[Et4N]3[Bi{Fe(CO)4}4] 與 n-BuBr在CH3CN中加熱41～42 ℃反應24小時後，再加入HOAc處理，可得到兩個中性的產物，一為雙聚合物 [n-BuBiFe(CO)4]2 (dimer)，另一為高分子聚合物 [n-BuBiFe(CO)4]￥ (polymer)。此外，若將 [Et4N]3[Bi{Fe(CO)4}4] 與HCoCCH2Br的反應，則會形成一個離子性的產物[Et4N]2[BrBiCH2C(CO)CH(CO)Fe(CO)3]2，若進一步將 [Et4N]3[Bi{Fe(CO)4}4] 與CBr4反應，其產物是一個Bi雙核的錯化合物 [Et4N]2[Bi2Br6Fe(CO)4]。然而若是在反應當中加入過量的HCoCCH2Br或是H2C=CHCH2Br，則會產生一系列的氧化性產物Bi2Fe3(CO)9、 [Et4N][BiFe3(CO)10] 、[Et4N]2[Bi4Fe4(CO)13]和 [Et4N]2[Bi4Fe5(CO)17]

The reaction of [Et4N]3[Bi{Fe(CO)4}4] with n-BuBr followed by HOAc gives two neutral compounds. One is the dimer complex [n-BuBiFe(CO)4]2, and the other is the polymer complex [n-BuBiFe(CO)4]￥. Besides, [Et4N]3[Bi{Fe(CO)4}4] reacts with HCoCCH2Br to form the ionic complex [Et4N]2[BrBi(C(O)C3H3C(O))Fe(CO)3]2. Further treatment of [Et4N]3[Bi{Fe(CO)4}4] with CBr4 gives the dinuclear complex [Et4N]2[Bi2(Br)2(Fe(CO)4)Br4]. However, if [Et4N]3[Bi{Fe(CO)4}4] is treated with excess H2C=CHCH2Br or HCoCCH2Br, a series of oxidation products Bi2Fe3(CO)9, [Et4N][BiFe3(CO)10], [Et4N]2[Bi4Fe4(CO)13], and [Et4N]2[Bi4Fe5(CO)17] are obtained.

1. Muetterties, E. L.; Rhodin, T. N.; Band, E.; Brucker, C. F.; Pretzer, W.
R. Chem. Rev. 1979, 79, 91.
2. (a) Li, S. L.; Zhang, Z. Z.; Chen, C. C.; Au-Yeung, C. F.; Mak, C. W. J.
Organomet. Chem. 1996, 522, 155. (b) Komine, N.; Hoh,H.; Hirano, M.; Komiya, S. Organometallics 2000, 19, 5251.
3. (a) Wheatley, N.; Kalck, P. Chem. Rev. 1999, 99, 3379. (b) Huang, Q.;
Wu, X.; Wang, Q.; Sheng, T. Lu, J. Inorg. Chem. 1996, 35, 893. (c) Waterman, S; Humphrey, M. G. Organometallics 1998, 17, 5789.
(d) Wong, W. T. Organometallics 1999, 18, 3474.
4. Mond, L.; Hirtz, H.; Coop, M. D. J. Chem. Soc. 1910, 997, 798.
5. Dewar, J.; Jones, H. O. Proc. R. Soc. 1905, A76, 558.
6. Dewar, J. ; Jones, H. O. Proc. R. Soc. 1907, A79, 66.
7. Cotton, F. A. Acc. Chem. Res. 1969, 2, 240.
8. (a) Xie, Y.; Schaefer, H. F. III; King, R. B. J. Am. Chem. Soc. 2000, 122,
8746. (b) Kenny, J. P.; King, R. B.; Schaefer, H. F. III J. Am. Chem. Soc. 2001, 40, 900.
9. (a) Rosa, A.; Ehlers, A. W.; Baerends, E. J.; Snijders, J. G.; Velde, g. te. J. Phys. Chem. 1996, 100, 5690. (b) Barckholtz, T. A.; Bursten, B. E. J. Organomet. Chem. 2000, 596, 212.
10. (a) McKinney, R. J. J. Chem. Soc. Chem. Commun., 1980, 490. (b) Suss-Fink, G.; Herrmann, G. J. Chem. Soc. Chem. Commun., 1985, 735.
(c) Souma, Y.; Kawasaki, H. Catal. Today 1997, 36, 91. (d) Xu, Q.; Nakatani, H.; Souma, Y. J. Org. Chem. 2000, 65, 1540.
11. (a) Dullaghan, C. A.; Carpenter, G. B.; Sweigart, D. A. Organometallics 1997, 16, 5688. (b) Zhang, X.; Dullaghan, C. A.; Watson, E. J.; Carpenter, G. B.; Sweigart, D. A. Organometallics 1998, 17, 2067. (c) Dungey, K. E.; Curtis, D. J. Am. Chem. Soc. 1997, 119, 842. (d) Raez, J.; Barjovanu, J. Massey, J. A.; Winnik, M. A.; Manners, I. Angew. Chem. Int. Ed. 2000, 39, 3862.
12. Comstock, M. C.; Shapley, J. R. Coord . Chem. Rev. 1995, 143, 501.
13. (a) Mathur, P.; Ghosh, S. Organometallics 1997, 16, 6028. (b) Masui, D.; Kochi, T.; Tang, Z.; Ishii, Y.; Mizobe, Y.; Hidai, M. J. Organomet. Chem. 2001, 620, 69.
14. (a) Nicholls, J. N. Polyhedron 1984, 3, 1307. (b) Whitmire, K. H.;
Lagrone, C. B.; Rheingold, A. L. Inorg. Chem. 1986, 25, 2472.
15. Hieber, W.; Gruber, J. Z. Anorg. Allg. Chem. 1958, 296, 91.
16. (a) Scheer, M.; Umbarkar, S. B.; Chatterjee, S.; Trivedi, R.; Mathur, P. Angew. Chem. Int. Ed. 2001, 40, 376. (b) Veith, M.; Weidner, S.; Kunze, K.; Kafer, D.; Hans, J.; Huch, V. Coord . Chem. Rev. 1994, 137, 297. (c) Goh, L. Y. Coord . Chem. Rev. 1999, 185-186, 257.
17. (a) Evans, J. Chem, Soc, Rev. 1997, 11. (b) Myllyoja, S.; Suvanto, M.; Kurhinen, M.; Hirva, P.; Pakkanen, T. A. Sur. Sci. 1999, 441, 454.
18. (a) Shieh, M.; Sheu, C.-M.; Ho, L.-F.; Cherng, J.-J.; Jang, L.-F.; Ueng,
C.-H. Inorg. Chem. 1996, 35, 5504.
19. (a) Shieh, M.; Liou, Y. Inorg. Chem. 1993, 32, 2212. (b) Shieh, M.;
Liou, Y.; Jeng, B.-W. Organometallics 1993, 12, 4926.
20. 葉秀娟，國立台灣師範大學碩士論文，1995.
21. (a) Shieh, M.; Tsai, Y.-C.; Cherng, J.-J.; Shieh, M.-H.; Chen, H.-S.;
Ueng, C.-H. Organometallics 1997, 16, 456. (b) Whitmire, K. H.; van Hal, J. W. Organometallics 1998, 17, 5197. (c) Roof, L. C.; Smith, D. M.; Drake, D. W.; Pennington, W. T.; Kolis, J. W. Inorg. Chem. 1995, 34, 337. (d) 程建彰，國立台灣師範大學博士論文，2000.
22. (a) Bruce, M. I.; Skelton, B. W.; White, A. H.; Zaitseva, N. N. J. Chem. Soc., Dalton Trans., 2000, 881. (b) Brait, S.; Gervasio, G. J.; Marabello, D.; Sappa, E. J. Chem. Soc., Dalton Trans., 2000, 989. (c) Aime, S.; Tiripicchio, A.; Camellini, M. T.; Deeming, A. J. Inorg.
Chem. 1981, 20, 2027. (d) Aime, S.; Osella, D.; Arce, A. J. ;
Deeming, A. J.; Hursthouse, M. B. Galas, A. M. R. J. Chem. Soc.,
Dalton Trans. 1986, 1459.
23. Adams, R. D.; Chen, G.; Tanner, J. T.; Yin, J. Organometallics 1990,
9, 595.
24. 陳鴻生，國立台灣師範大學碩士論文，1997。
25. Seidel, N.; Jacob, K.; Fischer, A. K. Organometallics 2001, 20, 578.
26. Agustin, D.; Rima, G.; Gornitzka, H.; Barrau, J. Inorg. Chem. 2000, 39, 5492.
27. Renia, R.; Rossell, O.; Seco, M. Organometallics 1996, 15, 5347.
28. Hitchcock, P. B.; Lappert, M. F.; Michalczyk, M. J. J. Chem. Soc. Dalton Trans. 1987, 2635.
29. Veith, D.; Hans, J. Angew. Chem. Int. Ed. 1991, 30, 878.
30. Burton, N. C.; Cardin, C. J.; Cardin, D. J.; Twamley, B.; Zubavichus,