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研究生: 謝易晉
Hsieh, Yi-Chin
論文名稱: 素養導向綠色化學實驗之設計與研究-以鐵的氧化還原反應與防鏽處理為例
Design and research of competemcy-based green chemistry experiment - an case study on topic of redox reaction and rust-preventive treatment of iron
指導教授: 林震煌
Lin, Cheng-Huang
學位類別: 碩士
Master
系所名稱: 化學系
Department of Chemistry
論文出版年: 2020
畢業學年度: 108
語文別: 中文
論文頁數: 58
中文關鍵詞: 素養導向教學科學素養
英文關鍵詞: literacy-based instruction, competemcy-based instruction science literacy
DOI URL: http://doi.org/10.6345/NTNU202001574
論文種類: 學術論文
相關次數: 點閱:133下載:4
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  • 現今教育現場開始以素養導向的教育取代原本知識本位的教學,強調透過「探究」與「實作」讓學生有展現多元思考的機會、以實證的方式學習科學知識。本文藉由文獻分析探討素養導向於實驗課程設計的內涵,並以「鐵器的防鏽挑戰」作為情境脈絡設計出一門可以適用於高中及大學端的多層次實驗課程,藉此體現素養導向實驗設計的內涵與實踐方法。
    本實驗以拉曼光譜儀確認實驗課程所製備的四種經防鏽處理的樣品其表面的成分,並透過掃描式電子顯微鏡對樣品表面進行粒徑分析,由TGS822TF傳感器及LM393放大器搭配NI USB-6008 DAQ等電子零件開發出一台自組裝氫氣感測器,對於將鐵表面由單寧酸、沒食子酸及鹽酸修飾成四氧化三鐵時所產生的氫氣進行監控,透過已知氫氣量推導出測得數值及產氫量的關係式,成功以這台自組裝氫氣感測器確認反應所產生的氣體即為氫氣,並且量測到確切的反應停止時間,並計算出反應的總產氫量。

    In recent years, education has been transformed from a knowledge-based orientation to a competency-based instruction. It emphasizes the method of practice and inquiry to make students have the opportunity to show multiple thinking and learn scientific knowledge in an empirical way. The Study herein analyzed the scientific literacy connotation by literature review. Using the "rust challenge of ironware" as a context to design a multi-level experimental course that can be applied to high school and university, further suggesting feasible approaches of course practices via a case study on topic of science subject. In this way, the connotation and practical methods of competency-based experimental design are reflected.
    In this experiment, the Raman spectrometer was used to confirm the composition of the surface of the four anti-rust samples prepared in the experimental course, and the particle size analysis of the sample surface through the scanning electron microscope. The self-assembly hydrogen sensor was assembled mainly by the TGS822TF sensor and the LM393 amplifier, along with electronic parts like NI USB-6008 DAQ. Monitor the hydrogen generated when the iron surface is modified from tannic acid, gallic acid and hydrochloric acid to 〖Fe〗_3 O_4. The relationship between the measured value and the amount of hydrogen produced is derived from the measurement of the known amount of hydrogen. This hydrogen sensor was used to confirm that the gas produced by the reaction was hydrogen, the exact reaction stop time was measured, and the total hydrogen p roduction of the reaction was calculated.

    第1章 緒論 1 1-1 研究目的 1 1-2 分析物簡介 2 1-2-1 沒食子酸 2 1-2-2 氫氯酸 3 1-2-3 藍洗液 3 第2章 分析原理及方法 4 2-1 拉曼散射 4 2-1-1 拉曼散射歷史簡介 4 2-1-2 拉曼散射原理介紹 5 2-2 TGS822TF傳感器 7 2-2-1 半導體式傳感器 7 2-2-2 基本電路 8 2-2-1 靈敏度 10 2-2-2 規格 11 2-3 酸洗產氫反應 12 2-3-1 氫氯酸 12 2-3-2 沒食子酸 13 第3章 藥品、儀器及實驗方法 14 3-1 主要實驗儀器 14 3-1-1 自組裝氫氣感測器 14 3-1-2 拉曼光譜儀 16 3-1-3 掃描式電子顯微鏡 17 3-2 儀器設備列表 18 3-3 實驗藥品列表 21 第4章 素養導向課程設計方法及概念 22 4-1 課程設計背景 23 4-2 核心素養及其具體內涵 23 4-3 自然科素養導向科學教育重點及課程設計原則 24 4-4 素養導向課程設計方法 25 第5章 課程設計內容與實驗結果 26 5-1 高中課程設計內容與實驗結果 26 5-1-1 單元一 防鏽大挑戰 27 5-1-2 單元二 產氫觀察-排水集氣法設計 29 5-1-3 單元三 實驗探討 32 5-2 標準品拉曼圖譜 33 5-2-1 Fe3O4及Fe2O3標準品拉曼 33 5-2-2 活性碳標準品拉曼圖 33 5-3 氫氯酸與鐵片產氫的反應 34 5-3-1 實驗流程 34 5-3-2 溶液配置 35 5-3-3 實驗結果 36 5-4 沒食子酸與鐵片產氫反應 38 5-4-1 實驗流程 38 5-4-2 溶液配置 39 5-4-3 實驗結果 40 5-5 鐵膽墨汁成分分析 42 5-5-1 樣品前處理 42 5-5-2 實驗結果 43 5-6 大馬士革刀刃表面分析 45 5-6-1 樣品前處理 45 5-6-2 實驗結果 48 5-7 藍洗液酸洗刀片分析 49 5-7-1 樣品前處理 49 5-7-2 實驗結果 50 5-8 自組裝氫氣感測器校正 52 第6章 結論 54 參考文獻 55

    [1] 林永豐(2017)。核心素養的課程教學轉化與設計。教育研究月刊,275,4-17。
    [2] 林慶隆(2016)。國小自然教科書之知識論與課程觀演變。新北:國家教育研究院。
    [3] 教育部(2014)。十二年國民基本教育課程綱要總綱。臺北:教育部。
    [4] 孫維新(2013)。2012 公民素養大未來─科學素養,創新的原動力,科學人雜誌,132,取自http://sa.ylib.com/Catalog.aspx?id=158。
    [5] 曾志朗(2103)。2012 公民素養大未來─科學素養,創新的原動力,科學人雜誌,132,取自http://sa.ylib.com/Catalog.aspx?id=158。
    [6] 陳文典(2005)。科學素養的內涵。取自phy.ntnu.edu.tw/~wdchen/doc/book94.11/01.doc。
    [7] 黃茂在、吳敏而(2017)。探索十二年國民基本教育自然科學素養導向教學設計。教育研究月刋,3,84-96。
    [8] 洪詠善(2016)。學習趨勢:跨領域、現象為本的統整學習。國家教育研究院電子報,134。取自:http://epaper.naer.edu.tw/index.php?edm_no=134&content_ no=2671
    [9] 吳清山(2014)。善用活化教學提升學生學習效能。師友月刊,559,31-35。doi:10.6437/EM.201401_(559).0008【Wu, C.-S. (2014). Make good use of activating teaching to improve students’ learning effectiveness. The EducatorMonthly, 559, 31-35. doi:10.6437/EM.201401_(559).0008】
    [10] 吳清山(2017a)。素養導向教育的理念與實踐。教育行政與評鑑學刊,21,1-24。【Wu, C.-S. (2017a). The ideas and implementation of competency-based education. Journal of Educational Administration and Evaluation, 21, 1-24.】
    [11] 吳清山(2017c)。教師素養導向教師教育:理念、挑戰與實踐。學校行政雙月刊,112,14-27。【Wu, C.-S. (2017c). Competency-based teacher education: Ideas, challenges and practice. School Administrators, 112, 14-27. doi:10.3966/160683002017110112002】
    [12] 王金國(2018)。以專題式學習培養國民核心素養。臺灣教育評論月刊,7(2),107-111。[Wang, C.-K. (2018). Cultivating national core competencies with project learning. Taiwan Educational Review Monthly, 7(2), 107-111.]
    [13] 林永豐(2018)。素養導向教學設計的要領。載於周淑卿、吳璧純、林永豐、張景媛、陳美如(主編),素養導向教學設計參考手冊(頁1-5)。臺北市:教育部國民及學前教育署。[Lin, Y.-F. (2018). The guideline of competence-based instructional design. In S.-C. Chou, B.-C. Wu, Y.-F. Lin, J.-Y. Chang, & M.-J. Chen (Eds.), The handbook of competencebased instructional design (pp. 1-5). Taipei, Taiwan: K-12 Education Administration, Ministry of Education.]
    [14] 褚宏啟(2016)。核心素養的概念與本質。華東師範大學學報(教育科學版),1,1-11。[Tsu, H.-C. (2016). The concept and essence of core competencies. Journal of East China Normal University (Education Sciences), 1, 1-11.]
    [15] 蔡清田(2016)。核心素養研究與課程設計的新進展。教育與多元文化研究,13,223-246。[Tsai, C.-T. (2016). Recent research and curriculum design of national core competencies in 1-12 national basic education curriculum reform in Taiwan. Journal of Educational and Mulicultural Research, 13, 223-246.]
    [16] Roberts, D. A. (2007). Scientific literacy/ science literacy. In S.K. Abell & N.G. Lederman, (Eds.), Handbook of research on science education. (pp. 729-780). Mahwah, NJ:Lawrence Erlbaum.
    [17] OECD (2005). Teachers matter: Attracting, developing and retaining effective teachers. Paris: Author.
    [18] OECD (2016). Global competency for an inclusive world. Paris: Author.
    [19] 楊俊鴻(2018)世界各國國定課程中的核心素養:以日本、韓國與新加坡為例。
    [20] 靳知勤(2007)。科學教育應如何提升學生的科學素養─台灣學術精英的看法。科學教育學刊,15(6),627-646。
    [21] Cydis, S. (2014). Fostering competencies in future teachers: A competency-based approach toteacher education. Creative Education, 5(13), 1148-1159.
    [22] Darling-Hammond, L. (2000). Teacher quality and student achievement: A review of State policy evidence. Education Policy Analysis Archives, 8(1), 1-44.
    [23] Department for Education(2010).The importance of teaching: The schools white paper 2010.London, England:Author.
    [24] Rui Liu, Haiyan Ding, Jian Lin, Fangping Shen, Zheng Cui and Ting Zhang , Nanotechnology, 2012 , 23 505301
    [25] Meng Zhao, Jian Xing Huang and ChungWo Ong, Nanotechnology, 2012, 23 315503
    [26] Wunderlich, C. H.; Weber, R.; Bergerhoff, G., Journal of Inorganic and General Chemistry 1991, 598 (1), 371-376.
    [27] Ponce, A.; Brostoff, L. B.; Gibbons, S. K.; Zavalij, P.; Viragh, C.; Hooper, J.; Alnemrat, S.; Gaskell, K. J.; Eichhorn, B., Anal. Chem. 2016, 88 (10), 5152-5158.
    [28] Krekel, C., International journal of forensic document examiners 1999, 5, 54-58.
    [29] Wunderlich, C.-H., Geschichte und Chemie der Eisengallustinte und Struktur des Eisen (III)-Gallussäure-Komplexes. Rheinischen Friedrich-Wilhelms-Universität: 1990.
    [30] Hahn, O.; Kanngießer, B.; Malzer, W., Studies in conservation 2005, 50 (1), 23-32.
    [31] Feller, R. K.; Cheetham, A. K., Solid state sciences 2006, 8 (9), 1121-1125.
    [32] Arpino, P.; Moreau, J.-P.; Oruezabal, C.; Flieder, F., J. Chromatogr. A 1977, 134 (2), 433-439.
    [33] Fong-Yee, D., & Normore, A. H. (2004, April). The impact of quality teachers on student achievement. Paper presented at the 3rd Annual South Florida Education Research Conference, Miami, FL.
    [34] Goral, T. (2018). A fresh look at an old way of teaching in K12: Competency-based education
    [35] Powell, H. K. J.; Taylor, M. C., Australian Journal of Chemistry 1982, 35 (4), 739-756.
    [36] Yamahara, R.; Ogo, S.; Masuda, H.; Watanabe, Y., J. Inorg. Biochem. 2002, 88 (3-4), 284-294.
    [37] Perron, N. R.; Brumaghim, J. L., Cell biochemistry and biophysics 2009, 53 (2), 75-100.
    [38] Rulison, A. J.; Flagan, R. C., Review of Scientific Instruments 1993, 64 (3), 683-686.
    [39] Kostiainen, R.; Bruins, A. P., Rapid Communications in Mass Spectrometry 1994, 8 (7), 549-558.
    [40] Chang, D.-Y.; Lee, C.-C.; Shiea, J., Anal. Chem. 2002, 74 (11), 2465-2469.
    [41] Chen, H.; Venter, A.; Cooks, R. G., Chem. Commun. 2006, (19), 2042-2044.
    [42] Liu, J.; Wang, H.; Manicke, N. E.; Lin, J.-M.; Cooks, R. G.; Ouyang, Z., Anal. Chem. 2010, 82 (6), 2463-2471.
    [43] Hu, B.; So, P.-K.; Chen, H.; Yao, Z.-P., Anal. Chem. 2011, 83 (21), 8201-8207.
    [44] Deng, J.; Yang, Y.; Wang, X.; Luan, T., TrAC Trends in Analytical Chemistry 2014, 55, 55-67.
    [45] Jiang, J.; Zhang, H.; Li, M.; Dulay, M. T.; Ingram, A. J.; Li, N.; You, H.; Zare, R. N., Anal. Chem. 2015, 87 (16), 8057-8062.
    [46] Chen, H.-K. Electrospray ionization using a bamboo pen nib.National Taiwan Normal University, Taipei.
    [47] Zeleny, J., Physical review 1917, 10 (1), 1.
    [48] Ikonomou, M. G.; Blades, A. T.; Kebarle, P., Anal. Chem. 1991, 63 (18), 1989-1998.
    [49] Dole, M.; Mack, L. L.; Hines, R. L.; Mobley, R. C.; Ferguson, L. D.; Alice, M. B., The Journal of Chemical Physics 1968, 49 (5), 2240- 2249.
    [50] Iribarne, J.; Thomson, B., The Journal of Chemical Physics 1976, 64 (6), 2287-2294.
    [51] Lutui, M. A.; Gilard, F.; Sablier, M., J. Mass Spectrom. 2008, 43 (8), 1123-1131.

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