研究生: |
黃國泰 Huang Kuo Tai |
---|---|
論文名稱: |
縮墨鑄鐵製程穩定性之研究 The Study of Compacted Graphite Cast Iron Process Stability |
指導教授: | 邱弘興 |
學位類別: |
碩士 Master |
系所名稱: |
工業教育學系 Department of Industrial Education |
論文出版年: | 2002 |
畢業學年度: | 90 |
語文別: | 中文 |
中文關鍵詞: | 縮墨鑄鐵 、穩定性 |
論文種類: | 學術論文 |
相關次數: | 點閱:427 下載:70 |
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本研究針對三種球化劑(KC合金、CG合金、稀土元素)在生產縮狀石墨鑄鐵時,所需添加量及在儘可能同一製程參數下了解金相組織和機械性質的穩定性,並探討以兩種不同退火處理的冷卻速度下所得基地組織之穩定性等情形作一研究。
實驗結果指出以CG合金球化劑生產縮墨鑄鐵所需添加含量為0.8%,KC合金球化劑生產縮墨鑄鐵所需添加含量為0.3%,稀土元素生產縮墨鑄鐵所需添加含量為0.45%,以上三種球化劑皆需添加0.2%的接種劑。經統計KC合金之縮墨率變異數為44.98標準差為6.71其值最小,且八個爐次縮墨率平均值為83.13%,所以添加KC合金所生產之縮墨鑄鐵縮墨率最高,製程最穩定。另外基地組織則以CG合金變異數17.41標準差4.17,值最小,穩定性最高。
由實驗結果得知以CG合金所生產之縮墨鑄鐵所獲得的機械性質普遍都較佳,穩定性也較高。縮墨鑄鐵在進行退火處理時,最後階段不管是爐冷至260℃再移至空冷或者直接進行空冷都不影響獲得完全肥粒鐵組織。
This paper is mainly focusing on the study of the amount of the three kinds of spheroidizing, KC alloys、CG alloys、Rare earths that is needed to produce the compacted graphite cast iron, and on the study of the stability in the process of producing optical microscope observation and mechanical property under as identical condition as possible. Besides, this paper will do the comparison between the stability of the two base structures under two different speed of annealing.
The results shows that the amount needed to produce the compacted graphite cast iron is 0.8% with CG alloy-spheroidizing, 0.3% with KC alloy-spheroidizing, 0.45% with Rare earths; and what’s more, the above three kinds of spheroidizing have to add 0.2% dose of inoculation. According to the gauging, the coefficient of variance of the KC alloys compacted rate of graphite is 44.98, and the standard deviation of it is 6.71, which is the smallest. In addition, the average figure of the eight-time experiment is 88.13% so to add KC alloys can produce.the highest the compacted rate of graphite of producing the compacted graphite cast iron, and have most stable processof producing it. moreover,the base structure that the coefficient of variance of CG alloys is 17.41,and the standard deviation of it is 4.17,which is the smallest, and have most stable.
From the results of the experiment, CG alloys can produce better mechanical property of the compacted graphite cast iron, and have more stable process of producing it. When the compacted graphite cast iron is under the process of the annealing, neither the temperature quenching down to 260°C in the stove before quenching in the air nor quenching the temperature directly in the air will have influence on getting the complete ferrite structure.
1. P.C.Liu , C.R.Loper, Jr, T..Kimura and E.N. Pan, “Observations on the Graphite Morphology of Compacted Graphite Cast Irons”, AFS Trans, Vol 89 1981,pp.65-78.
2. 葉源達 “縮墨鑄鐵之加工及實用” 中華民國鑄造學會,鑄工季刊,第45期,74年6月,p42-46。
3. H. Morrogh and W. J. Williams , “The Production of Nodular Graphite Structure in Cast Irons”, Journal of Iron and Steel Inst., 1948, pp306-324。
4. D.J. Reese,C. K. Donoho, G. Vennerholm and R. G. Mcelwee, “Symposium on Nodular Graphite Cast Iron,” AFS Trans., Vol.57,1949, pp. 576-578.
5. J.W. Estes and R.Schneidewind. “New High Strength Cast Iron Produced by Injection Methodism, “AFS Trans., Vol.63.1955, pp541-552
6. R.D. Schelleng, “Effect of Certain Elements on the Form of Graphite in Cast Iron,” AFS Trans., Vol.74, 1966, pp.700-708
7. E. R. Evans and J. V. Dawson, “An Alloy to Produce Compacted Graphite Irons by a Single Treatment, “BCIRA Journal, March 1975
8. T. Kimura, C.R. Loper, Jr. and H. H. Cornell,“Rare Earth Silicide Additions to Cast Iron,”AFS Trans., Vol.88,1980,pp.67-76.
9. T. Kimura,C.R. Loper, Jr., and H. H. Cornell,“Post Inoculation of Rare Earth Treated Compacted/Vermicular Graphite Cast Irons,” AFS Trans., Vol. 88, 1980, PP.443-500.
10. H. H. Cornell, C. R. Loper, Jr., and E. N. Pan,“Rare Earth Additions to Blast Furnace Iron for the Production of Large Castings,” Presented at the ASTM Symposium on Ferroalloys, Master Alloys and Other Liquid Metal Additives, May 20-22, 1980,Denver, Colorada.
11. T. Kimura, H. H. Cornell and C. R. Loper, Jr.,“Effect of Holding Time on Rare Earth Treated Cast Iron,” AFS Trans., Vol.89,1981, pp23-54.
12. E. N. Pan, K. Ogi, and C.R. Loper, Jr.,“Analysis of the Solidification Process of Compacted/Vermicular Graphite Cast Iron,” AFS Trans., Vol.90,1982,pp12-40.
13. 潘永寧,C. R. Loper, Jr.,“縮狀石墨鑄鐵—石墨顯微組織、凝固形成理論、生產方法、品質管制、性能及其應用發展(一)”,中華民國鑄造學會,鑄工季刊,第36期,72年3月,pp.16-25。
14. 潘永寧,C. R. Loper, Jr.,“縮狀石墨鑄鐵—石墨顯微組織、凝固形成理論、生產方法、品質管制、性能及其應用發展(二)”,中華民國鑄造學會,鑄工季刊,第37期,72年6月,pp.15-36。
15. 王進猷 “處理縮狀石墨鑄鐵之縮化劑效應研究”,國立台灣大學機械工程研究所碩士論文,民國76年。
16. E.D.Pan ; C.R. Loper , Jr., “A Study of the Production of Compacted/Vermiculan Graphite Cast Irons In Thin Section” AFS Trans.,Vol79, 1985. pp523-532.
17. G. F. Ruff and J. F. Wallace,“Graphite Configuration in Cast Iron,” AFS Trans., Vol.85, 1977, pp.167-170.
18. E. R. Evans, J. V. Dawson and M. J. Lalich,“Compacted Graphite Cast Iron and Their Production by a Single Alloy Addition,” AFS International Cast Metal Journal, June 1976, pp.13-18.
19. L. Sofroni, I. Riposan and I.Chria,“Some Considerations on the Crystallization Features of Cast Irons with Intermediate-Shaped Graphite (Vermicular Type)” Proceedings of the 2nd International Symposium on the Metallurgy of Cast Iron, Genera, 1974, pp.179-196.
20. J. Sissener, W. Thury and B.Smelteverk,“Cast Iron with Vermicular Graphite,”AFS Cast Metals Research Journal, Dec. 1972, pp.178-181.
21. K. P. Cooper and C.R. Loper, Jr.,“A Critical Evaluation of the Production of Compacted Graphite Cast Iron,” AFS Trans., Vol.86, 1978, pp.267-272.
22. N. Tsutsumi and M. Imarnura,“Proposal of the Classification of Spheroidal Graphite Form in Spheroidal Graphite Cast Iron,” Report of the Castings Research Laboratory, Waseda University, Tokyo, Japan, No.29,1978,pp.15-23.
23. N.N.Aleksandrov, et al., “Crystallization and Structure of Vermicular Graphite in Cast Iron,”Russian Castings Production, Sept. 1975, pp.365-366.
24. D.M. Stefanescu and L. Dinesue, “Production of Vermicular Graphite Cast Iron by Operative Control and Correction of Graphite Shape,” Proceedings of the 46th International Foundry Congress, Madrid, Spain, Sept. 30-Oct.3, 1979.
25. M. G. Day,“Use of Scanning Electron Microscopy to Investigate Aluminum/Silicon and Iron Graphite Eutectic Systems,” Journal of Metals. Vol. 21, April 1969,P.31.
26. 楊國和譯“縮墨鑄鐵的特性及製造方法”中華民國鑄造學會技術資料”民國70年。
27. M. G. Day, “Effect of Magnesium Additions on the Structure of Eutectic Graphite,” BCIRA Report, January 1971. pp.19-29.
28. R. D. Schelleng,“Cast Iron (with Vermicular Graphite),” British Patent Specification No.1,069,058,date of Applicaton April 26,1966.USA Application No.453,233 on May 4,1965.
29. M. J. Lalich,“Compacted Graphite Cast Iron-Its Properties and Production with a New Alloy,” Modern Casting, July, 1976, pp. 50-52.
30. J. V. Dawson, L.W. L. Smith and B. B. Bath, BCIRA Journal, June 1953,pp.540-552.
31. Nobuhisa Tsutsumi, and Masata Imamura,“Production of CV Cast Iron by Gas Injection.” Waseda Univ. Japan, 1980,pp15-45.
32. C.R.Loper, Jr,M.J. Lalich and H.K. Park, “Microstructure-Mechanical Property Relation Ship in Compacted (Vermicular) Graphite Cast Iron,” The Proceedings to the 46th International Foundry.
33. K.C.Cooper and C.R.Loper,A.F.S Transaction, 1978, 86, pp241-248.
34. 呂傳盛 “鑄鐵接種效果之探討” 中華民國鑄造學會,鑄工季刊54期,民國76年9月,p18~25。
35. “KUSAKA TECHNICAL NEWS”Vol.6.No,1,1987.
36. 李正國、李志偉、林本源、邱錫榮、陳文嘉、溫炯亮、傅豪編著 “熱處理”高立圖書公司,民國80年8月,p414-431。
37. 潘國桐 “常見的鑄鐵熱處理”,鑄造月刊,第89期,民國86年2月,PP.2-17。
38. 陳興時 “鑄鐵熱處理(三)”,中華民國鑄造學會,鑄工季刊,第37期,民國72年6月,P.97-102。
39. 邱維堂 “片墨與縮墨鑄鐵之動態與靜態韌性關係研究”大同工學院材料工程研究所碩土論文,民國87年。
40. ASTM A247-67, Annual Book of ASTM Standards, 1990, pp.129-130.
41. George E Dieter, “Mechanical Metallurgy”, McGraw-Hill Book Company, London, 1998, p.28.
42. 潘永寧,“球墨鑄鐵金相組織圖集”,中華民會鑄造學會編印,民國75年12月,p5-20。
43. ASTM. E8M-97 “Standard Test Methods for Tension Testing of Metallic Materials [Metric]”,1997, pp77-91.
44. ASTM. A327-91 “Standard Test Methods for Impact Testing of Cast Irons [Metric]”,1996, pp138-139.
45. 潘永寧,“變韌縮墨鑄鐵的鑄造”,中華民國鑄造學會,鑄工季刊,第40期,民國73年,pp1-13。