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研究生: 陳廷豪
Chen, Ting-Hao
論文名稱: 無機鹵素鈣鈦礦/磁性金屬薄膜 -雙層異質結構之形貌、磁性及熱穩定性分析
Morphology, magnetism and thermal stability analysis of inorganic lead halide perovskite coated on ferromagnetic layer
指導教授: 林文欽
Lin, Wen-Chin
口試委員: 洪振湧 李亞儒
口試日期: 2021/06/16
學位類別: 碩士
Master
系所名稱: 物理學系
Department of Physics
論文出版年: 2021
畢業學年度: 109
語文別: 中文
論文頁數: 67
中文關鍵詞: 鈣鈦礦磁光柯爾表面形貌CsPbBr3
英文關鍵詞: Perovskite, MOKE, AFM, CsPbBr3
研究方法: 實驗設計法行動研究法比較研究觀察研究內容分析法
DOI URL: http://doi.org/10.6345/NTNU202100484
論文種類: 學術論文
相關次數: 點閱:111下載:0
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  • 在這項研究中我們主要使用物理氣相沉積法(Physical vapor deposition, PVD)製備鐵鈀合金薄膜,並且利用旋轉塗佈法將鈣鈦礦(CsPbBr3)量子點旋塗於表面,接續觀察樣品在旋塗前後(CsPbBr3/FePd v.s FePd)的變化,包括表面形貌、光學及磁性,並且觀察不同退火溫度(100˚C ~ 180˚C)後的轉變。CsPbBr3/FePd在原子力顯微鏡(AFM)量測下,我們發現表面在經退火後粗糙度大致不變,且平均約為±10 nm高低且誤差值為1.5 nm。從掃描式電子顯微鏡(SEM)發現量子點為平均大小約11 nm的正方形,並且退火180˚C後有融合的現象。透過光致螢光(PL)的數據分析我們得知在退火100˚C後,光訊號強度下降了3/4,且發光波長有紅移4 nm的現象。最後經由磁光柯爾量測從室溫到退火160˚C,FePd樣品的矯頑場增加了74 %,而CsPbBr3/FePd樣品的矯頑場僅增加了19.2 %;由此結果方知CsPbBr3是一個可以保護磁性材料的覆蓋層。

    In this study, we used the physical vapor deposition to prepare FePd alloy, and spin-coating to spread perovskite (CsPbBr3) quantum dots (QDS) on the surface. We characterized the surface of the spin-coated perovskite and bave FePd before and after. Various measurements are carried out, including surface morphology, optical and magnetic properties, after thermal annealing the sample from 100˚C to 180˚C. The AFM study shows that the surface roughness of the CsPbBr3/ FePd remained invaricant and the average value was about ± 10 nm. The SEM study shows that the QDS were of square cubic sample with an average size around 11 nm and aggregated after thermal annealing at 180˚C. PL measurement shows that the intensity of perovskite decreases by 75 % after thermal annealing at 100˚C, and there is a red shift in PL-spectram. The magnetic coercivity of CsPbBr3/ FePd was increased by 19 % without serious inter diffusion effect as compared with the pure FePd was increased by 74 % after thermal annealing (100 to 160 ˚C). The perovskite could serve as a good capping layer, and the interface between perovskite and ferromagnetic layer sustained with good thermal stability.

    中文摘要 I Abstract II 致謝 III 第一章 緒論 1 1-1研究動機 1 1-2論文回顧 2 1-2-1 Influence of A-site cation on the thermal stability of metal halide perovskite polycrystalline films[13] 2 1-2-2 Discrete interfacial effects of organic lead halide perovskite coating on magneticunderlayer: MAPbBr3/FePd heterostructure[22] 3 第二章 基礎原理 4 2-1真空系統 4 2-2磁滯曲線 5 2-3磁性物質 6 2-3-1強磁 7 2-3-2弱磁 8 2-4磁異向性 (Magnetic anisotropy) 10 2-5鈣鈦礦 13 第三章 儀器介紹與原理 16 3.1磁光柯爾效應 (Magneto-Optic Kerr Effect, MOKE) 16 3-2原子力顯微鏡 (Atomic Force Microscopy, AFM) 20 3-3掃描電子顯微鏡 (Scanning Electron Microscope, SEM) 22 3-4光致螢光光譜儀 (Photoluminescence, PL) 24 第四章 樣品製備與步驟 27 4-1矽(SiO2)基板清洗 27 4-2使用電子束蒸鍍製備樣品 28 4-3製備鈣鈦礦溶液 30 第五章 實驗結果分析 33 5-1實驗流程 33 5-1鐵鈀/氧化矽-結構(FePd/SiO2) 34 5-1-1 原子力顯微鏡分析 34 5-1-2 磁光科爾分析 37 5-2鈣鈦礦/鐵鈀合金/氧化矽(CsPbBr3/FePd/SiO2) 42 5-2-1 原子力顯微鏡(AFM)分析 42 5-2-2 光致發光光譜儀(PL)分析 45 5-2-3掃描式電子顯微鏡(SEM)分析 47 5-2-4 磁光科爾分析 49 5-3 藍光雷射照射CsPbBr3/Fe 55 5-3-1 CsPbBr3/Fe/SiO2 gride 56 5-3-2 CsPbBr3/Fe 10 nm/SiO2 57 5-3-3 CsPbBr3/Fe 7 nm/SiO2 58 第六章 實驗結果討論 60 6-1 CsPbBr3/FePd/SiO2及FePd/SiO2表面形貌比較 60 6-2 CsPbBr3/FePd/SiO2 經過退火後產生的缺陷 61 6-3 CsPbBr3/FePd/SiO2 PL訊號分析 62 6-4 CsPbBr3/FePd/SiO2及FePd/SiO2 磁光柯爾比較 63 第七章 結論 64 第八章 未來工作 65 參考文獻 66

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