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研究生： 林岳興
Lin, Yueh-Hsin
論文名稱： 利用偶氮染料做為次氯酸鈉指示劑的開發與研究
Development of Sodium Hypochlorite Indicator by Azo Dyes
指導教授： 林震煌
Lin, Cheng-Huang
口試委員： 何佳安
He, Jia-An
李君婷
Li, Jun-Ting
林震煌
Lin, Cheng-Huang
口試日期： 2022/06/15
學位類別： 碩士
Master
系所名稱： 化學系
Department of Chemistry
論文出版年： 2022
畢業學年度： 110
語文別： 中文
論文頁數： 90
中文關鍵詞： 偶氮染料 、酸性橙7 、次氯酸鈉 、消毒 、紫外可見光譜儀
英文關鍵詞： azo dyes, acid orange 7, sodium hypochlorite, disinfection, UV-Vis spectrometer
研究方法: 實驗設計法 、 比較研究 、 觀察研究
DOI URL： http://doi.org/10.6345/NTNU202200937
論文種類： 學術論文
相關次數： 點閱：93  下載：0 
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    • 摘要 i Abstract ii 目次 iii 表次 vi 圖次 vii 第一章 緒論 1 1-1 研究目的 1 1-2 次氯酸鈉介紹 2 1-2-1 次氯酸鈉歷史 2 1-2-2 次氯酸鈉消毒的作用與限制 3 1-3 偶氮染料介紹 5 1-3-1 偶氮染料歷史 5 1-3-2 偶氮染料的分類-偶氮基的數目 6 1-3-3 偶氮染料的分類-官能基與應用性能 7 第二章 分析原理及方法 9 2-1 紫外光-可見光譜儀 9 2-1-1 紫外光-可見光譜儀構造 10 2-1-2 次氯酸鈉的紫外-可見光光圖譜 13 2-2 吸光光度計（Photo Absorbance Meter） 14 2-2-1 吸光光度計儀器構造 14 2-3 液相層析電噴灑游離質譜儀（LC/ESI-MS） 16 2-4 次氯酸鈉漂白原理 17 第三章 儀器、藥品與實驗方法 18 3-1 儀器參數 18 3-1-1 紫外可見光譜儀 18 3-1-2 手持式可見光光譜儀 19 3-1-3 液相層析質譜儀（LC/ESI-MS） 21 3-1-4 其他器材列表 22 3-2 藥品列表 24 3-3 實驗方法 26 第四章 結果與討論 27 4-1 偶氮染料對次氯酸鈉檢測範圍 27 4-1-1 直接染料D01凍黃（Direct Yellow 1）27 4-1-2 直接染料D08桃紅（Direct Red 8） 31 4-1-3 直接染料D10牡丹（Direct Red 10） 35 4-1-4 直接染料D11紫醬（Direct Red 11） 39 4-1-5 直接染料D14深藍（Direct Blue 14） 43 4-1-6 直接染料D22翠藍（Direct Blue 22） 47 4-1-7 酸性橙7（Acid Orange 7） 51 4-1-8 本節總整理與討論 56 4-2 六種偶氮染料與次氯酸鈉的反應時間 58 4-3 六種偶氮染料之熱穩定性 62 4-4 七種偶氮染料之篩選結果 66 4-5 酸性橙7延伸研究 66 4-5-1 固態酸性橙7附著於樣品槽的開發 66 4-5-2 酸性橙7與次氯酸鈉的pH值 70 4-5-3 酸性橙7與次氯酸鈉反應動力學探討 72 4-5-4 酸性橙7與次氯酸鈉的反應機制探討 77 第五章 結論 82 參考資料 83

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