本論文主要利用雙二苯膦烷基配子和Mo(CO)4(bipy)Mo(CO)4(phen), Mo(CO)4(bpp)(bpp=2, 3-Bis(2-pyridyl)pyrazine),以TMNO（氧化三甲基胺）合成含氮，磷混合配子三羰基零價金屬錯合物。紅外線光譜初步鑑定，並且製備得到單晶錯合物；Cr(CO)4(72-bpp)(1)， Mo(CO)4(72-bpp)(2)， Mo(CO)3(bipy)(71-dppm)(3)， W(CO)4(72-tpy)(4)， {Mo(CO)3(phen)}2(u-dppp)(5)， Mo(CO)3(phen)(71-dppm)(6)， Mo(CO)3(72-bpp)(71-dppm)(7)，所得到之單晶錯合物，進一步以X-ray繞射法完成其結構解析。
紅棕色的（１）錯合物為單斜晶系（Monoclinic），空間群P 21/n，a=12.220(6)A，b=11.607(6)A，c=13.076(5)A β=112.18(4)°，V=1717.5(1)A3，Z=4，Rf=0.050，Rw=0.059，Gof=3.82。
紅棕色的（2）錯合物為單斜晶系（Monoclinic），空間群P 21/n，a=12.364(3)A，b=11.5253(2)A，c=13.314(7)A，β=112.86(3)°，V=1748.2(1)A3，Z=4，Rf=0.033，Rw=0.030，Gof=1.73；其與（１）錯合物為同形異質體。
深紅色的（3）錯合物為單斜晶系（Monoclinic），空間群C 2/c，a=28.081(7)A，b=10.698(8)A，c=22.893(6)A，β=101.852(2)°，V=6731(6)A3，Z=8，Rf=0.052，Rw=0.047，Gof=2.05。
紅棕色的（4）錯合物為三斜晶系（Triclinic），空間群P 1，a=7.190(3)A，b=11.062(3)A，c=13.447(4)A，α=102.47(3)°，β=89.762(3)°，γ=102.27(3)°，V=1019.5(6)A3，Z=2，Rf=0.082，Rw=0.130，Gof=8.11。
深紅色的（5）錯合物為單斜晶系（Monoclinic），空間群P 21/c，a=10.7743(2)A，b=26.297(3)A，c=18.921(5)A，β=100.740(2)°，V=5267.0(17)A3，Z=4，Rf=0.055，Rw=0.050，Gof=1.76。
深紅色的（6）錯合物為單斜晶系（Monoclinic），空間群P 21/n，a=18.429(6)A，b=11.1618(2)A，c=20.189(4)A，β=107.395(2)°，V=3962.9(2)A3，Z=4，Rf=0.098，Rw=0.093，Gof=4.00。
藍綠色的（7）錯合物為三方晶系（Trigonal），空間群R 3，a=28.589(6)A，c=29.261(1)A，V=20712(8)A3，Z=18，Rf=0.094，Rw=0.113，Gof=4.16；其與（3），（6）錯合物相同，僅以(P-P)雙牙配子之一端磷參與鍵結，另一端磷則懸吊在外。

Molybdenum tricarbonyl complexes containing nitrogen and phosphorous ligands were synthesized with Mo(CO)4(bipy), Mo(CO)4(phen), Mo(CO)4(bpp) (bpp=2, 3-Bis(2-pyridyl)pyrazine) and alkyl-bis(diphenyl phosphino) ligand by oxidative decarbonylation using trimethylamine N-oxide as an chemical initiator. complexes were indentified by nfrared and other spectra. The crystal structures of Cr(CO)4(72-bpp)(1), Mo(CO)4(72-bpp)(2), Mo(CO)3(bipy)(71-dppm)(3), W(CO)4(72-tpy)(4), {Mo(CO)3(phen)}2(μ-dppm)(5), Mo(CO)3(phen)(71-dppm)(6), Mo(CO)3(72-bpp)(71-dppm)(7) have been undertaken by X-ray diffration method.
Browm red crystal of 1 crystallized in the monoclinic space group P 21/n with a=12.220(6)A, b=11.607(6)A, c=13.076(5)A, β=112.18(4)°, V=1717.5(1)A3, Z=4, Rf=0.050, Rw=0.059, Gof=3.82.
Browm red crystal of 2 crystallized in the monoclinic space group P 21/n with a=12.364(3)A, b=11.5253(2)A, c=13.314(7)A, β=112.86(3)°, V=1748.2(1)A3, Z=4, final R value are Rf=0.033, Rw=0.030, Gof=1.73; crystal 2 and crystal 1 are isomorphous.
Deeply red crystal of 3 crystallized in the monoclinic space group C 2/c with a=28.081(7)A, b=10.698(8)A, c=22.893(6)A, β=101.852(2)°, V=6731(6)A3, Z=8, final R value are Rf=0.052, Rw=0.047, Gof=2.05.
Browm red crystal of 4 crystallized in the triclinic space group P 1 with a=7.190(3)A, b=11.062(3)A, c=13.447(4)A, α=102.47(3)°, β=89.762(3)°, γ=102.27(3)°, V=1019.5(6)A3, Z=2, Rf=0.082, Rw=0.130, Gof=8.11.
Deeply red crystal of 5 crystallized in the monoclinic space group P 21/c with a=10.7743(2)A, b=26.297(3)A, c=18.921(5)A, β=100.740(2)°, V=5267.0(17)A3, Z=4, final R value are Rf=0.055, Rw=0.050, Gof=1.76.
Deeply red crystal of 6 crystallized in the monoclinic space group P 21/n with a=18.429(6)A, b=11.1618(2)A, c=20.189(4)A, β=107.395(2)°, V=3962.9(2)A3, Z=4, final R value are Rf=0.098, Rw=0.093, Gof=4.00.
Blue green crystal of 7 crystallized in the trigonal space group R 3 with a=28.589(6), c=29.261(1)A, V=20712(8)A3, Z=18, Rf=0.094, Rw=0.113, Gof=4.16；complexes (7), (6) and (3) are similiar with that the bidentate (P-P) ligand uses only one phosphine to coordinate to metal, and the other phosphine atom in the same ligand is dangling.