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研究生： 許益得
YiTe Hsu
論文名稱： SiC<p>/A390鋁基複合材料鑄件機械性質及腐蝕磨耗行為之研究
Studies on the Mechanical Properties and Corrosion Wear Behavior of SiC<p>/A390 Al-matrix Composites
指導教授： 邱弘興
Chiou, Horng-Shing
學位類別： 碩士
Master
系所名稱： 工業教育學系
Department of Industrial Education
畢業學年度： 87
語文別： 中文
論文頁數： 94
中文關鍵詞： A390鋁合金 、鋁基複合材料 、機械性質 、腐蝕磨耗
英文關鍵詞： A390 Aluminum Alloy, Al-matrix Composites, Mechanical Properties, Corrosion Wear
論文種類： 學術論文
相關次數： 點閱：495  下載：0 
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    • 本研究主要在探討SiC<p>之粒徑（46μm、80μm）及添加量（5wt％、10wt％）、固溶處理（480℃，3小時）、人工時效處理時間（150℃，1、3、10小時）及腐蝕磨耗環境（蒸餾水及3.5wt％鹽水）等實驗條件不同時，對於SiC<p>/A390鋁基複合材料鑄件機械性質及腐蝕磨耗行為之影響。
    實驗結果顯示，SiC<p>粒徑及添加量增加可提升SiC<p>/A390鋁基複合材料鑄件之硬度值及耐腐蝕磨耗性，且以添加量增加對硬度值的提升效果最為顯著。SiC<p>添加量為5wt％時，SiC<p>粒徑增加可提升抗拉強度值，但添加量為10wt％時，卻會造成抗拉強度值的降低。
    人工時效處理時間增加，可提升A390鋁合金之抗拉強度值，而對SiC<p>/A390鋁基複合材料鑄件之抗拉強度值及耐腐蝕磨耗性並沒有明顯影響。人工時效處理時間增至10小時後，其硬度值有明顯的提升。
    在腐蝕磨耗環境方面，SiC<p>/A390鋁基複合材料鑄件與A390鋁合金在蒸餾水中之耐腐蝕磨耗性皆比在3.5wt％鹽水中為佳，而其耐腐蝕性則會隨著SiC<p>添加量之增加而降低。

    The primary purpose of this research was to investigate the effects of SiC particles (SiC<p>) size (46μm、80μm ) and the amount of reinforcements (5wt%、10wt%), solid solution treatment (480℃,3 hours), articificial aging (150℃, 1、3、10 hours) and the environments of corrosion wear (distilled water、3.5wt% NaCl solution) on the mechanical properties and corrosion wear behavior of SiC<p>/A390 Al-matrix composites.
    The results show that the increasing of SiC<p> size and the amount of reinforcements increased the hardness and the corrosion wear resistance of SiC<p>/A390 Al-matrix composites. At 5wt% reinforcements , the increasing of the SiC<p> size increased the tensile strength, but at 10wt% the tensile strength was decreased.
    The tensile strength of A390 aluminum alloy was increased with the increasing of the holding time of artificial aging. For SiC<p>/A390 Al-matrix composites, the holding time of artificial aging has no significant influence on the tensile strength and the corrosion wear resistance.
    The corrosion wear resistance of SiC<p>/A390 Al-matrix composites and A390 aluminum alloy in the distilled water was better than that in the 3.5wt% NaCl solution. However, the corrosion resistance decreased with the increasing of the amount of the SiC<p> reinforcements.

    第一章 前　言………………………………………………………1 1-1 研究動機…………………………………………………1 1-2 研究目的…………………………………………………2 第二章 文獻探討……………………………………………………4 2-1 AMCs之融體鑄造…………………………………………4 2-1-1 AMCs之融體鑄造基本理論…………………………4 2-1-2 AMCs之融體鑄造攪拌方法…………………………5 2-1-3 AMCs之融體鑄造除氣方式…………………………6 2-2 AMCs之融體鑄造強化材之分散性………………………6 2-3 AMCs之融體鑄造的潤濕性………………………………9 2-4 AMCs之融體鑄造的流動性………………………………11 2-5 熱處理……………………………………………………12 2-5-1 鋁合金之析出強化處理………………………………12 2-5-2 複合材料之熱處理……………………………………14 2-6 AMCs之強化機構………………………………………15 2-7 AMCs之磨耗性質………………………………………17 2-8 AMCs之腐蝕問題………………………………………19 第三章 實驗方法及步驟…………………………………………21 3-1 實驗材料…………………………………………………21 3-2 實驗設備及裝置…………………………………………22 3-3 實驗配置…………………………………………………24 3-4 實驗流程…………………………………………………24 3-4-1 SiC<p>/A390鋁基複合材料熔煉與澆鑄…………24 3-4-2 熱處理………………………………………………26 3-4-3 試片製作……………………………………………26 3-4-4 機械性質試驗…………………………………………27 3-4-5 腐蝕磨耗試驗…………………………………………28 3-4-6 顯微組織觀察………………………………………28 3-4-7 抗拉試驗破斷面、腐蝕磨耗面及磨屑觀察…………29 第四章 實驗結果與討論…………………………………………30 4-1 製程參數對SiC<p>/A390鋁基複合材料鑄件顯微組織之影響……………………………………………………30 4-1-1 SiC<p>粒徑及添加量對SiC<p>/A390鋁基複合材料鑄件顯微組織之影響……………………………30 4-1-2 人工時效處理時間對SiC<p>/A390鋁基複合材料鑄件顯微組織之影響………………………………………31 4-2 製程參數對SiC<p>/A390鋁基複合材料鑄件機械性質之影響……………………………………………………31 4-2-1 SiC<p>粒徑及添加量對SiC<p>/A390鋁基複合材料鑄件機械性質之影響……………………………31 4-2-2 人工時效處理時間對SiC<p>/A390鋁基複合材料鑄件機械性質之影響………………………………………35 4-3 製程參數對SiC<p>/A390鋁基複合材料鑄件腐蝕磨耗行為之影響…………………………………………………36 4-3-1 SiC<p>粒徑及添加量對SiC<p>/A390鋁基複合材料鑄件腐蝕磨耗行為之影響………………………36 4-3-2 人工時效處理時間對SiC<p>/A390鋁基複合材料鑄件腐蝕磨耗行為之影響…………………………………38 4-3-3 SiC<p>/A390鋁基複合材料鑄件在蒸餾水及3.5wt％鹽水中之腐蝕磨耗行為及其差異…………………38 第五章 結論…………………………………………………………42 參考文獻………………………………………………………………45

    1. 楊耀昇、曹紀元, "半固態製程鑄造A356鋁矽合金製程參數對其微觀組織及黏度之影響",鑄工第20卷第3期,民國83 年, pp22-29。
    2. 謝棋旻, "液態攪拌法製作SiCp/A356鋁基複合材料之研究",逢甲大學機械工程研究所碩士論文,民國85年。
    3. 張子欽, "SiC<p>/A356鋁基複合材料鑄造方法與機械性質及顯微組織關係之研究",逢甲大學機械工程研究所碩士 論文,民國86年。
    4. 張文, "鋁基複合材料之熔融鑄程及其機械性質之研究",國立台灣大學材料工程學研究所碩士論文,民國79年。
    5. 李勝隆, "鋁合金熱處理技術",鑄造鋁合金工業技術講習會講義,國立中央大學機械研究所,民國85年。
    6. "鋁合金材料選用及熱處理技術",經濟部工業局八十七年度工業技術人才培訓計畫講義,金屬工業研究發展中心,民 國86年。
    7. 譚安宏、李勝隆、鄭榮瑞及林於隆, "Al-Si-Mg鑄造鋁合金之熱處理",鑄工季刊第86期,民國84年,pp68-74。
    8. 林玄良, "田口方法於A390鋁合金最佳化製程之應用",國立台灣師範大學工業教育研究所碩士論文,民國87年。
    9. 張偉名, "A390鋁合金製程參數之最佳化研究",國立台灣師範大學工業教育研究所碩士論文,民國86年。
    10. 楊榮顯、戴國政、李有山、蕭錫謙, "液態攪拌法製作MMC之水模模擬實驗"鑄工第21卷第3期,民國84年,pp33-52 。
    11. 楊家彰, "碳化矽顆粒強化A356鋁合金的融體鑄造技術及熱處理研究",國立成功大學碩士論文,民國84年。
    12. 蘇武忠, "半熔融A380鋁合金之攪拌速率對其凝固組織與機械性質的影響",鑄工第67期,民國79年,pp43-52。
    13. 楊榮顯、戴國政、蕭錫謙、謝棋旻, "液態攪拌法製作SiCp/A356鋁基複合材料之研究",鑄工第22卷第2期,民國85 年,pp16-24。
    14. 呂高榮, "A390鋁合金之矽型態控制及其與機械性質之關係",國立台灣師範大學工業教育研究所碩士論文,民國85 年。

    1. P. Rohatgi,"Foundry Processing of Metal Matrix Composites",Modern Casting,Apr,(1988), p47.
    2. Y. M. Pan, M.E. Fine and H. S. Cheng, "Aging Effects on the Wear Behavior of P/M Aluminum Alloy SiC Particle Composites ",Scripta Met., Vol.24,(1990), pp1341-1345.
    3. S. P. Midson and K. Brissing,"Semi-solid Casting of Aluminum Alloys", A Status Report, Modern Casting, Feb,(1997).
    4. A. K. Jha, S. V. Prasad and G. S. Vpadhyaya,"Sintered 6061 Aluminum Alloy-solid Lubricant Particle Composites: Sliding Wear and Mechanisms of Lubrication",Wear, Vol.133,(1989), pp163-172.
    5. H. L. Lee, W. H. Lu and S. L. I. Chan, Chin J. Mater. Sci.,Vol.24(1),(1992),p40.
    6. F. M. Hosking, F. F. Portillo, R. Wunderlin and R. Mehrabian, "Composites of Aluminum Alloys: Fabrication and Wear Behavior",J. Mater. Sci.,Vol.17,(1982),pp477-498.
    7. K. J. Bhansali and R. Mehrabian,"Abrasive Wear of Aluminum-matrix Composites",J. Met.,Dec,(1982),pp30-34.
    8. P. P. Trzaskoma, E. C. Mcafferty and C. R. Crowe, J. Electrochem.Soc.,Vol.130,(1983),p1804.
    9. D. M. Aylor and D. Taylor,"Metals Handbook 9th Edition",ASM,Vol.2,(1986),p859.
    10. T. Otani, B. Mcenaney and V. D. Scott,"Proceedings of the Int. Sym.On Avdances in Cast Reinforced Metal Composite",ed. by. S. G. Fishman and A. K. Dhingra,ASM,(1989),p383.
    11. D. M. Aylor and R. M. Kain,"Recent Advances in Composites in the United States and Japan",ed. by J.R. Vinson and M. Taya,ASTM STP 864,(1985),p632.
    12. F. Mansfeld and S. L. Jeanjaquet,"The Evaluation of Corrosion Protection Measures for Metal Matrix Composites",Corr. Sci.,Vol.26(9),(1986),pp727-734.
    13. D. M. Aylor, R. J. Ferrara and R. M. Kain,"Marine Corrosion and Protection for Graphite/Aluminum Metal Matrix Composites",Mater. Prerformance,Vol.23(7),(1984),pp32-38.
    14. F. Mansfeld, S. Lin, K. Kim and H. Shin,"Pitting and Surface Modification of SiC/Al", Corr. Sci.,Vol.27(9),(1987),
    pp997-1000.
    15. M. S. N. Bhat, M. K. Surappa and H. V. Nayak, "Corrosion Behaviorur of Silicon Carbide Particle Reinforced 6061/Al Alloy Composites", J. Mater. Sci.,Vol.26,(1991),pp4991-4996.
    16. H. L. Lee, W. H. Lu and S. L. I. Chan,"Abrasive Wear of Powder Metallurgy Al Alloy 6061-SiC Particle ",Wear, Vol.159,(1992), pp223-231.
    17. S. J. Lin and K. S. Liu,"Abrasion Rate in An Al-Zn-Mg-SiC composites",Wear, Vol.121,(1988),pp1-14.
    18. Ma Zongyi, Bi Jing, Lu Yuxiong,Shen Hongwei and Gao Yinxuan,
    "Abrasive Wear of Discontinous SiC Reinforced Aluminum Alloy Composites",Wear,Vol.148,(1991),pp287-293.
    19. O. E. Okorafor,"Effect of Heat Treatment on the Corrosion Resistance of 6063 Aluminum Alloy", Corrosion Prevention & Control,December, (1991),pp141-143.
    20. Huei-Long Lee,Sammy Lap-Ip Chan,"Abrasive Wear of Aged 2014 and 6061 Aluminum Alloy Composites",J. Mater. Sci. Lett.,Vol.12,(1993),pp476-477.
    21. R. Mehrabian, R. G. Riek, and M. C. Fleming, "Preparation and Casting of Metal of Metal Particulate Non-metal Composites", Metall.Trans. ,Vol.5,(1974),pp1899-1904.
    22. A. Sato and R. Mehrabian ,"Aluminum Matrix Composites: Fabricaton and Properties", Metall. Trans.,Vol.7B,(1976),
    p443.
    23. P. K. Rohatgi, B. C. Pai ,and S. C. Panda, " Preparation of Cast Aluminum Silica Particulate Composites",J. Mater. Sci.,Vol.14,(1979),p2277.
    24. M. K. Surappa and P. K. Rohatgi, " Preparation and Properties of Cast Aluminum Ceramic Particle Composites", J. Mater. Sci.,Vol.16,(1981),p983.
    25. B. P. Krishnan, M. K. Surappa, and P. K. Rohatgi, "The UPAL Process; A Diect Method of Preparing Cast Aluminum Alloy Graphite Particle Composites",J. Mater. Sci.,Vol.16,(1981),p1209.
    26. D. B. Spencer, R. Mehrabian, and M. C. Flemings, "Rheological Behavior of Sn-15 Pct Pb in the Crystallization Range",Metall. Trans.,Vol.3,(1972),p1925.
    27. F. A. Girot, J. M. Quenisset, and R. Naslain, "Discontinuously-reinforced Aluminum Matrix Composites", Comp. Sci. and Technol.,Vol.30,(1987),p155.
    28. T. Z. Kattamis and J. A. Cornie ,"Solidification Processing of Particulate Ceramic-Aluminum Alloy Composites",
    International Symposium on Advances in Cast Reinforced Metal Composites, Vol.9,(1988),p47.
    29. A. Mortensen, M. N. Gungor, J. A. Cornie, and M. C. Flemings, "Alloy Microstructures in Cast Metal Matrix Composites", J. Met.,Vol.3,(1986),p30.
    30. A. Luo,"Effect of Matrix Alloy Composition on the Interfacial Phenomena and Microstructure of Cast Mg/SiCp Composites",The Tenth International Conference on Composite Materials,Vol.2,(1995),p287.
    31. A. Mortensen and I. Jin, Int. Mat. Rev.,Vol.37,(1992),p101.
    32. M. K. Surappa and P. K. Rohatgi,"Preparation and Properties of Cast Aluminum-Ceramic Particle Composites", J. Mater. Sci. Lett.,Vol.16,(1981),p983.
    33. A. W. Neumann, J. Szekely and E. J. Rabenda, Jr., J. olloid Interf. Sci.,Vol.43,(1993),p727.
    34. S. N. Omenyi and A. W. Nenumann, J. Appl. Phys.,Vol.47,(1976),p3956.
    35. D. M. Stefanescu and B. K. Dhindaw; "Metals Handbook 9th Edition",Vol.15,ASM Int.,Material Park,OH,U.S.A.,(1988).
    36. P. K. Rohatai, R. Sathyamoorthy, C. S. Narendranath, D. Nath;"Studies on Casting Characteristics and Settling Behavior of Al-Base SiC-Particle Metal Matrix Composites",AFS Trans.,(1993),pp597-604.
    37. S. Y. Oh, J. A. Cornie, and K. C. Russell,"Wetting of Ceramic Particulates with Liquid Aluminum Alloys: Part Ⅰ Experimental Techniques",Metall. Trans., Vol.24A,(1989),p527.
    38. M. K. Surappa and P. K. Rohatgi, Met. Technol. ,Vol.7(9),(1980),p370.
    39. M. K. Surappa and P. K. Rohatgi, Metal. Trans.,Vol.128,(1981),p327.
    40. D. M. Aylor and D. Taylor, "Metal Handbook 9th edition",ASM,Vol.2,(1986),pp171-172.
    41. J. Rowe and W. E. Sicha, "Heat Treatment of Cast Aluminum Alloys",AFS Trans.,Vol.54,(1946),pp424-435.
    42. Charlie R. Brooks, "Heat Treatment ,Structure and Properties of Nonferrous Alloys",ASM,(1982).
    43. C. Badini, F. Marino, E. Verne, Mat. Sci. and Eng.,Vol.191,(1995),pp185-191.
    44. S. Suresh, T. Christman and Y. Sugimura,"Accelerated Aging in Cast Al Alloy-SiC Particulate Composites", Scr. Metal., Vol.23,(1989),pp1599-1602.
    45. M. J. Starink, P. V. Mourik and B. M. Korevaar,"Misfit Accommodation in A Quenched and Aged Al-Cu Alloy with Silicon Particles", Metal. Trans. A ,Vol.24A, Aug,(1993),pp1723-1731.
    46. M. Vogesang, R. J. Arsenault and R. M. Fisher,"An In Situ HVEM Study of Dislocation Generation at Al/SiC Interfaces in Metal Matrix Composites", Metal. Trans. A, Vol.17A ,Mar,(1986),pp379-398.
    47. I. Dutta and D. L. Bourell,"A Theoretical Investigation of Accelerated Aging in Metal-Matrix Composites", J. Compo. Mater.,Vol.229,(1988),pp829-832.
    48. I. Dutta, S. M. Allen and J. L. Hafley,"Effect of Reinforcement on the Aging Response of Cast 6061 Al-Al2O3 Particulate Composites",Metal. Trans. A ,Vol.22A ,Nov,(1991),pp2553-2563.
    49. W. S. Miller and F. J. Humphreys,"Strengthening Mechanisms in Particulate Metal Matrix Composites", Scripta Metall. et Mater.,Vol.25,(1991),pp33-38.
    50. M. Taya and K. E. Lulay ,"Strengthening of Particulate Metal Matrix Composites by Quenching",Acta Metall.,Vol.39
    ,(1991),pp73-87.
    51. F. J. Humphreys,"The Nucleation of Recrystallization at Second Phase Particles in Deformed Aluminum",Acta Metall.
    ,Vol.25,(1977),pp1323-1344.
    52. F. J. Humphreys,ŝth Riso Conference Denmark",p.25.
    53. K. J. Bhansali and W. L. Silence,"Metallurgical Factors Affect Wear Resistance ",Met. Prog., November,(1981),p38.
    54. H. L. Lee, N. T. Lian and S. L. I. Chan, "Mechanical Behaver of Metal-matrix Composites",Corr. Eng., Vol.6(2),(1992),p9.
    55. A. Turnbull,"Review of Corrosion Studies on Aluminum Metal Matrix Composites", British Corrosion Journal, Vol.27,
    (1992),pp27-35.
    56. Well Being Enterprise Co., Ltd.,(1998).
    57. E. N. Pan, M. W. Hsieh, S. S. Jang, C. R.. Loper, Jr., "Study of the Influence of Processing Parameters on the Microstructure and Properties of A356 Aluminum Alloy" ,AFS Trans., Vol.97, (1989), pp397-414.
    58. P. K. Rohatgi, " Metal Handbook 9th Edition",ASM, Vol.15,(1983),pp840-854.
    59. A. P. Bates and D. S. Calvert, "Refinement and Foundry Characteristics of Hypereutectic Aluminum-Silicon Alloys",The British Foundryman, Vol.59,(1966),pp119-133.
    60. N.Tenekedjiev, D. Argo and J. E. Gruzleski, "Sodium ,Strontium and Phosphorous Effects in Hypereutectic Al-Si Alloy",AFS. Trans., Vol.97,(1989),pp127-136.
    61. A. J. Cligg and A. A. Das, "The Influence of Structural Modifiers on the Refinement of the Primary Silicon in a Hypereutectic Aluminum-silicon Alloy ",The British Foundryman ,Vol.70 ,(1977),pp56-63.
    62. R. Chen and G. Zhang,"Casting Defects and Properties of Cast A356 Aluminum Alloy Reinforced with SiC Particles",Compo. Sci. and Technol.,Vol.47,(1993),pp51-56.

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