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研究生: 劉岳函
論文名稱: 以高真空壓鑄法製備陣列式氧化鋅-鋁奈米線及氣體感測特性之研究
The Study on Manufacture of Array Nanowires of Zinc oxide - Aluminum by High Vaccum Die-Casting and Property of Gas Sensin
指導教授: 李景峰
Li, Jeen-Fong
學位類別: 碩士
Master
系所名稱: 工業教育學系
Department of Industrial Education
論文出版年: 2013
畢業學年度: 101
語文別: 中文
論文頁數: 78
中文關鍵詞: 鋅鋁合金陽極氧化鋁真空壓鑄金屬半導體氣體感測元件氧化鋅
英文關鍵詞: Zinc-Aluminum alloy, AAO, Vacuum die-casting, Metal semiconductor gas sensor, zinc oxide
論文種類: 學術論文
相關次數: 點閱:109下載:6
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  • 氧化鋅在氣體偵測器應用方面為一種極為普遍使用的材料,因為其在還原性氣氛中會與氧化物表面吸附的氧氣反應造成電阻的改變。並可偵測或辨別多種有毒氣體及可燃燒性的氣體,如一氧化碳、乙醇、丙烷等等。本研究首先利用高真空壓鑄方式將亞共晶、共晶與過共晶相熔融的鋅鋁合金金屬溶液鑄入陽極氧化鋁(Anodic Aluminum Oxide, AAO)奈米模板中,待金屬液冷卻固化後,可得到陣列式鋅鋁合金奈米線,經熱處理後可得陣列式氧化鋅鋁奈米線,以濕蝕刻方式將AAO奈米模板移除使奈米線裸露,最後於上方蒸鍍銅薄膜完成金屬半導體氣體感測元件製作。而元件之成份、微結構及性質檢測則以能量散佈光譜儀(Energy Dispersive Spectrometer , EDS)、掃瞄式電子顯微鏡(Scanning Electron Microscopy , SEM)、X光繞射分析儀(X-ray Diffractometer , XRD)與示差掃描熱量分析儀(Differential Scanning Calormetry , DSC)做分析。本文之目的在研究以氧化鋅陣列式奈米線感測器元件作為對照組,而添加各比例鋁之氧化鋅陣列式奈米線感測元件作為設計組,將兩組元件置於相同檢測條件中,比較其對氧氣響應之靈敏度。而氣體檢測部分則是自行設計之量測平台,藉由質量流量控制器( Mass Flow Controler, MFC)控制待測氣體濃度,進行微訊號量測與訊號數據擷取,於溫度100℃、150℃、200℃,分別通入5%、10%、15%、20% 體積百分濃度的O2。結果顯示,提高溫度有助於靈敏度的提升;具有奈米線陣列之感測元件靈敏度排列順序ZnO 95%-Al 5%>ZnO 98%-Al 2%>ZnO 100%>ZnO 90%-Al 10%,因此靈敏度會隨鋁的含量增多而提升,但若添加超過5%,其靈敏度會隨鋁的含量增多而下降。

    目 錄 中文摘要 I 英文摘要 II 誌 謝 IV 表目錄 VII 圖目錄 VIII 第一章 緒論 1 1.1 前言 1 1.2 感測器簡介 3 1.2.1 氣體感測器性能要素 4 1.2.2 吸附原理 6 1.3 研究動機及目的 10 1.4 研究流程及論文架構 12 第二章 文獻回顧 14 2.1 陽極氧化鋁文獻回顧 14 2.1.1 陣列式陽極氧化鋁簡介 14 2.1.2 陣列式陽極氧化鋁的生成機制 16 2.1.3 影響陽極氧化鋁的參數 19 2.2 氧化鋅文獻回顧 22 2.2.1 氧化鋅基本物理性質 22 2.2.2 氧化鋅與氧化鋅摻雜金屬之電性 24 2.3 氣體感測器文獻回顧 25 2.3.1 金屬半導體氣體感測器 26 2.3.2 電化學氣體感測器 27 2.3.3 固態電解質氣體感測器 29 2.3.4 觸媒燃燒式氣體感測器 30 2.3.5 光電式氣體感測器 31 2.3.6場效電晶體氣體感測器 32 2.3.7 壓電型氣體感測器 33 第三章 陣列式鋅鋁合金奈米線氣體感測元件設計與製作 35 3.1 陣列式陽極氧化鋁奈米模板製作 36 3.1.1 實驗方法與流程 36 3.1.2 電解拋光 36 3.1.3 一次陽極化處理 38 3.1.4 鉻酸蝕刻 39 3.1.5 二次陽極化處理 39 3.1.6 去背蝕刻與薄膜通孔 40 3.2 鋅鋁合金真空熔煉 42 3.2.1 實驗方法及流程 42 3.3 以真空壓鑄法製備陣列式鋅鋁合金奈米線 47 3.3.1 實驗方法及流程 48 第四章 實驗結果與討論 50 4.1 陽極氧化鋁奈米模板探討 50 4.2 合金檢測與成份分析 51 4.2.1 EDS成份分析 51 4.2.2 XRD性質檢測 52 4.2.3 DSC性質檢測 54 4.3 鋅鋁合金奈米線微結構檢測 57 4.4 氧氣氣體檢測系統 58 4.5 氣體檢測 59 4.5.1 實驗程序 59 4.5.2 氧氣氣體檢測 59 4.5.2.1 各比例ZnO 100℃訊號量測 60 4.5.2.2 各比例ZnO 150℃訊號量測 64 4.5.2.3 各比例ZnO 200℃訊號量測 67 第五章 結論與未來展望 70 5.1 結論 70 5.2 未來展望 71 參考文獻 72

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