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研究生: 游若琳
Rouahlin You
論文名稱: 碳六十/聚合物石英壓電晶體偵測器之研製與應用
Preparation and Application of Piezoelectric Crystal Detector Based on C60/Polymer Coatings
指導教授: 施正雄
Shih, Jeng-Shong
學位類別: 碩士
Master
系所名稱: 化學系
Department of Chemistry
畢業學年度: 87
語文別: 中文
論文頁數: 150
中文關鍵詞: 碳六十碳六十/聚合物石英壓電晶體偵測器石英微量天平
英文關鍵詞: C60, buckminsterfullerene, piezoelectric crystal detector, quartz crystal microbalance, fullerene polymers
論文種類: 學術論文
相關次數: 點閱:219下載:0
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碳六十/聚合物石英壓電晶體偵測器之研製與應用
摘 要
本實驗是利用Friedel-Craft反應合成C60/聚肉桂醛(C60/polycinnamaldehyde, C60/PCA)及C60/聚苯乙炔(C60/polyphenylacetylene, C60/PPA)兩種共聚合物來作為石英壓電晶體之塗佈物質。在C60/PCA石英壓電晶體偵測器中,利用自製微電腦介面中的頻率/電壓(F / V)轉換器,將頻率訊號轉為電壓訊號並以放大器(OPA)放大,再經類比 / 數位(A / D)介面卡轉換成數位訊號後,輸入電腦讀取記錄並繪圖。而在C60/PPA石英壓電晶體偵測器中,則利用含ALTERA及8255卡之介面來讀取振盪頻率及其變化,並以軟體控制介面、讀取數據及繪圖。
在C60/PCA塗佈膜之蛋白質壓電晶體偵測器中,發現血紅素(hemoglobin)及過氧化氫酵素(catalase)有較佳的感應頻率變化。其對血紅素有不錯的靈敏度(6530 Hz / (mg / mL)),良好的濃度線性關係及偵測下限(~ ppm level)。
而在C60/PPA塗佈膜之有機氣體壓電晶體偵測器中,其偵測訊號之大小分別為芳香烴>炔>烯>烷。即使在加熱的情況下,其對甲苯仍有不錯的靈敏度,偵測下限(~ppm)及再現性(RSD = 6.4 ﹪)。此外,我們也發現在加熱的情況下,若以甲苯作為多環芳香烴(PAHs)之溶劑時,C60/PPA塗佈膜對PAHs也有不錯的感應效果。

Preparation and Application of Piezoelectric Crystal Detector Based on C60/Polymer Coatings
Abstract
The C60/polycinnamaldehyde ( C60/PCA ) and C60/polyphenylacetylene ( C60/PPA ) copolymers were synthesized by using the Friedel – Craft reaction and applized as the piezoelectric quartz crystal coating materials.
A C60/polycinnamaldehyde (PCA) coated piezoelectric quartz crystal membrane sensor with a home – made computer interface was prepared and applied as a PZ protein sensor. The adsorption of protein such as hemoglobin onto the C60/PCA coated crystal resulted in the decrease of oscillating frequency. The variations of crystal frequency were converted to voltage with a frequency to voltage converter, and followed by amplification with OPA and data acquisition with analog to digital converter. It was found that hemoglobin had the best signal shift among the testing proteins. The PZ protein sensor exhibited good sensitivity of 6530 Hz / ( mg / mL ) and with detection limit of ppm level for hemoglobin.
Furthermore, a C60/polyphenylacetylene (PPA) coated piezoelectric quartz crystal sensor with an Intell-8255 data processing system for various olefin vapors was also made. The aromatic hydrocarbons such as toluene seems to have greater adsorption onto C60/PPA membrane than alkynes, alkenes and alkanes. The absorption of ploycyclic aromatic hydrocarbons (PAHs) onto the C60/PPA membrane was also investigated. And we found that by using toluene as the solvent for PAHs, the C60/PPA membrane has a much larger frequency shift for naphthalene.

目 錄 英文摘要 中文摘要 目錄 圖目錄 表目錄 第一章 緒論 1-1冠狀醚 1-1-1 冠狀醚的簡介 1-1-2 冠狀醚的應用 1-2碳六十 1-2-1 C60的發展簡介 1-2-2 C60的性質 1-2-2-1 C60於有機溶劑之溶解度 1-2-2-2 C60質譜鑑定 1-2-2-3 C60的UV-VIS及光譜 1-2-2-4 C60的核磁共振(NMR)光譜 1-2-2-5 C60的X-ray光譜 1-2-2-6 C60的循環電伏法(CV) 1-2-2-7固態C60和石墨及鑽石的性質比較 1-2-3 C60的反應特性 1-2-3-1 C60的有機反應 1-2-3-2 C60的無機反應 1-3碳六十聚合物(Fullerene Polymers) 1-3-1 C60聚合物簡介 1-3-2各種包含C60的聚合物之合成方法 1-3-2-1自由基聚合反應(free radical reaction) 1-3-2-2陰離子聚合反應(anion polymerization) 1-3-2-3胺加成反應(amine addition) 1-3-2-4經由azide官能基的反應 1-3-2-5 Diels-Alder環化加成反應 1-3-2-6 Friedel-Craft 反應 1-3-2-7 C60在聚合物主鏈上之聚合反應 1-3-2-8 C60和polydiene之聚合反應 1-3-3 C60作為聚合反應之催化劑 1-3-4 C60聚合物的應用 1-4壓電晶體特性及其應用 1-4-1壓電性 1-4-2石英振盪器 1-4-3石英振盪器的使用 1-4-3-1石英振盪器的線路 1-4-3-2振盪頻率的量測 1-4-4石英微量天平(Quartz Crystal Microbalance, QCM) 1-4-5石英壓電晶體在液相之振盪情形 1-4-6石英壓電晶體在分析化學領域的應用 1-4-6-1石英壓電晶體在氣相之應用 1-4-6-2石英壓電晶體在液相之應用 第二章 實驗部分 2-1藥品溶劑及儀器 2-2碳六十/聚合物的合成 2-2-1聚肉桂醛(PCA)的合成 2-2-2聚苯乙炔(PPA)的合成 2-2-3碳六十/聚肉桂醛的合成 2-2-4 碳六十/聚苯乙炔的合成 2-3石英振盪晶體處理 2-3-1配製表面塗佈液(coating solution) 2-3-2表面塗佈法 2-4實驗系統與方法 2-4-1液相實驗系統 2-4-2氣相實驗系統 第三章 結果與討論 3-1 C60/聚桂肉醛,C60/聚苯乙烯的合成 3-1-1 C60/聚肉桂醛的合成 3-1-2 C60/聚苯乙炔的合成 3-1-3 C60/聚肉桂醛的分析鑑定 3-1-4 C60/聚苯乙炔的分析鑑定 3-2石英壓電晶體液相蛋白質偵測系統之研製與應用 3-2-1不同塗佈膜對血紅素(hemoglobin)之感應頻率變化情形 3-2-2 C60/聚肉桂醛/PVC塗佈量對壓電偵測器感應影響 3-2-3不同塗佈膜之石英壓電晶體對五種蛋白質之感應頻率變化情形 3-2-4蛋白質濃度效應,偵測下限及再現性 3-2-5溶劑效應 3-3石英壓電晶體氣相有機氣體偵測系統之研製與應用 3-3-1 C60/聚苯乙炔塗佈量對有機氣體壓電偵測器感應影響 3-3-2不同塗佈膜之石英壓電晶體對各種有機氣體之感應效應 3-3-3 C60/PPA石英壓電晶體偵測系統對炔、烯、烷、甲苯之感應頻率變化比較 3-3-4溫度效應 3-3-5濃度效應、偵測下限及再現性 3-3-6 C60/PPA石英壓電晶體偵測器對多環芳香族碳氫化合物(PAHs)之感應頻率變化情形 第四章 結論 附錄 參考資料

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