簡易檢索 / 詳目顯示

研究生: 王澤諭
Wang, Tse-Yu
論文名稱: 微型氣相層析儀應用於揮發性有機氣體之現場即時分析研究
The Field Study of Real-Time Volatile Organic Compounds Analysis Using a Micro Gas Chromatograph
指導教授: 呂家榮
Lu, Chia-Jung
學位類別: 碩士
Master
系所名稱: 化學系
Department of Chemistry
論文出版年: 2015
畢業學年度: 103
語文別: 中文
論文頁數: 90
中文關鍵詞: 微型氣相層析儀揮發性有機物即時分析
英文關鍵詞: micro gas chromatograph, volatile organic compounds, real-time analysis
論文種類: 學術論文
相關次數: 點閱:135下載:7
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報
  • 本研究將已經開發完成的微型氣相層析儀應用於半導體無塵室以及工業區鄰近鄉鎮地區8個採樣點,同時與國立臺灣大學職業工業安全與職業衛生系合作將儀器架設於車上成為可移動式監測站。利用微型氣相層析儀進行現場有機氣體之即時連續分析並於半導體無塵室時利用不鏽鋼採樣筒採樣8個小時,於鄉鎮地區8個採樣點使用不鏽鋼採樣筒以及吸附管並且採樣1天後送至工業技術研究院以氣相層析質譜儀分析進行定性及定量,並提供比對。

    本研究結果顯示,微型氣相層析儀分析出的有機化合物可呈現濃度隨時間變化之趨勢,在無塵室的部份,我們分離出六種有機氣體,濃度0.8 ppb到343.9 ppb,在鄉鎮地區監測部分,我們選擇了五種重要氣體做分析,濃度0.05 ppb到8.2 ppb,透過微型氣相層析儀於短時間可以分析大量的數據並提供人員作統計分析,協助追溯其氣體原因。

    This research used a ready-to-use and highly reliable instrument , micro gas chromatograph,(μGC),for rapid and complex environmental volatile organic compounds (VOCs) analysis in a semiconductor fabrication cleanroom and 8 sampling site of 2 township near the complex plants. In this site, canisters and stainless adsorption tube were collected and analyzed by GC-MS to provide the side by side comparisons. Field study results indicated the trend of concentrations for all chemical species. For first site, semiconductor fabrication clean room, we separated 6 compounds and the concentration ranges of chemical species from 0.8 ppb to 343.9 ppb. For second site, 8 sampling sites near the complex plants, we separated 5 compounds and the ranges from 0.05 ppb to 8.2 ppb. This study demonstrates that micro gas chromatograph can provide fast and continuous analysis for complex VOCs in field study. This research also can identified and traced back to their emission reasons.

    摘要 i Abstract ii 表目錄 vi 圖目錄 vii 第一章 緒論 1 1-1 研究背景、目的 1 1-2 揮發性有機氣體 4 1-2-1揮發性有機氣體定義 4 1-2-2 揮發性有機氣體排放來源 6 1-3 揮發性有機氣體檢測方式 9 1-4 微小化氣相層析系統裝置介紹 11 第二章 實驗部分 15 2-1-2儀器設備 16 2-2 採樣地點 17 2-2-1 無塵室微型氣相層析儀系統架設 17 2-2-2 工業區鄰近周遭鄉鎮微型氣相層析儀系統架設 19 2-3 不銹鋼採樣筒-氣相層析質譜儀 21 2-4 不鏽鋼採樣管 23 2-5 數據統計 25 第三章 結果與討論 26 3-1 無塵室採樣分析 26 3-1-1 採樣筒-氣相層析質譜儀分析結果 26 3-1-2 無塵室有機氣體校正結果 29 3-1-3 無塵室微型氣相層析儀採樣分析結果 31 3-1-4 無塵室有機氣體濃度隨時間變化之結果 33 3-1-5 實驗結果探討 41 3-1-6 小結 44 3-2 鄰近工業區周遭鄉鎮採樣分析 45 3-2-1 鄰近工業區周遭鄉鎮微型氣相層析儀採樣 45 3-2-2 採樣筒-氣相層析質譜儀分析結果 46 3-2-3 吸附管-氣相層析質譜儀分析結果 48 3-2-4 微型氣相層析儀有機氣體校正結果 52 3-2-5 微型氣相層析儀濃度隨時間變化之結果 54 3-2-6 實驗結果與風向探討 71 3-2-7 小結 81 第四章 結論 82 文獻 85

    1. 中華民國經濟部, http://www.moea.gov.tw/
    2. Delgado-Saborit, J. M., Aquilina, N. J., Meddings, C., Baker, S., & Harrison, R. M. (2011). Relationship of personal exposure to volatile organic compounds to home, work and fixed site outdoor concentrations. Science of the total environment, 409(3), 478-488.
    3. Liu, H. W., Wu, B. Z., Nian, H. C., Chen, H. J., Lo, J. G., & Chiu, K. H. (2012). VOC amounts in ambient areas of a high-technology science park in Taiwan: their reciprocal correlations and impact on inhabitants. Environmental Science and Pollution Research, 19(2), 303-312.
    4. Chiu, K. H., Wu, B. Z., Chang, C. C., Sree, U., & Lo, J. G. (2005). Distribution of volatile organic compounds over a semiconductor industrial park in Taiwan. Environmental science & technology, 39(4), 973-983.
    5. Caro, J., & Gallego, M. (2009). Environmental and biological monitoring of volatile organic compounds in the workplace. Chemosphere, 77(3), 426-433.
    6. Kampa, M., & Castanas, E. (2008). Human health effects of air pollution. Environmental pollution, 151(2), 362-367.
    7. 高雄地方法院檢察署, http://www.ksc.moj.gov.tw/
    8. 簡日昇, 微型氣相層析儀, 國立臺灣師範大學博士論文, 2013.
    9. 行政院環境保護署,http://ivy5.epa.gov.tw/epalaw/index.aspx
    10. 吳立言, 高雄地區固定源揮發性有機物指紋及光化反應潛勢之探討,國立中山大學環境工程研究所碩士論文,2002.
    11. J. Benítez, Process Engineering and Design for Air Pollution Control, PTR Prentice-Hall, 1993.
    12. Rappaport, S. M., Selvin, S., & Waters, M. A. (1987). Exposures to hydrocarbon components of gasoline in the petroleum industry. Applied Industrial Hygiene, 2(4), 148-154.
    13. Guenther, A., Karl, T., Harley, P., Wiedinmyer, C., Palmer, P. I., & Geron, C. (2006). Estimates of global terrestrial isoprene emissions using MEGAN (Model of Emissions of Gases and Aerosols from Nature). Atmospheric Chemistry and Physics Discussions, 6(1), 107-173.
    14. Wadden, R. A., Uno, I., & Wakamatsu, S. (1986). Source discrimination of short-term hydrocarbon samples measured aloft. Environmental science & technology, 20(5), 473-483.
    15. 張翼書, 華亞科技園區揮發性有機化合物與懸浮微粒特性探討長庚大學碩士論文, 2008
    16. 劉巧蓮, 大社石化工業區臭味特徵成份分析研究, 國立成功大學碩士論文, 2004
    17. Chen, C. L., Shu, C. M., & Fang, H. Y. (2006). Location and characterization of VOC emissions at a petrochemical plant in Taiwan. Environmental Forensics, 7(2), 159-167.
    18. Shie, R. H., & Chan, C. C. (2013). Tracking hazardous air pollutants from a refinery fire by applying on-line and off-line air monitoring and back trajectory modeling. Journal of hazardous materials, 261, 72-82.
    19. 羅卓卿, 油品儲運站鄰近空氣中揮發性有機污染物之特性研究, 國立中山大學碩士論文, 2001.
    20. 翁閎政, 機車排氣之揮發性有機物特徵及光化反應性研究, 國立成大學碩士論文,1998.
    21. 劉育穎, 機車排放醛酮類化合物特徵與光化反應性研究, 國立
    成功大學碩士論文, 2001.
    22. 范姜威鎧, 台北市道路鄰近地區及加油站空氣中揮發性有機化合物濃度調查研究, 國立陽明大學碩士論文, 2000.
    23. Harkov, R., Kebbekus, B., Bozzelli, J. W., & Lioy, P. J. (1983). Measurement of selected volatile organic compounds at three locations in New Jersey during the summer season. Journal of the Air Pollution Control Association, 33(12), 1177-1183.
    24. Jackson, M. W. (1978). Effect of catalytic emission control on exhaust hydrocarbon composition and reactivity (No. 780624). SAE Technical Paper.
    25. Black, F., & High, L. (1980). Passenger car hydrocarbon emissions speciation (No. EPA-800/2-80-085 Final Rpt.).
    26. Kebbekus, B., Greenberg, A., Horgan, L., Bozzelli, J., Darack, F., Eveleens, C., & Stangeland, L. (1983). Concentration of selected vapor and particulate-phase substances in the Lincoln and Holland Tunnels. Journal of the Air Pollution Control Association, 33(4), 328-330
    27. Evans, G. F., Lumpkin, T. A., Smith, D. L., & Somerville, M. C. (1992). Measurements of VOCs from the TAMS Network. Journal of the Air & Waste Management Association, 42(10), 1319-1323.
    28. U.S. Environmental Protection Agency, Washington, DC. ( 1999)
    Compendium method TO-14A. determination of Volatile Organic compounds (VOCs) in ambient air using specially prepared canisters with subsequent analysis by gas chromatography.
    29. U.S. Environmental Protection Agency, Washington, DC. ( 1999)
    Compendium method TO-15, determination of volatile organic
    compounds (VOCs) in air collected in specially prepared canisters and analyzed by gas chromatography/mass spectrometry.
    30. U.S. Environmental Protection Agency, Washington, DC. ( 1999)
    Compendium Method TO-16, determination of toxic organic
    compounds in ambient air.
    31. Lu, C. J., Steinecker, W. H., Tian, W. C., Oborny, M. C., Nichols, J. M., Agah, M., ... & Zellers, E. T. (2005). First-generation hybrid MEMS gas chromatograph. Lab on a Chip, 5(10), 1123-1131.
    32. Kim, S. K., Burris, D. R., Bryant-Genevier, J., Gorder, K. A., Dettenmaier, E. M., & Zellers, E. T. (2012). Microfabricated gas chromatograph for on-site determinations of TCE in indoor air arising from vapor intrusion. 2. spatial/temporal monitoring. Environmental science & technology, 46(11), 6073-6080.
    33. Jian, R. S., Huang, Y. S., Lai, S. L., Sung, L. Y., & Lu, C. J. (2013). Compact instrumentation of a μ-GC for real time analysis of sub-ppb VOC mixtures. Microchemical Journal, 108, 161-167.
    34. Jian, R. S., Sung, L. Y., & Lu, C. J. (2014). Measuring real-time concentration trends of individual VOC in an elementary school using a sub-ppb detection μGC and a single GC–MS analysis. Chemosphere, 99, 261-266.
    35. Lewis, P. R., Manginell, R. P., Adkins, D. R., Kottenstette, R. J., Wheeler, D. R., Sokolowski, S. S., ... & Frye-Mason, G. C. (2006). Recent advancements in the gas-phase MicroChemLab. Sensors Journal, IEEE, 6(3), 784-795.
    36. Zampolli, S., Elmi, I., Mancarella, F., Betti, P., Dalcanale, E., Cardinali, G. C., & Severi, M. (2009). Real-time monitoring of sub-ppb concentrations of aromatic volatiles with a MEMS-enabled miniaturized gas-chromatograph. Sensors and Actuators B: Chemical, 141(1), 322-328.
    37. 郭秀如, 建立自動化甲烷連續量測系統與其在指示大氣輻射冷卻之應用, 國立中央大學碩士論文,2000.
    38. 劉承玨 許瑛玿, 淺談逆溫,科學online( 2009)
    http://highscope.ch.ntu.edu.tw/wordpress/?p=4057

    下載圖示
    QR CODE