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研究生: 周文傑
CHOU,WEN-CHIEH
論文名稱: 乳化燃料添加不同比例奈米Al2O3之柴油引擎性能研究
Study of the effect using different proportions of Nano-Al2O3 emulsion fuel in Diesel Engine Performance
指導教授: 呂有豐
Lue, Yeou-Feng
洪翊軒
Hung, Yi-Huan
學位類別: 碩士
Master
系所名稱: 工業教育學系
Department of Industrial Education
論文出版年: 2015
畢業學年度: 103
語文別: 中文
論文頁數: 85
中文關鍵詞: 奈米流體生質柴油乳化燃料柴油引擎
英文關鍵詞: nanofluid, biodiesel, emulsified fuel, diesel engine
論文種類: 學術論文
相關次數: 點閱:43下載:3
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  • 本研究主要在研發奈米添加劑於柴油乳化燃料,藉以提升柴油引擎的性能。針對此一問題,將採用直接混合法製造不同重量濃度的奈米Al2O3流體。奈米Al2O3具有較佳的懸浮特性,比較不易發生阻塞與磨損管路的問題。接著將不同濃度的Al2O3/Water奈米流體與市售柴油調配最佳比例的奈米高效能柴油乳化燃料,作為柴油引擎使用之奈米柴油乳化燃料。接著針對該流體的物化性質如熱值、密度、動黏度、潤滑性與HLB值等基本特性進行分析,並探討不同掺配比例奈米添加劑於柴油乳化燃料穩定性之影響。
    最後再實際以動力計,進行柴油引擎試驗,藉以評估各種不同濃度奈米添加劑柴油乳化燃料的引擎性能與排放特性。實驗結果顯示無論在BSFC、Smoke濃度值、HC濃度值、NOx濃度值和EGT值,均較不加任何奈米Al2O3的水乳化柴油低,故由實驗證明,在水乳化柴油中,添加適當比例的奈米Al2O3,對柴油引擎廢氣的排放減低有顯著的效果。

    The purpose of this study is to research and produce a high performance emulsion fuel for biodiesel containing nanoadditives, which can be used on the existent diesel engines for performance improvement. In this work, research will be held on direct synthesis method to produce Al2O3/water nanofluid. According to the previous study, Al2O3 has the better performance of suspension, so it has fewer problems for Al2O3 to be used in nanofluids. This Al2O3/water nanofluid will be mixed with commercial biodiesl for the solutions of optimum proportions, which are used as nanoadditives emulsion fuel for diesel engine vehicle. Next, the fundamental physicochemical properties of the emulsions, including calorific value, density, kinematic viscosity,lubricity and HLB values will be measured, analyzed and evaluated for the performance of nanoadditive biodiesel emulsion fuel property.
    The present work attempts to study the effect factors of stability of emulsion fuel by investigating the influence of adding Al2O3 nanoparticles to biodiesel, in order to confirm the emulsionfication performance and practicability. In the other work, the investigations are carried out to study the performance, emission, and combustion characteristics of a single cylinder diesel engine using biodiesel, water–biodiesel emulsion fuel, and the alumina nanofluid blended biodiesel emulsion fuels. The operating characteristics of diesel engines with dynamometer performance testing will be measured, which in including bsfc, bmep and emissions(NOx and smoke) will be measured, analyzed and evaluated for the performance of nanoadditive biodiesel emulsion fuels for diesel engine application.

    目錄 摘 要 i ABSTRACT ii 致謝 iii 目錄 iv 表目錄 vi 圖目錄 vii 第一章 緒論 1 1.1前言 1 1.2研究動機及目的 3 1.3研究方法 5 1.4研究範圍與限制 6 第二章 文獻探討 7 2.1 乳化燃料與節能減排機制 7 2.1.1 乳化燃料之發展 7 2.1.2 乳化燃料的選擇 9 2.1.3 乳化燃料的燃燒與節能減排機制 9 2.2乳化燃料的製造 10 2.2.1 乳化燃料 10 2.2.2 乳化劑 11 2.2.3 均質機 12 2.2.4 生質柴油乳化燃料 13 2.3奈米流體 13 2.3.1 奈米流體的製備與分散技術 13 2.3.2奈米添加劑改善生質柴油乳化燃料 14 2.4引擎性能 16 第三章 實驗材料與方法 18 3.1乳化燃料的調配 18 3.1.1基礎油 18 3.1.2界面活性劑與HLB值選擇 19 3.1.3相關設備 19 3.1.4奈米流體及奈米乳化燃料 20 3.1.5奈米乳化燃料調配步驟 23 3.2奈米乳化燃料特性與試驗 24 3.2.1熱值試驗 24 3.2.2密度試驗 25 3.2.3動黏度試驗 25 3.2.4潤滑性試驗 26 3.3引擎性能實驗設備 27 3.3.1實驗用柴油引擎規格 29 3.3.2引擎馬力試驗機 30 3.3.3其他實驗設備 31 3.3.4實驗方法 35 第四章 結果與討論 36 4.1奈米乳化燃料的性質 36 4.1.1熱值 36 4.1.2密度 38 4.1.3動黏度 40 4.1.4潤滑性 42 4.1.5乳化燃料沉澱觀察 44 4.2奈米乳化柴油的引擎性能與排放特性 46 4.2.1引擎性能 46 4.2.2排放特性 47 4.3奈米乳化生質柴油的引擎性能與排放特性 53 4.3.1引擎性能 53 4.3.2排放特性 56 4.4奈米乳化柴油和奈米乳化生質柴油比較 64 4.4.1引擎性能比較 64 4.4.2排放特性比較 66 第五章 結論與建議 77 5.1奈米乳化燃料的調配與特性 77 5.2引擎性能和排放特性 78 5.3建議 80 參考文獻 81 表目錄 表3.1 超級柴油(SD)的性質檢驗 18 表3.2 B10生質柴油(BD)的性質檢驗 18 表3.3 B100生質柴油的性質檢驗 18 表3.4 實驗用設備 19 表3.5 全自動熱量計規格 20 表3.6 奈米Al2O3粉末性質表 21 表3.7 奈米乳化柴油 單位:ml 22 表3.8 奈米乳化生質柴油 單位:ml 22 表3.9 實驗設備一覽表 27 表3.10 實驗柴油引擎規格 29 表4.1 奈米乳化柴油熱值 36 表4.2 奈米乳化生質柴油熱值 37 表4.3 奈米乳化柴油密度 38 表4.4 奈米乳化生質柴油密度 39 表4.5 奈米乳化柴油動黏度 40 表4.6 奈米乳化生質柴油動黏度 41 表4.7 奈米乳化柴油潤滑性 42 表4.8 奈米乳化生質柴油潤滑性 43 表4.9 BSFC之平均值比較 53 表4.10 BMEP之平均值比較 55 表4.11 NOx之平均值比較 56 表4.12 Smoke之平均值比較 58 表4.13 HC之平均值比較 60 表4.14 EGT之平均值比較 62 圖目錄 圖2.1 乳化設備系統圖 11 圖3.1 均質機 20 圖3.2 自動熱量計 20 圖3.3 奈米Al2O3粉末 21 圖3.4 生質柴油添加界面活性劑 23 圖3.5 生質柴油添加奈米流體 23 圖3.6 均質機攪拌 24 圖3.7 熱量計量測鋼瓶 24 圖3.8 實驗設備配置圖 28 圖3.9 SCHENCK D-230-1E 引擎馬力試驗機 30 圖3.10 MODEL 400 CLD NOx分析儀 31 圖3.11 MODEL 300 HFID/MHFID HC分析儀 32 圖3.12 IYASAKA GSM-2 黑煙濃度計 33 圖3.13 排氣溫度感知器 34 圖4.1 奈米乳化柴油熱值 36 圖4.2 奈米乳化生質柴油熱值 37 圖4.3 奈米乳化柴油密度 38 圖4.4 奈米乳化生質柴油密度 39 圖4.5 奈米乳化柴油動黏度 40 圖4.6 奈米乳化生質柴油動黏度 41 圖4.7 奈米乳化柴油潤滑性 42 圖4.8 奈米乳化生質柴油潤滑性 43 圖4.9 奈米乳化柴油沉澱觀察範例 44 圖4.10 奈米乳化生質柴油沉澱觀察範例 44 圖4.11 奈米乳化柴油沉澱 45 圖4.12 奈米乳化生質柴油沉澱 45 圖4.13 奈米乳化柴油BSFC值 47 圖4.14 奈米乳化柴油NOX值 48 圖4.15 奈米乳化柴油Smoke值 49 圖4.16 奈米乳化柴油HC值 51 圖4.17 奈米乳化柴油EGT值 52 圖4.18 奈米乳化生質柴油BSFC值 54 圖4.19 奈米乳化生質柴油BMEP值 55 圖4.20 奈米乳化生質柴油NOX值 57 圖4.21 奈米乳化生質柴油Smoke值 59 圖4.22 奈米乳化生質柴油HC值 61 圖4.23 奈米乳化生質柴油EGT值 63 圖4.24 奈米乳化柴油和奈米乳化生質柴油BSFC比較 66 圖4.25 奈米乳化柴油和奈米乳化生質柴油NOx比較 69 圖4.26 奈米乳化柴油和奈米乳化生質柴油Smoke比較 71 圖4.27 奈米乳化柴油和奈米乳化生質柴油HC比較 74 圖4.28 奈米乳化柴油和奈米乳化生質柴油EGT比較 76

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