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研究生: 徐有駿
Hsu, Yu-Chun
論文名稱: 紅外線奈米塗料提升R-600a冰箱性能之研究
Research on Enhancing the Performance of R-600a Refrigerator by Using Infrared Water-based Nano-coating
指導教授: 鄧敦平
Teng, Tun-Ping
學位類別: 碩士
Master
系所名稱: 工業教育學系
Department of Industrial Education
論文出版年: 2015
畢業學年度: 103
語文別: 中文
論文頁數: 128
中文關鍵詞: 紅外線奈米塗料異丁烷性能係數能源因數環境溫度
英文關鍵詞: infrared water-based nano-coating (IWNC), isobutene (R-600a), coefficient of performance (COP), the energy factor (EF), ambient temperature
論文種類: 學術論文
相關次數: 點閱:95下載:21
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  • 本研究針對紅外線奈米塗料(IWNC)塗佈於異丁烷(R-600a)冰箱的冷凝器進行提升冰箱性能之可行性研究。首先利用複立葉紅外線光譜儀(FTIR)選擇出較高紅外線吸收值的三種紅外線材料,並使用二階合成法製作這三種材料的IWNC。接著經由FTIR、發射率、熱交換實驗的結果來篩選出最佳的紅外線材料與濃度。最後將IWNC塗佈於R-600a冰箱冷凝器上,並探討冷凝器有無塗佈IWNC在不同的環境溫度(26、30、34 ℃)下的無載下拉測試與環境溫度30℃的24小時加載運轉測試的性能係數(COP)、能源因數(EF)、庫內溫度、耗電量等相關參數,藉以評估IWNC對於冰箱性能的影響。
    研究結果顯示,IWNC最佳的添加材料為多壁奈米碳管(MWCNTs),最佳濃度為4 wt.%。與未塗佈MWCNTs/IWNC的R-600a冰箱測試數據相比較,冷凝器塗佈4 wt.%的MWCNTs/IWNC之後的高壓壓力可減低5.74%,EF提升7.89%,耗電量下降7.15%,COP則提升6.17%。相關研究結果顯示在R-600a 冰箱的冷凝器上塗佈MWCNTs/IWNC確實可提升冰箱的性能與降低耗電量,對於節能減碳將將能有所助益。

    In this study, the infrared water-based nano-coating (IWNC) was coated on the condenser of isobutane (R-600a) refrigerator to demonstrate the feasibility for enhancing the performance of the refrigerator. First, the Fourier transform infrared spectroscopy (FTIR) was used to select three infrared materials with high infrared absorbance to be prepared for the IWNC by a two-step synthesis method. Then, the optimal infrared materials and concentration was selected by using the FTIR, emissivity, and heat exchange experiments. Finally, the IWNC was coated on the condenser of R-600a refrigerator for evaluating the coefficient of performance (COP), the energy factor (EF), the freezer temperature, electricity consumption, and other related parameters under the conditions of no load pull-down test at different ambient temperatures (26, 30, and 34 oC) and 24-hour loading test at ambient temperature of 30 oC, respectively, to assess the performance of the refrigerator with and without the IWNC.
    The results showed that the optimal infrared material and concentration was multi-walled carbon nanotubes (MWCNTs) and 4 wt.%, respectively. The condenser of R-600a refrigerator with 4 wt.% MWCNTs/IWNC reduced the high-pressure and electricity consumption 5.74% and 7.15%, respectively; enhanced COP and EF 6.17% and 7.89%, respectively; as compared with the test data of original R-600a refrigerator. The relevant results displayed that the condenser of an R-600a refrigerator coated by the MWCNTs/IWNC indeed improved performance and reduced electricity consumption of the refrigerator, which is helpful for energy conservation and carbon reduction.

    摘要 i ABSTRACT ii 謝誌 iii 目錄 iv 表目錄 vi 圖目錄 viii 第一章 緒論 1 1.1. 前言 1 1.2. 研究目的 3 1.3. 研究流程 4 1.4. 論文架構 6 1.5. 文獻回顧 6 第二章 理論分析 11 2.1. 紅外線相關理論 11 2.1.1. 維恩位移定律 12 2.1.2. 史蒂芬-波茲曼輻射定律 13 2.2. 奈米流體 14 2.2.1. 奈米流體的製備 14 2.2.2. 紅外線奈米塗料 18 2.3. 蒸汽壓縮冷凍循環系統之熱力分析 19 2.3.1. 蒸汽壓縮冷凍循環之基本理論 19 2.3.2. 理想蒸汽壓縮冷凍循環 20 2.3.3. 實際蒸氣壓縮冷凍循環 21 2.3.4. 冷凍系統熱力分析 23 2.4. 自然冷媒 27 2.4.1. 異丁烷 27 2.4.2. 冷媒的選用 28 2.5. 毛細管長度的計算 30 第三章 實驗設計 35 3.1. 實驗架構 35 3.2. 實驗設備與材料 38 3.2.1. 實驗設備與量測儀器 40 3.2.2. 實驗材料 50 3.3. 紅外線材料性能實驗 52 3.3.1. 紅外線材料篩選方法 52 3.3.2. 紅外線奈米塗料的製備 55 3.3.3. IWNC的FTIR實驗 59 3.3.4. IWNC發射率實驗 59 3.3.5. 熱交換實驗 60 3.4. 冰箱系統性能實驗 64 3.4.1. 冰箱負載規範 67 3.4.2. 測試環境 68 3.4.3. 無載下拉實驗 69 3.4.4. 加載24小時運轉實驗 69 3.5. 冰箱系統數據分析 70 3.5.1. 實驗量測狀態點 70 3.5.2. 冰箱性能數據分析 71 第四章 結果與討論 73 4.1. IWNC基礎實驗以及最佳材配方的選擇 73 4.1.1. IWNC的紅外光譜檢測實驗結果與討論 73 4.1.2. 發射率實驗結果與討論 80 4.1.3. 熱交換實驗結果與討論 83 4.1.4. IWNC最佳材料與比例的選擇 89 4.2. 冰箱無載下拉結果與討論 91 4.2.1. R-600a 冰箱無載下拉實驗結果與討論 91 4.2.2. R-600a冰箱冷凝器塗佈IWNC無載下拉實驗結果與討論 96 4.2.3. 無載下拉實驗綜合比較結果與討論 99 4.3. 冰箱加載24小時運轉實驗 101 4.3.1. R-600a 冰箱加載24小時運轉實驗結果與討論 101 4.3.2. R-600a冰箱冷凝器塗佈IWNC加載24小時運轉實驗結果與討論 106 4.3.3. 加載24小時運轉實驗綜合比較結果與討論 108 第五章 結論與建議 111 5.1. 結論 111 5.2. 未來研究方向 112 參考文獻 113 符號說明 123 略傳 127

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