, 1685–1691.
11. In The Manipulation of Air-Sensitive Compounds; Shriver, D. F., Drezdon, M. A., Eds.; Wiley-VCH: New York, 1986.
12. Smith, M. B.; Bau, R. J. Am. Chem. Soc. 1973, 95, 2388‒2389. (b) Darensbourg, M. Y.; Darensbourg, D. J.; Barros, H. L. C. Inorg. Chem. 1978, 17, 297‒301.
13. Sheldrick, G. M. A Short History of SHELX. Acta Cryst. 2008, A64, 112−122.
14. SADABS; Bruker AXS Inc.: Madison, WI, 2003.
15. Kubelka, P.; Munk, F. Ein Beitrag zür Optik der Farbanstriche. Z. Tech. Phys. 1931, 12, 593−601. (b) Tauc, J. Mater. Res. Bull. 1970, 5, 721−729.
16. Moulder, J. F., Stickle, W. F., Sobol, P. E., Bomben, K. D. Handbook of X-ray Photoelectron Spectroscopy; Chastin, J., King, R. C. Jr., Eds.; Physical Electronics:  Eden Prairie, MN, 1992.
17. Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Scalmani, G.; Barone, V.; Mennucci, B.; Petersson, G. A.; Nakatsuji, H.; Caricato, M.; Li, X.; Hratchian, H. P.; Izmaylov, A. F.; Bloino, J.; Zheng, G.; Sonnenberg, J. L.; Hada, M.; Ehara, M.; Toyota, K.; Fukuda, R.; Hasegawa, J.; Ishida, M.; Nakajima, T.; Honda, Y.; Kitao, O.; Nakai, H.; Vreven, T.; Montgomery, J. A., Jr.; Peralta, J. E.; Ogliaro, F.; Bearpark, M.; Heyd, J. J.; Brothers, E.; Kudin, K. N.; Staroverov, V. N.; Kobayashi, R.; Normand, J.; Raghavachari, K.; Rendell, A.; Burant, J. C.; Iyengar, S. S.; Tomasi, J.; Cossi, M.; Rega, N.; Millam, J. M.; Klene, M.; Knox, J. E.; Cross, J. B.; Bakken, V.; Adamo, C.; Jaramillo, J.; Gomperts, R.; Stratmann, R. E.; Yazyev, O.; Austin, A. J.; Cammi, R.; Pomelli, C.; Ochterski, J. W.; Martin, R. L.; Morokuma, K.; Zakrzewski, V. G.; Voth, G. A.; Salvador, P.; Dannenberg, J. J.; Dapprich, S.; Daniels, A. D.; Farkas, Ö.; Foresman, J. B.; Ortiz, J. V.; Cioslowski, J.; Fox, D.J. Gaussian 09, revision E.01; Gaussian, Inc.: Wallingford, CT, 2009.
18. Becke, A. D. Phys. Rev. A 1988, 38, 3098–3100. (b) Perdew, J. P. Phys. Rev. B 1986, 33, 8822–8824.
19. Adamo, C.; Barone, V. J. Chem. Phys. 1998, 108, 664–675.
20. . Reed, A. E.; Weinstock, R. B.; Weinhold, F. Natural Population Analysis. J. Chem. Phys. 1985, 83, 735−746.
21. Wiberg, K. B. Tetrahedron 1968, 24, 1083–1096.
22. Weigend, F.; Ahlrichs, R. Phys. Chem. Chem. Phys. 2005, 7, 3297–3305.
23. (a) Avogadro: An Open-Source Molecular Builder and Visualization Tool, version 1.2.0, http://avogadro.openmolecules.net/. (b) Hanwell, M. D.; Curtis, D. E.; Lonie, D. C.; Vandermeersch, T.; Zurek, E.; Hutchison, G. R. Avogadro: An Advanced Semantic Chemical Editor, Visualization, and Analysis Platform. J. Cheminf. 2012, 4, 4−17.
24. Gorelsky, S. I. AOMix. http://www.sg-chem.net/.
25. 孫子硯，國立臺灣師範大學碩士論文，2016。
26. 謝明惠，李昱輝，未發表之結果。
27. Mantina, M.; Chamberlin, A. C.; Valero, R.; Cramer, C. J.; Truhlar, D. G. J. Phys. Chem. A 2009, 113, 5806─5812.
1. In The Manipulation of Air-Sensitive Compounds; Shriver, D. F., Drezdon, M. A., Eds.; Wiley-VCH: New York, 1986.
2. Cui X.; Khlobystov AN.; Chen X.; Marsh DH.; Blake AJ.; Lewis W.; Champness NR.; Roberts CJ.; and Schrcder M.; Chem. - Eur. J. 2009, 15, 8861 – 8873.
3. Sheldrick, G. M. A Short History of SHELX. Acta Cryst. 2008, A64, 112−122.
4. SADABS; Bruker AXS Inc.: Madison, WI, 2003.