簡易檢索 / 詳目顯示

研究生: 黃依涵
Huang, Yi-Han
論文名稱: 鋯金屬有機骨架無序到結晶化的快速轉換
Rapid Amorphous to Crystalline Transition of Zr (Ⅳ) Metal-Organic Frameworks
指導教授: 林嘉和
Lin, Chia-Her
口試委員: 陳登豪
Chen, Teng-Hao
蔡明剛
Tsai, Ming-Kang
林嘉和
Lin, Chia-Her
口試日期: 2023/05/26
學位類別: 碩士
Master
系所名稱: 化學系
Department of Chemistry
論文出版年: 2023
畢業學年度: 111
語文別: 中文
論文頁數: 109
中文關鍵詞: 金屬有機骨架雙溶劑置換加熱抽真空結晶化
英文關鍵詞: Metal-Organic Framework, Two Solvent Exchange, Heat under Vacuum, Crystallization
研究方法: 實驗設計法
DOI URL: http://doi.org/10.6345/NTNU202300567
論文種類: 學術論文
相關次數: 點閱:159下載:0
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報
  • 第一章緒論 1 1-1MOF 介紹 1 1-2MOF缺陷 5 1-3鋯 MOF介紹 9 UiO-66 12 UiO-66-NH2 17 MOF-808 18 1-4MOF結晶化現象 21 1-5研究動機 24 第二章實驗與儀器 25 2-1實驗藥品 25 2-2儀器操作 27 粉末X光繞射儀 (PXRD) 27 場發式掃描電子顯微鏡 (FE-SEM) 27 比表面積及空隙分析儀 28 熱重分析儀(TGA) 28 2-3MOF合成與活化 29 UiO-66之合成 29 UiO-66-NH2之合成 29 MOF-808之合成 30 MOF純化與活化 30 第三章結果與討論 31 3-1非晶相轉晶相 31 粉末X光繞射 33 場發式掃描電子顯微鏡(FE-SEM) 38 比表面積及孔徑分析儀 41 3-2加熱迴流攪拌優化實驗 47 粉末X光繞射 48 場發式掃描電子顯微鏡(FE-SEM) 51 比表面積及孔徑分析儀 53 熱穩定性 58 3-3清洗方式與加熱的成效 61 粉末X光繞射 62 場發式掃描電子顯微鏡(FE-SEM) 71 比表面積及孔徑分析儀 75 熱穩定性 89 第四章結論與展望 94 參考文獻 96 附錄 100 Q&A 100

    1. Yaghi, O. M.; Li, H., Hydrothermal Synthesis of a Metal-Organic Framework Containing Large Rectangular Channels. Journal of the American Chemical Society 1995, 117, 10401-10402.
    2. Li, H.; Eddaoudi, M.; O'Keeffe, M.; Yaghi, O. M., Design and synthesis of an exceptionally stable and highly porous metal-organic framework. Nature 1999, 402, 276-279.
    3. Chui, S. S.-Y.; Lo, S. M.-F.; Charmant, J. P. H.; Orpen, A. G.; Williams, I. D., A Chemically Functionalizable Nanoporous Material [Cu3(TMA)2(H2O)3]n. Science 1999, 283, 1148-1150.
    4. Férey, G.; Mellot-Draznieks, C.; Serre, C.; Millange, F.; Dutour, J.; Surblé, S.; Margiolaki, I., A chromium terephthalate-based solid with unusually large pore volumes and surface area. Science 2005, 309, 2040-2.
    5. Horike, S.; Shimomura, S.; Kitagawa, S., Soft porous crystals. Nature Chemistry 2009, 1, 695-704.
    6. Horike, S.; Nagarkar, S. S.; Ogawa, T.; Kitagawa, S., A New Dimension for Coordination Polymers and Metal–Organic Frameworks: Towards Functional Glasses and Liquids. Angewandte Chemie International Edition 2020, 59, 6652-6664.
    7. Krause, S.; Hosono, N.; Kitagawa, S., Chemistry of Soft Porous Crystals: Structural Dynamics and Gas Adsorption Properties. Angewandte Chemie International Edition 2020, 59, 15325-15341.
    8. Fang, Z.; Bueken, B.; De Vos, D. E.; Fischer, R. A., Defect-Engineered Metal–Organic Frameworks. Angewandte Chemie International Edition 2015, 54, 7234-7254.
    9. Kozachuk, O.; Meilikhov, M.; Yusenko, K.; Schneemann, A.; Jee, B.; Kuttatheyil, A. V.; Bertmer, M.; Sternemann, C.; Pöppl, A.; Fischer, R. A., A Solid-Solution Approach to Mixed-Metal Metal–Organic Frameworks – Detailed Characterization of Local Structures, Defects and Breathing Behaviour of Al/V Frameworks. European Journal of Inorganic Chemistry 2013, 2013, 4546-4557.
    10. Chen, X.; Lyu, Y.; Wang, Z.; Qiao, X.; Gates, B. C.; Yang, D., Tuning Zr12O22 Node Defects as Catalytic Sites in the Metal–Organic Framework hcp UiO-66. ACS Catalysis 2020, 10, 2906-2914.
    11. Choi, K. M.; Jeon, H. J.; Kang, J. K.; Yaghi, O. M., Heterogeneity within Order in Crystals of a Porous Metal–Organic Framework. Journal of the American Chemical Society 2011, 133, 11920-11923.
    12. Schaate, A.; Roy, P.; Godt, A.; Lippke, J.; Waltz, F.; Wiebcke, M.; Behrens, P., Modulated Synthesis of Zr-Based Metal–Organic Frameworks: From Nano to Single Crystals. Chemistry – A European Journal 2011, 17, 6643-6651.
    13. Cai, G.; Jiang, H. L., A Modulator-Induced Defect-Formation Strategy to Hierarchically Porous Metal-Organic Frameworks with High Stability. Angew Chem Int Ed Engl 2017, 56, 563-567.
    14. Burtch, N. C.; Jasuja, H.; Walton, K. S., Water Stability and Adsorption in Metal–Organic Frameworks. Chemical Reviews 2014, 114, 10575-10612.
    15. Nguyen, J. G.; Cohen, S. M., Moisture-Resistant and Superhydrophobic Metal−Organic Frameworks Obtained via Postsynthetic Modification. Journal of the American Chemical Society 2010, 132, 4560-4561.
    16. Decoste, J. B.; Peterson, G. W.; Smith, M. W.; Stone, C. A.; Willis, C. R., Enhanced Stability of Cu-BTC MOF via Perfluorohexane Plasma-Enhanced Chemical Vapor Deposition. Journal of the American Chemical Society 2012, 134, 1486-1489.
    17. Yang, S. J.; Park, C. R., Preparation of Highly Moisture-Resistant Black-Colored Metal Organic Frameworks. Advanced Materials 2012, 24, 4010-4013.
    18. Yuan, S.; Feng, L.; Wang, K.; Pang, J.; Bosch, M.; Lollar, C.; Sun, Y.; Qin, J.; Yang, X.; Zhang, P.; Wang, Q.; Zou, L.; Zhang, Y.; Zhang, L.; Fang, Y.; Li, J.; Zhou, H.-C., Stable Metal–Organic Frameworks: Design, Synthesis, and Applications. Advanced Materials 2018, 30, 1704303.
    19. Cavka, J. H.; Jakobsen, S.; Olsbye, U.; Guillou, N.; Lamberti, C.; Bordiga, S.; Lillerud, K. P., A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability. Journal of the American Chemical Society 2008, 130, 13850-13851.
    20. Yuan, S.; Qin, J.-S.; Lollar, C. T.; Zhou, H.-C., Stable Metal–Organic Frameworks with Group 4 Metals: Current Status and Trends. ACS Central Science 2018, 4, 440-450.
    21. Low, J. J.; Benin, A. I.; Jakubczak, P.; Abrahamian, J. F.; Faheem, S. A.; Willis, R. R., Virtual High Throughput Screening Confirmed Experimentally: Porous Coordination Polymer Hydration. Journal of the American Chemical Society 2009, 131, 15834-15842.
    22. Devic, T.; Serre, C., High valence 3p and transition metal based MOFs. Chemical Society Reviews 2014, 43, 6097-6115.
    23. Zhang, M.; Chen, Y.-P.; Bosch, M.; Gentle Iii, T.; Wang, K.; Feng, D.; Wang, Z. U.; Zhou, H.-C., Symmetry-Guided Synthesis of Highly Porous Metal–Organic Frameworks with Fluorite Topology. Angewandte Chemie International Edition 2014, 53, 815-818.
    24. Pearson, R. G., Hard and Soft Acids and Bases. Journal of the American Chemical Society 1963, 85, 3533-3539.
    25. Lee, D. B. N.; Roberts, M.; Bluchel, C. G.; Odell, R. A., Zirconium: Biomedical and Nephrological Applications. ASAIO Journal 2010, 56.
    26. Yao, C.-X.; Zhao, N.; Liu, J.-M.; Fang, G.-Z.; Wang, S. Ultra-Stable UiO-66 Involved Molecularly Imprinted Polymers for Specific and Sensitive Determination of Tyramine Based on Quartz Crystal Microbalance Technology Polymers, 2020.
    27. Shearer, G. C.; Chavan, S.; Ethiraj, J.; Vitillo, J. G.; Svelle, S.; Olsbye, U.; Lamberti, C.; Bordiga, S.; Lillerud, K. P., Tuned to Perfection: Ironing Out the Defects in Metal–Organic Framework UiO-66. Chemistry of Materials 2014, 26, 4068-4071.
    28. Tsuruoka, T.; Furukawa, S.; Takashima, Y.; Yoshida, K.; Isoda, S.; Kitagawa, S., Nanoporous Nanorods Fabricated by Coordination Modulation and Oriented Attachment Growth. Angewandte Chemie International Edition 2009, 48, 4739-4743.
    29. Umemura, A.; Diring, S.; Furukawa, S.; Uehara, H.; Tsuruoka, T.; Kitagawa, S., Morphology Design of Porous Coordination Polymer Crystals by Coordination Modulation. Journal of the American Chemical Society 2011, 133 , 15506-15513.
    30. Katz, M. J.; Brown, Z. J.; Colón, Y. J.; Siu, P. W.; Scheidt, K. A.; Snurr, R. Q.; Hupp, J. T.; Farha, O. K., A facile synthesis of UiO-66, UiO-67 and their derivatives. Chemical Communications 2013, 49, 9449-9451.
    31. Wu, H.; Chua, Y. S.; Krungleviciute, V.; Tyagi, M.; Chen, P.; Yildirim, T.; Zhou, W., Unusual and Highly Tunable Missing-Linker Defects in Zirconium Metal–Organic Framework UiO-66 and Their Important Effects on Gas Adsorption. Journal of the American Chemical Society 2013, 135, 10525-10532.
    32. Klet, R. C.; Liu, Y.; Wang, T. C.; Hupp, J. T.; Farha, O. K., Evaluation of Brønsted acidity and proton topology in Zr- and Hf-based metal–organic frameworks using potentiometric acid–base titration. Journal of Materials Chemistry A 2016, 4, 1479-1485.
    33. Kazemi, S.; Safarifard, V., Carbon dioxide capture in MOFs: The effect of ligand functionalization. Polyhedron 2018, 154, 236-251.
    34. Cohen, S. M., Postsynthetic Methods for the Functionalization of Metal–Organic Frameworks. Chemical Reviews 2012, 112, 970-1000.
    35. Dai, S.; Nouar, F.; Zhang, S.; Tissot, A.; Serre, C., One-Step Room-Temperature Synthesis of Metal(IV) Carboxylate Metal—Organic Frameworks. Angewandte Chemie International Edition 2021, 60, 4282-4288.
    36. Luu, C. L.; Nguyen, T. T. V.; Nguyen, T.; Hoang, T. C., Synthesis, characterization and adsorption ability of UiO-66-NH2. Advances in Natural Sciences: Nanoscience and Nanotechnology 2015, 6, 025004.
    37. Chen, Q.; He, Q.; Lv, M.; Xu, Y.; Yang, H.; Liu, X.; Wei, F., Selective adsorption of cationic dyes by UiO-66-NH2. Applied Surface Science 2015, 327, 77-85.
    38. Furukawa, H.; Gándara, F.; Zhang, Y.-B.; Jiang, J.; Queen, W. L.; Hudson, M. R.; Yaghi, O. M., Water Adsorption in Porous Metal–Organic Frameworks and Related Materials. Journal of the American Chemical Society 2014, 136, 4369-4381.
    39. Park, B. H.; Jung, Y.; Kim, S., Particle Size Control Influence on the Electrochemical Properties of Sulfur Deposited on Metal Organic Frameworks Host Electrodes. Journal of Inorganic and Organometallic Polymers and Materials 2021, 31, 1931-1938.
    40. Liu, X.; Chee, S. W.; Raj, S.; Sawczyk, M.; Král, P.; Mirsaidov, U., Three-step nucleation of metal–organic framework nanocrystals. Proceedings of the National Academy of Sciences 2021, 118.
    41. Loiseau, T.; Serre, C.; Huguenard, C.; Fink, G.; Taulelle, F.; Henry, M.; Bataille, T.; Férey, G., A Rationale for the Large Breathing of the Porous Aluminum Terephthalate (MIL-53) Upon Hydration. Chemistry – A European Journal 2004, 10, 1373-1382.
    42. Zhang, X.; Chen, Z.; Liu, X.; Hanna, S. L.; Wang, X.; Taheri-Ledari, R.; Maleki, A.; Li, P.; Farha, O. K., A historical overview of the activation and porosity of metal–organic frameworks. Chemical Society Reviews 2020, 49, 7406-7427.
    43. Lo, S.-H.; Feng, L.; Tan, K.; Huang, Z.; Yuan, S.; Wang, K.-Y.; Li, B.-H.; Liu, W.-L.; Day, G. S.; Tao, S.; Yang, C.-C.; Luo, T.-T.; Lin, C.-H.; Wang, S.-L.; Billinge, S. J. L.; Lu, K.-L.; Chabal, Y. J.; Zou, X.; Zhou, H.-C., Rapid desolvation-triggered domino lattice rearrangement in a metal–organic framework. Nature Chemistry 2020, 12, 90-97.

    無法下載圖示 電子全文延後公開
    2024/12/31
    QR CODE