研究生: |
高建群 |
---|---|
論文名稱: |
兩性分散劑的合成及對鈦酸鋇漿體分散性質的影響 |
指導教授: | 許貫中 |
學位類別: |
碩士 Master |
系所名稱: |
化學系 Department of Chemistry |
論文出版年: | 2007 |
畢業學年度: | 95 |
語文別: | 中文 |
中文關鍵詞: | 鈦酸鋇 、共聚物 、合成 、分散性質 |
論文種類: | 學術論文 |
相關次數: | 點閱:196 下載:0 |
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本篇論文主要是合成一種兩性共聚物,聚(甲基丙烯醯胺-氮-[3- (二甲基胺)-丙基醋酸鈉]-甲基丙烯醯胺,探討不同分子量之PDSM對於鈦酸鋇BT水系漿體分散性質的影響,並與Darvan C比較。本研究中合成之共聚物以1H-NMR及FTIR確認其結構並利用GPC測得四種PDSM之分子量,並以電位滴定儀測量單體比例及解離率。
將合成之PDSM添加於BT漿體中,經由測試流變行為、界達電位、粒徑分佈等方法來探討漿體之穩定性,並量測BT漿體中鋇離子的溶出。實驗結果顯示添加PDSM (Mw=2.5×105) 在漿體的分散效果優於其他分子量,因PDSM (Mw=2.5×105) 使得漿體有較低的黏度、較大的界達電位、較小的粒徑分佈及鋇離子溶出量減少,其分散效果和Darvan C相近,故添加此共聚物能夠使漿體達到良好分散且穩定之效果;經過壓胚、燒結後的胚體之密度及介電常數均較Darvan C高,顯示PDSM (Mw=2.5×105) 對BT漿體有很好的分散效果。
[1] J. Davies and J.G..P. Binner, “The role of ammonium polyacrylate in dispersing concentratedalumina suspensions,” J. Eur. Ceram. Soc. 20 (2000) 1539-1553
[2] K.W. Kirby and B.A. Wechsler, “Phase relations in bartium titanate-titanate oxide system,” J. Am. Ceram. Soc., 74 (1991) 1841 - 1846
[3] A.L. Jennifer, “Colloidal processing of ceramics,” J. Am. Ceram. Soc., 83 (2000) 2341 - 2359
[4] 王惠民,“兩性高分子對黏土粒子行為之影響”,國立成功大學化工研究所碩士論文, 1994。
[5] G..D. Parfitt, “Dispersion of powders in liquids,” 3ed. ed. Appl Sci. Pub,Inc.,New Jersey, (1981)
[6] J.H. Jean and H.R. Wang, “Dispersion of aqueous barium titanate suspensions with ammonium salt of poly(methacrylic acid)” J. Am. Ceram. Soc., 81 (1998) 1589 -1599
[7] Z.G. Shen, J.F. Chen, H.K. Zou and J. Yun, “Dispersion of nanosized aqueous suspensions of barium titanate with ammonium polyacrylate,” J. Colloid. Inter. Sci. 275 (2004) 158–164
[8] 吳杏璇,“添加陰離子型分散劑之鈦酸鋇漿體在不同pH值下的分散行為” 國立台灣師範大學化學研究所碩士論文, 2004。
[9] C.C. Li and J.H. Jean., “Interaction between dissolved Ba2+ and PAA-NH4 dispersant in aqueous barium titanate suspensions,” J.Am.Ceram.Soc.,. 85 (2002) 1449–1455
[10] J.H. Jean. and H.R. Wang, “Effects of solids loading, pH, and polyelectrolyte addition on the stabilization of concentrared aqueous BaTiO3 suspensions” J. Am. Ceram. Soc., 83 (2000) 277 - 280
[11] J. Zhao, X. Wang, Z. Gui and L. Li, “Dispersion of barium titanate with poly(acrylic acid-co-maleic acid) in aqueous media,” Ceram. Int. 30 (2004) 1985–1988
[12] M.R.B. Romdhane, S. Baklouti, J. Bouaziz, T. Chartier and J.F. Baumard, “Dispersion of Al2O3 concentrated suspensions with new molecules able to act as binder,” J. Eur. Ceram. Soc. 24 (2004) 2723–2731
[13] G.H. Hsiue., W.C. Li and I.N. Lin, “Optimized phosphate ester structure for the dispersion of nano-sized barium titanate in proper non-aqueous media,” Colloids Surf. A. 294 (2007) 212–220
[14] X. Wang, B.I. Lee and L. Mann, “Dispersion of barium titanate with polyaspartic acid in aqueous media,” Colloids Surf. A 202 (2002) 71–80
[15] 劉鳳錦,“鈦酸鋇的溶膠凝膠程序”, 國立臺灣工業技術學院工程技術研究所化學工程組碩士論文,1987
[16] Y.L. Sonng, X.L. Liu and J.F. Chen, “The maximum solid loading and viscosity estimation of ultra-fine BaTiO3 aqueous suspensions,” Colloids. Surf. A. 247 (2004) 27–34
[17] K. Kudaka, K. Iizumi and K. Sasaki,“Preparation of stoichiometric barium titanyl tetahydrate”, J. Am. Ceram. Soc.,Bull,61〔11〕(1982) 1236
[18] K.S. Mazdiyasni and L.M.Brown“Synthesis of Nb2O5-Doped with BaTiO3 improved electrical properties” J. Am. Ceram. Soc.,55〔12〕(1972) 633-34
[19] K.S. Mazdiyasni,“Fine particle peroveskite processing”, J. Am. Ceram. Soc.,Bull,63〔4〕(1984) 591-94
[20] L.P. Chen , K.L. Ying and K.C. Hsu,“Amphibious water-soluble copolymer.I.Its synthesis and dispersing ability on barium titanate”, J. Appl. poly. Sci. ,92 (2004) 2232-2239
[21] C.W. Chiang and J.H.Jean, “Effects of barium dissolution on dispersing aqueous barium titanate suspensions,” Mater. Chem. Phys. 80 (2003) 647–655
[22] D.H. Yoon and B.I. Lee., “Effects on aqueous barium titanate type poperties of passivation of barium ion leaching by using dispersant,” J. Eur. Ceram. Soc. 24 (2004) 3747–3752
[23] S. Baklouti and M.R.B. Romdhane., “Effects of copolymer dispersant structure on the poperties of alumina suspensions ” J. Eur. Ceram. Soc. 23 (2003) 905–911
[24] S.G. Malghan,“The stability of alumina-zirconia suspensions” Colloids. Surf. A. 133 (1998) 135-142
[25] M.C.B .Lόpez, B. Rand and F.L. Riley, “Polymeric stabilization of aqueous suspensions of barium titanate. Part I: Effect of pH,” J. Eur. Ceram. Soc. 20 (2000) 1579–1586
[26] K.L. Ying , K.C. Hsu and W. Cheng “An amphoteric water-soluble copolymer.II. Effect of its molecular weight on the dispersion of barium titanate in water”, J. Appl. Poly. Sci. ,100 (2006) 886-891
[27] W.J. Wei, S.J. Lu and B. Yu, “Characterization of submicron alumina dispersions with poly(methacrylic acid) polyelectrolyte,” J. Eur. Ceram. Soc. 15 (1995) 155-164
[28] M.C.B. Lόpez, B. Rand and F.L. Riley, “Polymeric stabilization of aqueous suspensions of barium titanate. Part II: effect of polyelectrolyte concentration,” J. Eur. Ceram. Soc. 20 (2000) 1587–1594
[29] Q. Zhang and W. Li , “Dispersion and rheological properties of concentrated silicon aqueous suspensions ” Powder Technology. 161 (2006) 130–134
[30] S. Boufi and S. Baklouti., “Interaction of cationic and anionic polyelectrolyte with SiO2 and Al2O3 powders” J. Eur. Ceram. Soc. 22 (2002) 1493–1500
[31] P.S. Bimal and M. Ruben, “Stability of dispersions of colloidal alumina particles in aqueous suspensions ,” J.Colloid. Inter. Sci. 291 (2005) 181–186
[32] T.S. Chartier, “Degradation of dispersant during milling,” J. Eur. Ceram. Soc. 16 (1996) 1283–1291
[33] F. Tang and T. Uchikoshi, “Effect of polyethylenimine on the dispersion and electrophoretic desposition of nano-sized titania aqueous suspensions ,” J. Eur. Ceram. Soc. 26 (2006) 1555–1560
[34] Z.C. Chen, T.A. Ring and J. Lemaître “Stabilization and processinf of aqueous BaTiO3 suspension with polyacrylic acid,” J. Am. Ceram. Soc., 75 (1992) 3201 - 3208
[35] U. Paik. “Influence of solids concentration on the isoelectric point of aqueous barium titanate,” J. Am. Ceram. Soc., 10 (2000) 2381 - 2384
[36] H.K. Glen and J.H. Daniel. “Poly(acrylic acid)-poly(ethylene oxide) comb polymer effects on BaTiO3 nanoparticle suspension stability ,” J. Am. Ceram. Soc., 87 (2004) 181 - 186
[37] C.S. Zhai and J. Wang “Influence of rheological behavior of aqueous Al2O3/mamo-TiO2 slurry on the characteristics of powders prepared by spray pelletization,” Mat. Sci. Eng. A., 392 (2005) 1 - 7
[38] Y. Fukuda and T. Togahi “Influence of additive content of anionic polymer dispersant on dense alumina suspension viscosity,” Chem. Eng. Sci., 56 (2001) 3005 - 3010
[39] H.T. Natliya and M.Y. Zinoviy “Influence of poly(methacrylic acid) on aggregative stability and electrical surface properties of aqueous susoensions of titanium dioxide,” Colloids. Sur. A., 279 (2006) 149 - 158
[40] J. Cesarano III and I.A. Aksay, “Stability of aqueous α-Al2O3 suspensions with poly(methacrylic acid) polyelectrolyte,” J. Am. Ceram. Soc., 4 (1988) 250-55
[41] M.R.B. Romdhane, B. Sami, B. Samir, C. Thierry and J.F. Baumard, “Dispersion of Al2O3 suspension with acrylic copolymers bearing carboxylic groups” Colloids. Surf. A . 212 (2003) 271-283
[42] N. Das and H.S. Maiti, “Effect of size distribution of the starting powder on the pore size and its distribution of tape cast alumina microporous membranes,” J. Eur. Ceram. Soc. 19(1999) 341-345
[43] M.C.B. Lόpez, B. Rand and F.L. Riley, “The properties of aqueous phase suspensions of barium titanate,” J. Eur. Ceram. Soc. 17 (1997) 281-287
[44] 應國良, “鈦酸鋇漿體分散劑的合成與應用” 國立台灣師範大學化學研究所碩士論文, 2003。
[45] 吳朗,“介電陶瓷” 全欣資訊圖書,1994。
[46] W.R. Buessem, L.E. Cross, and A.K. Goswami, “Phenomenological theory of high permittivity in fine-grained barium titanate,” J. Am. Ceram. Soc., 49 (1966) 33 – 36
[47] G. Arlt and D. Hennings,“Dielectric properties of fined-grained barium titanate,” J. Appl. Phys., 58 (1985) 1619-1625
[48] 蔡立瑜,“聚醯亞胺與鈦酸鋇奈米複合薄膜之製備及其介電特性之研究” 中原大學化學研究所碩士論文,2002。
[49] 傅勝利,“介電陶瓷” 陶瓷技術手冊上,中華民國粉末冶金協會,1994。
[50] 吳心玲,“氧化鋁漿體的穩定性研究” 國立成功大學化學工程研究所碩士論文, 2000。