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研究生: 呂紹宏
Lyu, Shao-Hung
論文名稱: 親水性鋁金屬有機骨架之快速合成及吸水應用
Rapid Synthesis and Water Adsorption Application of Hydrophilic Aluminum Metal-Organic Framework
指導教授: 林嘉和
Lin, Chia-Her
口試委員: 楊仲準
Yang, Chun-Chuen
謝發坤
Shieh, Fa-Kuen
林嘉和
Lin, Chia-Her
口試日期: 2022/06/09
學位類別: 碩士
Master
系所名稱: 化學系
Department of Chemistry
論文出版年: 2022
畢業學年度: 110
語文別: 中文
論文頁數: 139
中文關鍵詞: 加熱抽真空縮短反應時間結晶化
英文關鍵詞: heat under vacuum, crystallization, reduce reaction time
研究方法: 實驗設計法
DOI URL: http://doi.org/10.6345/NTNU202200791
論文種類: 學術論文
相關次數: 點閱:248下載:0
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第1章 緒論 1 1-1 前言 1 1-2 MOF的演進 3 1-3 MOF的吸水應用 7 1-4 研究動機 11 第2章 實驗與儀器 12 2-1 實驗藥品 12 2-2 儀器機型和測量簡介 17 2-3 實驗合成方法 22 第3章 Al-MOF快速結晶化結果與討論 23 3-1 Al-MOF 介紹 23 3-1-1 MIL-160 23 3-1-2 MIL-53-TDC 26 3-1-3 CAU-23 29 3-1-4 MOF-303 32 3-2 快速結晶化實驗 35 3-2-1 MIL-160 36 3-2-2 CAU-23 39 3-2-3 MIL-53-TDC 42 3-2-4 MOF-303 45 3-3 快速結晶化結果與討論 46 3-3-1 粉末X光繞射鑑定與討論 46 3-3-2 場發式掃描電子顯微鏡(FE-SEM)鑑定與結果討論 67 3-3-3 比表面積及孔隙分析儀(BET)鑑定 77 3-3-4 快速結晶化樣品熱穩定性討論 105 3-4 配位基溶解度差異性 109 3-5 快速合成Al-MOF吸水應用 113 第4章 結論與展望 120 參考資料 121 附錄A 124 附錄B 129 附錄C 138

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