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研究生: 陳氏緣
Tran, thi-duyen
論文名稱: 中國西南攀枝花火成雜岩之實驗岩石學研究-關於鐵-鈦-釩氧化 礦床成因
An experimental investigation of the Panzhihua igneous complex, SW China-Addressing the genesis of Fe-Ti-V oxide ore deposits
指導教授: 謝奈特
John Gregory Shellnutt
學位類別: 碩士
Master
系所名稱: 地球科學系
Department of Earth Sciences
論文出版年: 2016
畢業學年度: 104
語文別: 英文
論文頁數: 86
中文關鍵詞: 攀枝花於鐵-鈦-釩氧化礦床實驗岩石學
英文關鍵詞: Panzhihua, Fe-Ti-V oxide ore deposits, experimental petrology
DOI URL: https://doi.org/10.6345/NTNU202204508
論文種類: 學術論文
相關次數: 點閱:44下載:9
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  • The Late Permian Panzhihua layered gabbroic intrusion of SW China hosts one of the largest magmatic Fe-Ti-V oxide deposits within the Emeishan large igneous province and is coeval with a peralkaline granitic pluton. The largest oxide ore body is found at the base of the intrusion, which is unlike other layered intrusions where the Fe-Ti oxide deposits are located in the uppermost portions. This study attempts to model the genesis of the Panzhihua layered intrusion, including the formation of the ore deposit by reconstructing the crystallization sequence of minerals from low and high-pressure experiments. The starting composition used for the experiment is similar to high-Ti Emeishan basalt that resembles the theoretical parental composition of the Panzhihua intrusion. The low-pressure experiments were conducted between 1312oC and 1102oC. The first mineral to crystallize is Cr-rich titanomagnetite at 1274oC. Following Cr-rich titanomagnetite are: Fe-Ti oxides (ilmenite+titanomagnetite); clinopyroxene (Wo39-52En39-47Fs8-16) at 1188oC; plagioclase (An67-41) and orthopyroxene (Mg# = 93-95) at 1162oC. The compositional range of clinopyroxene and plagioclase matches those measured from the rock of the Panzhihua intrusion. The high-pressure experiments occur between 1240oC and 1050oC. Iron-titanium oxide and clinopyroxene (Wo23-48En37-58Fs10-22) appear together as the first phases at 1180oC. The sequence is followed by orthopyroxene at 1100oC and plagioclase (An61-37) at 1050oC. The experiment results indicate that the early crystallization sequence of the parental magma is dominated by Fe-Ti oxide and partially explain why the largest oxide ore deposit of the Panzhihua intrusion is found in the lowermost layers. The low temperature residual glass compositions in both experiments are enriched in SiO2, Al2O3, Na2O and K2O; and depleted in TiO2, FeOt, MgO and CaO. However, minerals crystallize at relatively low temperature in the high-pressure and consequently have less silicic (SiO2 ≈ 61 wt%) residual glass composition than that of the low-pressure experiment (SiO2 ≈ 72 wt%). The similarity between Panzhihua granite and low-pressure residual glass suggests that the Panzhihua intrusion probably formed at shallow depth. Furthermore, the liquid-crystal evolution constructed from the low-pressure experiment show that a parental magma similar to high-Ti Emeishan basalt can produce an early enrichment of oxide minerals and a silicic residual liquid via fractional crystallization.

    Keywords: Panzhihua, Fe-Ti-V oxide deposits, experimental petrology

    The Late Permian Panzhihua layered gabbroic intrusion of SW China hosts one of the largest magmatic Fe-Ti-V oxide deposits within the Emeishan large igneous province and is coeval with a peralkaline granitic pluton. The largest oxide ore body is found at the base of the intrusion, which is unlike other layered intrusions where the Fe-Ti oxide deposits are located in the uppermost portions. This study attempts to model the genesis of the Panzhihua layered intrusion, including the formation of the ore deposit by reconstructing the crystallization sequence of minerals from low and high-pressure experiments. The starting composition used for the experiment is similar to high-Ti Emeishan basalt that resembles the theoretical parental composition of the Panzhihua intrusion. The low-pressure experiments were conducted between 1312oC and 1102oC. The first mineral to crystallize is Cr-rich titanomagnetite at 1274oC. Following Cr-rich titanomagnetite are: Fe-Ti oxides (ilmenite+titanomagnetite); clinopyroxene (Wo39-52En39-47Fs8-16) at 1188oC; plagioclase (An67-41) and orthopyroxene (Mg# = 93-95) at 1162oC. The compositional range of clinopyroxene and plagioclase matches those measured from the rock of the Panzhihua intrusion. The high-pressure experiments occur between 1240oC and 1050oC. Iron-titanium oxide and clinopyroxene (Wo23-48En37-58Fs10-22) appear together as the first phases at 1180oC. The sequence is followed by orthopyroxene at 1100oC and plagioclase (An61-37) at 1050oC. The experiment results indicate that the early crystallization sequence of the parental magma is dominated by Fe-Ti oxide and partially explain why the largest oxide ore deposit of the Panzhihua intrusion is found in the lowermost layers. The low temperature residual glass compositions in both experiments are enriched in SiO2, Al2O3, Na2O and K2O; and depleted in TiO2, FeOt, MgO and CaO. However, minerals crystallize at relatively low temperature in the high-pressure and consequently have less silicic (SiO2 ≈ 61 wt%) residual glass composition than that of the low-pressure experiment (SiO2 ≈ 72 wt%). The similarity between Panzhihua granite and low-pressure residual glass suggests that the Panzhihua intrusion probably formed at shallow depth. Furthermore, the liquid-crystal evolution constructed from the low-pressure experiment show that a parental magma similar to high-Ti Emeishan basalt can produce an early enrichment of oxide minerals and a silicic residual liquid via fractional crystallization.

    Keywords: Panzhihua, Fe-Ti-V oxide deposits, experimental petrology

    Table of contents Acknowledgements 1 Table of contents 2 List of Figures 4 List of Tables 6 Abstract 7 Chapter 1. Introduction 8 1.1. Introduction 8 1.2. Layered mafic intrusions 8 1.3. Debated issues 11 1.4. Purpose of this study 14 Chapter 2. Geological Background 15 2.1. China’s tectonic framework in the global context 15 2.2. Yangtze Block and the collision to form the South China block 16 2.3. The Emeishan Large Igneous Province (ELIP) 17 2.4. The layered gabbroic Panzhihua intrusion 19 Chapter 3. Methods 22 3.1. Experimental methods 22 3.2. Analytical methods 27 Chapter 4. Results 29 4.1. Crystallization sequence of minerals 29 4.2. Synthesis mineral chemistry 35 4.3. Composition of residual glass 48 Chapter 5. Discussion 53 5.1. Early crystallization of oxide and the occurrence of ore deposit at the base of the Panzhihua intrusion 53 5.2. Ore forming process: Immiscibility vs. Fractional Crystallization 54 5.3. Composition of residual magma and relationship with surrounding silicic rocks 58 5.4. Comparison among chemical composition of synthesis minerals, MELTS models and mineral from the Panzhihua intrusion 59 5.5. The effect of thermodynamic parameters on magmatic differentiation 61 Chapter 6. Conclusions 66 References 67 Appendix 71

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