當 K2TeO3 與 Fe(CO)5 在鹼性的環境下, 以甲醇為溶劑在室溫下反應
後, 再以大陽離子團 [PhCH2NMe3]+ 當配對離子 , 可以產生 [PhCH2NMe3
]2[Te6Fe8(CO)24] 與次要產物 [PhCH2NMe3]2[Te4Fe5(CO)14]。它門可以
利用對溶劑有不同的溶解渡來分離, [PhCH2NMe3]2[Te4Fe5(CO)14] 並使
用光譜分析法以及 X-ray 繞射解析鑑定其結構。起始物 [Te6Fe8(CO)24
]2- 與有機雙鹵化物 BrCH2CH2Br, BrCH2CH2Cl, ClCH2CH2CH2Cl 在 THF
環境下反應, 分別可以得到 [BrTe2Fe2(CO)6]-, Fe2(CO)6(u-TeCH2CH2
Te), 與 Fe2(CO)6(u-TeCH2CH2CH2Te)。而產物之結構可以利用 X-ray繞
射解析得到明確的鑑定。此外, 利用 NaBiO3 與 Mo(CO)6 在甲醇中反應
後, 以大陽離子團 [Et4N]+ 當配對離子, 再利用 CH2Cl2 將其萃取可以
產生新的混合金屬簇化合物 [Et4N]2[BiMo4(CO)12(u3-OMe)3].CH2Cl2,
其結構也可由 X-ray 繞射解析得到明確的鑑定。

The reaction of K2TeO3 with Fe(CO)5/KOH in MeOH followed by the
treatment with [PhCH2NMe3]Cl produces [PhCH2NMe3]2[Te6Fe8(CO)24
] and the minor product [PhCH2NMe3]2[Te4Fe5(CO)14]. [PhCH2NMe3]2
[Te4Fe5(CO)14] has been isolated and structrually characterized
by ingle-crystal X-ray diffraction and spectroscopic methods.
Treatment of [Te6Fe8(CO)24]2- with BrCH2CH2Br, BrCH2CH2Cl or
ClCH2CH2CH2Cl in THF produces [BrTe2Fe2(CO)6]-, Fe2(CO)6(u-TeCH2
CH2Te) or Fe2(CO)6(u-TeCH2CH2CH2Te), respectively. The
structures of [BrTe2Fe2(CO)6]-, Fe2(CO)6(u-TeCH2CH2Te) and Fe2(
CO)6(u-TeCH2CH2CH2Te) have been performed by single -crystal X-
ray diffraction method. Besides, the reaction of NaBiO3 with Mo(
CO)6 in MeOH followed by the treatment with [Et4N]Br produces
[Et4N]2[BiMo4(CO)12(u3-OMe)3].CH2Cl2. It has been structurally
characterized by single-crystal X-ray diffraction method and
spectroscopic methods.
The reaction of K2TeO3 with Fe(CO)5
KOH in MeOH followed by the