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研究生: 高郁勝
Kao, Yu-Sheng
論文名稱: 混合型石墨烯奈米結構於多工感測器之開發研究
Hybrid graphene nanocomposites for the development of multi-function sensors
指導教授: 李亞儒
Lee, Ya-Ju
學位類別: 碩士
Master
系所名稱: 光電工程研究所
Graduate Institute of Electro-Optical Engineering
論文出版年: 2019
畢業學年度: 107
語文別: 中文
論文頁數: 47
中文關鍵詞: 多工感測器石墨烯石墨烯量子點
英文關鍵詞: Multi-Function Sensors, Graphene, Graphene Quantum Dots
DOI URL: http://doi.org/10.6345/NTNU201900966
論文種類: 學術論文
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  • 可撓式與可穿戴式應變感測器對於人體運動檢測具有無限的潛力,並引起研究人員極大的興趣。在本論文中,我們提出一種以可撓的聚二甲基矽氧烷 (Polydimethyl Siloxane, PDMS) 為基板,加入低成本的石墨烯與石墨烯量子點奈米結構,開發出同時具備應變與光偵測之多工感測器。本研究共分為兩大類,第一部份為拉伸量測以及第二部份為照光量測。第一部份為加入不同次數 (濃度) 的石墨烯進行拉伸量測,在 SEM 拍攝下 20 次數 (濃度) 的石墨烯厚度為 50 μm 和 50 次的石墨烯厚度為 200 μm;在 50 次下所得到的應變因子 (Gauge Factor) 為 GF = 14,在 20 次下得到的應變因子為 GF = 76,並且形變量可以達到 30 % 以上。此外,我們也對該元件進行耐久性測量,以每拉伸 25 次數進行量測,經重複拉伸300次後,其電阻變化率從 4.5 變為 6.5,其改變量約為 14 %。第二部份為加入不同次數的石墨烯與石墨烯量子點進行照光量測,使用波長為 365 nm 的紫外光進行照光量測。發現隨著照光功率提升,電流會從 300 μA 提高至 410 μA,其提升約 30 %。我們預期本論文所開發之混合型石墨烯奈米結構多工感測器,在未來對人體運動檢測上,將能夠發揮重要作用。

    Flexible and wearable strain sensors have great potentials for the appliation of human motion detections, and have hence attracted broad research interests. In this thesis, we propose a novel strain sensor combining the graphene flakes with graphene quantum dots on the flexible polydimethylsiloxane (PDMS) substrate. Such novel sensor is able to simutaneously detect the variation of both exerted strain and incident light-power appied on it.
    The study is mainly divided into two parts: Firstly, we have systematically discussed the dependence of strain variation on a series samples with different times (concentrations) of graphene flakes. The graphene flakes accumulate on the PDMS substrate and form a bulk-like film. According to the corss-sectinal SEM image, the thicknesses are 50 μm and 200 μm for the samples with 20 and 50 times concentrations of graphene flakes, respectively. The measured strain factors are 76 and 20 for the samples with 20- and 50- time concentrations of graphene flakes, respectively. Our stain sensor can sustain upon to the maximum deformation of ~30 %. We also perform the durability test on our strain samples, in which sample is experienced with 25 times stretching of 30 % deformation in each durability test. The resistance change rate was only varied from 4.5 to 6.5, even after a repeated stretching test up to 300 times, and that corresponds to a slight change of ~14 % in the resistance.
    Secondly, we have detected the variation of incident light-power on the samples with different concentrations of graphene flakes and graphene quantum dots. To perfomce such experiments, the fabricated samples are illuminated by using the ultraviolet LED with a wavelength of 365 nm. It was found that the measured photocurrent will increase from 300 μA to 410 μA with the increasing of illumination power from 0 to 3600 mW. It corresponds to ~30 % increasment in the measured photocurrent. As a result, we believe such novel hybrid graphene nanostructured sensors will play an important role for the detection of human motions in the near future.

    致謝 i 摘要 ii Abstract iii 目錄 v 圖目錄 viii 表目錄 x 第一章 緒論 1 1.1 前言 1 1.2 研究動機 1 1.3 研究目的 2 1.4 論文架構 3 第二章 基本原理及文獻回顧 4 2.1 石墨烯之材料特性及應用 4 2.2 單層石墨烯製備方法 7 2.3 應變感測器 9 2.4 石墨烯量子點介紹與應用 13 2.5 石墨烯量子點合成方法 16 2.6 光激發光(Photoluminescence, PL)簡介與原理 18 2.7 光電感測器 19 第三章 實驗方法和使用材料 22 3.1 多工感測器製程 22 3.2 石墨烯量子點合成 25 3.3 KEITHLEY 2400量測系統 27 3.4拉伸量測 28 3.5 照光量測 29 3.6 實驗耗材 30 第四章 結果與討論 31 4.1 石墨烯材料分析 31 4.2 拉伸量測 35 4.3 穿戴式裝置量測 37 4.4 多工感測器之耐久性 38 4.5 石墨烯量子點材料分析 38 4.6 照光量測 40 第五章 結論與未來展望 43 參考文獻 44

    [1] P. Sahatiya, S. K. Puttapati, V. V. Srikanth, and S. Badhulika, "Graphene-based wearable temperature sensor and infrared photodetector on a flexible polyimide substrate," IOP Publishing, Flexible and Printed Electromics, vol. 1, no. 2, p. 025006, 2016.
    [2] S. Akbar, P. Dutta, and C. Lee, "High‐temperature ceramic gas sensors: a review," American Ceramic Society, Applied Ceramic Technology, vol. 3, no. 4, pp. 302-311, 2006.
    [3] R. Kumar, O. Al-Dossary, G. Kumar, and A. Umar, "Zinc oxide nanostructures for NO 2 gas–sensor applications: A review," Springer, Nano-Micro Letters, vol. 7, no. 2, pp. 97-120, 2015.
    [4] M. Sugiura, "Obstacle sensor having supersonic sensor," ed: Google Patents, 2008.
    [5] D. Ding, R. A. Cooper, P. F. Pasquina, and L. Fici-Pasquina, "Sensor technology for smart homes," ScienceDirect, Maturitas, vol. 69, no. 2, pp. 131-136, 2011.
    [6] T. I. Miller, B. F. Spencer , Jr. J. Li, and H. Jo, "Solar energy harvesting and software enhancements for autonomous wireless smart sensor networks," Newmark Structural Engineering Laboratory, University of Illinois at Urbana-Champaign, 1940-9826, 2010.
    [7] K. S. Novoselov, A. K. Geim, S. V. Morozov, D. Jiang, Y. Zhang, S. V. Dubonos, I. V. Grigorieva and A. A. Firsov, "Electric field effect in atomically thin carbon films," Science, vol. 306, no. 5696, pp. 666-669, 2004.
    [8] https://en.wikipedia.org/wiki/Graphene
    [9] A. K. Geim and K. S. Novoselov, "The rise of graphene," Nature Materials, vol. 6, pp. 183-191, 2007.
    [10] W. A. De Heer, C. Berger, M. Ruan, M. Sprinkle, X. Li, Y. Hu, and B. Zhang, "Large area and structured epitaxial graphene produced by confinement controlled sublimation of silicon carbide," Proceedings of the National Academy of Sciences, vol. 108, no. 41, pp. 16900-16905, 2011.
    [11] A. Reina, X. Jia, J. Ho, D. Nezich, H. Son, V. Bulovic, M. S. Dresselhaus, and J. Kong, "Large area, few-layer graphene films on arbitrary substrates by chemical vapor deposition," American Chemical Society, vol. 9, no. 1, pp. 30-35, 2008.
    [12] Y-J. Hu, J. Jin, H. Zhang, P. Wu, and C-X. Cai, "Graphene: Synthesis, Functionalization and Applications in Chemistry by Wuli Huaxue Xuebao," Editorial office of Acta Physico-Chimica Sinica, vol. 26, no. 8, pp. 2073-2086, 2010.
    [13] N. Liu, F. Luo, H. Wu, Y. Liu, C. Zhang, and J. Chen, "One‐step ionic‐liquid‐assisted electrochemical synthesis of ionic‐liquid‐functionalized graphene sheets directly from graphite," Advanced Functional Materials, vol. 18, no. 10, pp. 1518-1525, 2008.
    [14] H. Tian, Y. Shu, Y-L. Cui, W-T. Mi, Y. Y, D. Xie, and T-L. Ren, "Scalable fabrication of high-performance and flexible graphene strain sensors," Nanoscale vol. 6, no. 2, pp. 699-705, 2014.
    [15] X. Wang, J. Li, H. Song, H. Huang, and J. Gou, "Highly stretchable and wearable strain sensor based on printable carbon nanotube layers/polydimethylsiloxane composites with adjustable sensitivity," ACS Appl. Mater., vol. 10, no. 8, pp. 7371-7380, 2018.
    [16] https://www.ni.com/zh-tw/innovations/white-papers/07/measuring-strain-with-strain-gages.html
    [17] Y. Yan, J. Chen, Z. Zeng, W. Huang, K. Pu, J. Liu, and P. Chen, "Recent Advances on Graphene Quantum Dots: From Chemistry and Physics to Applications," Advanced Materials, vol. 31, no. 21, p. 1808283, 2019.
    [18] 林凱聖, 方之宜, 張儀真, 葉珮君, 江偉宏, "石墨烯量子點的合成、 特性及感測應用," 化工, 第六十五卷, 第三期, 第10-25頁 (2018)。
    [19] https://www.graphene-info.com/graphene-quantum-dots
    [20] P. Tian, L. Tang, K. S. Teng, and S. P. Lau, "Graphene quantum dots from chemistry to applications," ScienceDirect, materialstoday Chemistry, vol. 10, pp. 221-258, 2018.
    [21] Y. Li, Y. Hu, Y. Zhao, G. Shi, L. Deng, Y. Hou, and L. Qu, "An electrochemical avenue to green‐luminescent graphene quantum dots as potential electron‐acceptors for photovoltaics," Advanced Materials, vol. 23, no. 6, pp. 776-780, 2011.
    [22] D. Pan, L. Guo, J. Zhang, C. Xi, Q. Xue, H. Huang, J. Li, Z. Zhang, W. Yu, Z. Chen, Z. Li, and M. Wu, "Cutting sp 2 clusters in graphene sheets into colloidal graphene quantum dots with strong green fluorescence," Journal of Materials Chemistry, vol. 22, no. 8, pp. 3314-3318, 2012.
    [23] J-J. Wang, M. Feng, and H-B. Zhan, "Advances in Preparation of Graphene Quantum Dots by Progress in Chemistry," Progress in Chemistry, vol. 25, no. 01, pp. 86-94, 2013.
    [24] X. Yan, X. Cui, and L-S. Li, "Synthesis of large, stable colloidal graphene quantum dots with tunable size," American Chemical Society, vol. 132, no. 17, pp. 5944-5945, 2010.
    [25] L. Tang, R. Ji, X. Cao, J. Lin, H. Jiang, X. Li, K. S. Teng, C. M. Luk, S. Zeng, J. Hao, and S. P. Lau, "Deep ultraviolet photoluminescence of water-soluble self-passivated graphene quantum dots," ACSNANO, vol. 6, no. 6, pp. 5102-5110, 2012.
    [26] 謝嘉民, 賴一凡, 林永昌, 枋志堯, "光激發螢光量測的原理、架構及應用," 奈米通訊, 第十二卷, 第二期, 第28-39頁 (2005)。
    [27] C. O. Kim, S. W. Hwang, S. Kim, D. H. Shin, S. S. Kang, J. M. Kim, C. W. Jang, J. H. Kim, K. W. Lee, S-H. Choi, and E. Hwong, "High-performance graphene-quantum-dot photodetectors," Scientific Reports, vol. 4, p. 5603, 2014.
    [28] https://kknews.cc/zh-tw/science/r88kbgo.html

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