本論文敘述以一價銠金屬和掌性雙環雙烯配基形成錯合物為催化劑，催化有機硼試劑與亞胺，進行具位像選擇性及鏡像選擇性的不對稱加成反應。
使用一價銠金屬和掌性雙環雙烯配基L6a形成的錯合物為催化劑，以1,4-二噁烷為溶劑碳酸鉀為添加劑，催化芳香基硼酸與α,β-不飽和亞胺21，進行不對稱1,4-加成反應，產物22產率最高可達95%，鏡像超越值最高可達99% ee。
以一價銠金屬和掌性雙環雙烯配基L1a形成的錯合物為催化劑，以乙腈為溶劑水為添加劑，進行烯丙基三氟硼酸鉀鹽對亞胺21的1,2-加成反應，產物32產率最高可達99%，鏡像超越值最高可達99.5% ee。

A highly enantioselective and regioselective addition of organo boron reagents to cyclic α,β-unsaturated N-sulfonyl ketimines catalyzed by in situ generated Rh (Ι) catalyst is described.
The 1,4-addition reaction of arylboronic acids proceeds with excellent regioselectivity to offer 1,4 adducts in good yields (up to 95% yield) and stereoselectivity (up to 99% ee) in the presence of Rh (Ι) catalyst.
Futhermore, in the presence of Rh(Ι)/L1a the enantioselective allyation of cyclic N-sulfonyl ketimine of 21 proceeds via 1,2-addition fashion, offering the corresponding products in up to 99% yield and 99.5% ee.

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