研究生: |
廖國華 Miaw-Jin Lin |
---|---|
論文名稱: |
吸附採樣技術與毛細管氣相層析法對大氣中鹵化碳氫化合物側定之運用 applications of sorbent sampling techniques and capillary gas |
指導教授: |
吳家誠
Wu, Jia-Cheng |
學位類別: |
碩士 Master |
系所名稱: |
化學系 Department of Chemistry |
畢業學年度: | 81 |
語文別: | 中文 |
論文頁數: | 124 |
中文關鍵詞: | 空氣; 鹵化碳氫化合物;吸附管;毛細管柱;氣相層析 |
英文關鍵詞: | air;halogenated hydrocarbonsne ;preconcentration sorbent tube; |
論文種類: | 學術論文 |
相關次數: | 點閱:290 下載:0 |
分享至: |
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報 |
鹵化碳氫化合物至今於工業生產與應用上仍扮演重要角色, 許多這類化合
物有些具有很高的蒸氣壓, 屬於揮發性有機化物, 處理不當時易氣化而散
佈於空氣中造成污染, 對人體健康易造成影響或傷害, 所以有許多針對這
類化合物的分析測定方法已陸續被發表, 在本研究中所發展的是兩種具有
不同前處理過程的分析方法一種是使用活性碳採樣管技術, 以溶劑脫附的
方式前處理; 另一種則是使用Tenax TA採樣管, 以熱脫附方式前處理 兩
種方法皆是以毛細管氣相層析法來分離化合物, 並以電子捕捉偵測器測定
第一種方法由於方法偵測極限較高, 所以用途受限, 只適用於工廠等高污
染場所之週界檢測; 第二種方法的方法偵測極限較低, 可廣泛運用, 但所
需成本則較高
Halogenated hydrocarbons still play important role in
industrial ductions and applications . Some of these compounds
with high are volatile organic compounds and can vaporize and
distribute air . Because of their possible hazards to human ,
various determination of halogenated hydrocarbons have been
published . , two methods with different pretreatment processes
are developed capillary GC analyses . One uses charcoal
sampling tube technique for sample collection , the tube is
then pretreated by solvent desorption . The other sampling tube
technique followed by thermal desorption . Analytes methods are
separated with capillary gas chromatography andth an electron
capture detector . Due to their relatively high method
detection limits , the lity of the first method is limited only
to regions such as work high contamination . The second method
with lower methods , but higher cost can be applied more widely
.
Halogenated hydrocarbons still play important role in