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研究生: 李麟
Li, Lin
論文名稱: 聚(丙烯酸/丙烯醯胺)/稻殼灰的合成和性質的研究
Study on the Synthesis and Properties of Poly(Acrylic acid-co-Acrylamide)/Rice Husk Ash Hydrogel Composites
指導教授: 許貫中
Hsu, Kung-Chung
學位類別: 碩士
Master
系所名稱: 化學系
Department of Chemistry
論文出版年: 2018
畢業學年度: 106
語文別: 中文
論文頁數: 81
中文關鍵詞: 複合水膠稻殼灰合成吸水率砂漿乾縮裂縫指數
英文關鍵詞: hydrogel composites, rice husk ash, synthesis, water absorbency, mortar, drying shrinkage, cracking index
DOI URL: http://doi.org/10.6345/THE.NTNU.DC.003.2018.B05
論文種類: 學術論文
相關次數: 點閱:193下載:0
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  • 稻殼灰是在農業生產中的常見的廢棄物,本論文製備了P(AA/AM)/RHA複合水膠,並改變稻殼灰劑量和沒有添加稻殼灰的P(AA/AM)水膠比較,使用FT-IR來對水膠結構鑑定,SEM觀察表面型態,然後將水膠浸泡在去離子水、不同濃度的鹽水和孔隙溶液,測試水膠在不同環境的吸水率。
    將P(AA/AM)/RHA複合水膠添加至水泥漿、水泥砂漿中,當作自養護劑,並比較一般的P(AA/AM)水膠和稻殼灰複合水膠,對於砂漿漿體中重量損失、內部濕度、乾縮變化、自體收縮、抗壓強度以及凝結時間的影響;以及水泥漿體的裂縫指數和水泥漿體的表面型態,探討水泥漿體的水化現象。
    結果發現,P(AA/AM)/RHA複合水膠在鹽水溶液、孔隙溶液有較高的吸水率,而且對孔隙溶液有較好的保水率。將P(AA/AM)/RHA複合水膠加至水泥砂漿與水泥漿中,減少了水泥砂漿的重量損失、乾縮變化還有自收縮變化,改善了抗壓強度、內部濕度,對減少水泥漿的裂縫有不錯的效果。

    Rice husk ash (RHA) was very common waste in agricultural production. In the thesis,we had prepared P(AA/AM)/RHA hydrogel composites, and changed the dosage of RHA, compared to P(AA/AM) hydrogel without RHA. FT-IR spectrum was used to identity the functional group of hydrogels. SEM was observed the surface of hydrogels. Then the hydrogels was determined water absorbency in deionized water、saline solution of different concentration and pore solution.
    P(AA/AM)/RHA hydrogel composites were used as self-curing agent, added to cement paste and mortar. We compared mortar added to RHA composites with that added general P(AA/AM) hydrogel for the influences of weight-loss、relative humidity、drying shrinkage、autogenous shrinkage and setting time. Further, the cracking index in cement paste and the surface of cement paste were determined, observed and discussed cement hydration.
    The results indicated that the higher water absorbency of all tested P(AA/AM)/RHA hydrogel composites in saline solution, and better water retention in pore solution. When P(AA/AM)/RHA composites was added to mortar and cement paste, it reduced weight-loss、drying shrinkage and autogenous shrinkage, improved compressive strength and internal humidity, lower cracking formation had good influences in cement paste.

    摘要 Ⅰ Abstract Ⅱ 目錄 Ⅲ 第一章 緒論1 1-1 前言 1 1-2 研究目的與動機 3 1-3 研究內容 3 第二章 文獻回顧 4 2-1 水膠簡介 4 2-2 影響水膠膨潤的因素 5 2-2-1 交聯密度 5 2-2-2 親水基的親和力 6 2-2-3 吉普斯自由能 6 2-2-4 水溶液的離子濃度 7 2-2-5 水溶液的pH值 7 2-2-6 鹽水溶液的影響 8 2-3 水膠的種類 9 2-4 有機/無機複合型水膠 10 2-5 稻殼灰簡介 11 2-6 波特蘭水泥 13 2-6-1 水泥的水化反應 14 2-6-2 水泥的水化反應過程 15 2-7 混凝土的收縮變形機制 16 2-8 自養護劑的養護機理 17 2-9 水膠作為自養護劑的作用 18 第三章 水膠合成與實驗流程 21 3-1 實驗流程 21 3-2 實驗材料與實驗設備 23 3-2-1 實驗藥品 23 3-2-2 實驗儀器 25 3-3 實驗方法 26 3-3-1 P(AA/AM)的合成 26 3-3-2 P(AA/AM)/RHA的合成 27 3-4 聚合物的結構分析與性質鑑定 30 3-4-1 紅外線光譜測定 30 3-4-2 核磁共振(1H-NMR)光譜分析 30 3-4-3 掃描是電子顯微鏡(SEM)之結構鑑定 30 3-4-4 水膠吸水率之測量 31 3-4-5 水膠在鹽水溶液下的吸水率 31 3-4-6 pH值對水膠的吸水率的影響 31 3-4-7 水膠在拌合水中的吸水率 32 3-4-8 水膠在孔隙溶液(pore solution)的吸水率 32 3-4-9 水膠抗壓強度之測量 32 3-5 添加水膠的水泥漿試體之測定 33 3-5-1 水泥漿試體之拌製 33 3-5-2 水泥漿圓盤裂縫之測試 34 3-5-3 水泥漿水化反應之表面結構測定 35 3-6 添加水膠的水泥砂漿試體之測定 35 3-6-1 水泥砂漿試體之拌製 35 3-6-2 水泥砂漿的流度測試 36 3-6-3 水泥砂漿重量損失之測量 37 3-6-4 水泥砂漿內部濕度之測量 38 3-6-5 水泥砂漿抗壓強度之測量 38 3-6-6 水泥砂漿乾燥收縮之測量 39 3-6-7 水泥砂漿自體乾燥收縮之測量 40 3-6-8 水泥砂漿凝結時間之測量 41 第四章 結果與討論 42 4-1 聚合物之結構測定 42 4-1-1 單體1H-NMR光譜 42 4-1-2 稻殼灰與聚合物的紅外光光譜 43 4-1-3 稻殼灰與乾燥水膠結構之鑑定 47 4-2 RHA 含量對P(AA/AM)/RHA吸水率的影響 48 4-2-1 P(AA/AM)/RHA 水膠在去離子水溶液的吸水率影響 48 4-2-2 P(AA/AM)/RHA在鹽水溶液的吸水率影響 50 4-2-3 P(AA/AM)/RHA在孔隙溶液的吸水率影響 54 4-2-4 P(AA/AM)/RHA在拌合水的吸水率 56 4-2-5 P(AA/AM)/RHA水膠在拌合水的吸水率 58 4-2-6 稻殼灰含量對水膠抗壓強度的影響 58 4-3 P(AA/AM)/RHA對水泥砂漿的性質影響 59 4-3-1 P(AA/AM)/RHA對水泥砂漿重量損失的影響 59 4-3-2 P(AA/AM)/RHA 對水泥砂漿內部濕度的影響 61 4-3-3 P(AA/AM)/RHA 對水泥砂漿乾縮量的影響 62 4-3-4 P(AA/AM)/RHA對水泥砂漿自體收縮的影響 64 4-3-5 P(AA/AM)/RHA對水泥砂漿抗壓強度的影響 65 4-3-6 P(AA/AM)/RHA對水泥砂漿凝結時間的影響 66 4-4 P(AA/AM)/RHA對水泥漿的性質影響 67 4-4-1 水泥漿試體的SEM分析 67 4-4-2 P(AA/AM)/RHA對水泥漿圓盤裂縫影響 71 第五章 結論 74 第六章 參考文獻 75

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