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研究生: 陳昱勛
Chen, Yu-Hsun
論文名稱: 高結晶性天然鱗片石墨用於鋁離子電池之電化學分析及機制研究
The Electrochemical Characterization and Mechanism Study of High-Crystalline Natural Flake Graphite Applied on Aluminum-Ion Battery
指導教授: 陳家俊
Chen, Chia-Chun
學位類別: 碩士
Master
系所名稱: 化學系
Department of Chemistry
論文出版年: 2016
畢業學年度: 104
語文別: 中文
論文頁數: 85
中文關鍵詞: 鋁離子電池XRDRamanXAS
英文關鍵詞: Aluminum ion battery, XRD, Raman, XAS
DOI URL: https://doi.org/10.6345/NTNU202203550
論文種類: 學術論文
相關次數: 點閱:156下載:0
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  • 隨著能源問題日漸嚴重,對於電能儲存的開發越來越受到重視。次世代的電池目標是低成本、高充放電速率、高穩定性且具有高能量及功率密度。為了達到以上目標,我們發展出具有高安全性的鋁離子電池系統。鋁金屬的氧化還原由三個電子進行,所以鋁金屬能提供更高的能量密度,且具有無汙染等優點。
    先前本團隊研究利用天然鱗片石墨作為鋁離子電池的陰極,具有高電量、高電位平台,且在長圈數的循環下電量並無衰退,而本研究主要探討為鋁離子電池在進行充放電的過程中,石墨與氯鋁酸鹽離子間的關係,因此利用各種不同電位下探討其中的反應機制,藉由in-situ XRD、in-situ Raman、XAS等分析證明氯鋁酸鹽離子嵌入嵌出於石墨層間,最後再以用密度泛函理論(DFT)和第一計算來模擬AlCl4-陰離子與石墨間的行為表現。
    另外,對鋁離子電池做參數的調整,例如改變石墨負載量、不同材質隔離膜及觀察在不同環境溫度下對鋁離子電池的電化學表現。

    With the energy issues, electrochemical energy storage is an important issue for future technology development. The goals of the next generational battery are low cost, high-rate charging, high stability, high energy and power density. To meet this requirement, we developed aluminum ion battery which is a high safety and low cost battery system. With three-electron redox anode reaction, aluminum ion battery has higher energy and power density. For the environmental issues, the battery system is without pollution and poison.
    In our early work, we used natural flake graphite as cathode for AIB. The performance of the graphite cathode was high capacity, high voltage plateau and without decay after thousands of cycles. The purpose of this study was to investigate the interaction of AlCl4- and graphite cathode during charging. We dug deeper on the reaction mechanisms with in situ XRD, in-situ Raman and XAS. Finally, we used DFT and first principle method to confirm the reaction between graphite and AlCl4-.
    Besides, we observed the performance of AIB with different graphite loading, different kind of separators and charging at various temperatures.

    目 錄 I 表目錄 IX 摘 要 X Abstract XI 謝 誌 XII 第一章. 緒論 1 1-1. 前言: 1 1-2. 鋁離子電池發展 2 1-3. 鋁離子電池與鋰離子電池的比較 3 1-4. 鋁離子電池的理論電容、功率與能量密度計算 5 第二章. 工作原理與文獻回顧 6 2-1. 鋁離子電池工作原理 6 2-2. 離子液體介紹與優勢 8 2-2-1. AlCl3型離子液體的發展及應用 10 2-2-2. 鋁離子二次電池之電解液限制 12 2-3. 鋁負極材料的改進方法 13 2-3-1. 鋁負極的活化與抗腐蝕 13 2-3-2. 鋁負極枝晶形成和抑制 14 2-4. 鋁離子電池正極材料研究與探討 15 2-4-1. 二氧化錳 (MnO2) 15 2-4-2. 釩氧化物 16 2-4-3. 有機多硫化物 20 2-4-4. 硫化物 21 2-4-5. 導電聚合物 24 2-4-6. 鋰鐵磷酸(LiFePO4) 25 2-4-7. 石墨(Graphite) 26 2-5. 隔離膜簡介 30 第三章. 研究動機與實驗內容 32 3-1. 研究動機 32 3-2 實驗藥品 33 3-3 儀器設備 34 3-4. 材料鑑定分析 38 3-4-1. XRD (X-ray Diffraction)粉末繞射分析 38 3-4-1. 拉曼光譜分析儀 39 3-4-2. 掃描式電子顯微鏡(Scanning Electron Microscopy, SEM) 41 3-4-3. X光吸收光譜近邊緣結構(X-ray absorption near edge structure; XANES) 42 3-5. 石墨電極的製備(碳纖維紙) 44 3-6. Free-Standing 石墨電極製備 45 3-7. 軟包電池(Pouch cell)的組裝 46 3-8. 離子液體電解液製備 47 3-9. 軟包電池一般充放電之電化學測試 48 3-10 變溫測試裝置 49 3-11. 交流阻抗分析 51 第四章. 結果與討論 52 4-1. 原位X射線繞射圖(in-situ XRD) 52 4-2. 原位拉曼光譜(in-situ Raman Spectrum) 55 4-3. X光吸收光譜( C K-edge XAS) 58 4-4. 密度泛函理論(DFT) 60 4-5.不同石墨負載量對鋁離子電池的影響 62 4-6. 以不同材質隔離膜對鋁離子電池的影響 66 4-7. 以不同溫度下對鋁離子電池的影響 70 第五章. 總結與未來展望 79 參考文獻 81

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