研究生: |
陳文賓 Wen-bin Chen |
---|---|
論文名稱: |
硫酸鈉與硼酸溶液對導電玻璃ITO上鍍鈷的影響 The effects of sodium sulfate and boric acid solution on coating cobalt onto ITO substrate |
指導教授: |
傅祖怡
Fu, Tsu-Yi 何慧瑩 Ho, Huei-Ying |
學位類別: |
碩士 Master |
系所名稱: |
物理學系 Department of Physics |
論文出版年: | 2012 |
畢業學年度: | 100 |
語文別: | 中文 |
論文頁數: | 77 |
中文關鍵詞: | 磁滯曲線 、磁性 、矯頑力 、磁光柯爾效應 、循環伏安法 、計時安培分析法 |
英文關鍵詞: | Hysteresis curves, magnetic, coercivity, magneto-optical Kerr effect (MOKE), cyclic voltammetry (CV), chronoamperometry (CA) |
論文種類: | 學術論文 |
相關次數: | 點閱:230 下載:9 |
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本研究探討硫酸鈉與硼酸溶液對導電玻璃ITO上鍍鈷的影響。以循環伏安法找出適合的電鍍電壓,並改變不同的電解質輔助液探討對鈷膜表面的影響。我們藉由金相顯微鏡、原子力顯微鏡對鈷膜表面進行觀察,再以固定電鍍電壓的方式,分析得到電流對時間的關係,判定鈷在ITO上為接近瞬時成核的機制,並利用磁光柯爾效應測量鈷膜的磁性。
在實驗的過程中我們發現,電解質輔助液硫酸鈉以及硼酸各有其優缺點,硫酸鈉幫助我們決定所需要電鍍的電壓以及增加還原電流,硼酸輔助液不僅可以抑制產生Co的氫氧化物,它還能讓薄膜均勻成長。我們發現硼酸的濃度明顯影響Co島的結構,並進而改變磁性之量測結果。
The effects of sodium sulfate (Na2SO4) and boric acid (H3BO3) solution on coating cobalt onto the ITO were investigated by cyclic voltammetry (CV), metallurgical microscopy, atomic force microscope (AFM) and magneto-optical Kerr effect (MOKE).
We looked for the proper plating voltage of Co by CV studies; we observed the topography of Co films by optical microscope and AFM. During the electrodeposition process, we monitored the relationship between current and time by chronoamperometry (CA). From analyzing the CA curves, we determined that the growth kinetic of the Co onto ITO substrate was approximately instantaneous nucleation mechanism.
The data clearly shows that adding Na2SO4 is helpful for us to determine the proper voltage of deposition Co; it also increases the reduction current. Adding H3BO3 not only inhibits the reduction of Co hydroxide but also helps the Co nuclei to uniformly distribute on the ITO surface. The concentration of H3BO3 significantly affects the structure and varies the magnetic properties of the Co nuclei.
OE Kongstein, GM Haarberg, J. Thonstad (2007). J. Appl. Electrochem. 37 ,669.
M. Rivera, C.H. Rios-Reyes, L.H. Mendoza-Huizar(2008). Appl. Surf. Sci. 255, 1754-1758.
KL Kavanagh and ZL Bao , J. Cryst. Growth 287 (2006).Aligned Co/GaAs by Electrodeposition, 514-516.
Darko Grujicic, Batric Pesic(2004) .Electrochimica Acta 49,4719–4732.
Hiroki,MIYAMOTO(1966).The Magnetic Properties of Ni(OH)2 and β-Co(OH)2.Bulletin of the Institute for Chemical Research, Kyoto University,44(5),420-429.
JOHN B. PARISE, WILLIAM G. MARSHALL, RONALD I. SMITH, H.D. LUTZ, HENDRIK MÖLLER (2000).American Mineralogist, Volume 85,189–193.
Enghag, Per (2004). "Cobalt". Encyclopedia of the elements: technical data, history, processing,applications. p. 667.
胡啟章(2002),電化學原理與方法。臺北市:五南
蔡志申( 2003 ),表面磁光柯爾效應與超薄膜磁性性質,物理雙月刊,廿五 巻五期.
何慧瑩(1998), 表面磁光柯爾效應儀的製作及鈷超薄膜在鉑(111)面上的磁性研究, 碩士論文.
D.R. Gabe(1997). J. Appl. Electrochem. 27,908.
M. Rojas, C.L. Fan, H.J. Miao, D.L. Piron(1992). J. Appl. Electrochem. 22 ,1135.
Vanýsek, Petr (2007). “Electrochemical Series”, in Handbook of Chemistry and Physics: 88th Edition (Chemical Rubber Company).
Peter Atkins (1997). Physical Chemistry, 6th edition (W.H. Freeman and Company, New York).
E. Gomez, A. Labarta, A. Llorente, E. Valles(2001). Electrodeposited cobalt+copper thin films on ITO substrata,Journal of Electroanalytical Chemistry 517,63–68.
J.S. Santos, R. Matos, F. Trivinho-Strixino, E.C. Pereira(2007) .Electrochimica Acta 53 ,644–649.
Rios-Reyes, C. H.; Granados-Neri, M.; Mendoza-Huizar, L. H.( 2009). Quim. Nova, 32, 2382.
S.P. Jiang, Y.Z. Chen, J.K. You, T.X. Chen, A.C.C. Tseung(1990). J. Electrochem.Soc. 137,3374.
S. Jaya, T. Prasada Rao, G. Prabhakara Rao(1987). Electrochim. Acta 32,1073.
Huajun Zheng,Fengqiu Tang, Melvin Lim ,Thomas Ruf ford, Aniruddh Mukherji,Lianzhou Wang ,Gaoqing (Max) Lu, Journal of Power Sources(2009) .Volume 193, Issue 2, Pages 930-934.
A.B. Soto, E.M. Arce, M. Palomar-Pardave and I. Gonzales(1996). “Electrochemical Nucleation of Cobalt onto Glassy Carbon Electrode from Ammonium Chloride Solutions”, Electrochim. Acta., 41 (16), 2647-2655.
B.C. Tripathy, P. Singh, D.M. Muir, Metall(2001). Trans. B 32,395.
N. Zech, D. Landolt(2000). Electrochim. Acta 45,3461.
J.P. Hoare(1986). J. Electrochem. Soc. 133,2491.
B.V. Tilak, A.S. Gendron, M.A. Mosoiu(1977). J. Appl. Electrochem. 7 ,495.
J. Horkans(1979). J. Electrochem. Soc. 126 ,1861.
K.M. Yin, B.T. Lin(1996). Surf. Coat. Technol. 78,205.
Darko Grujicic, Batric Pesic (2004),Electrochimica Acta 49,4719–4732.
Scharifker, B. R.; Hills, G.( 1983). Electrochim. Acta, 28, 879.
Scharifker, B. R.; Mostany, J.( 1984). J. Electroanal. Chem., 177, 13.
S. Kaya(1928), Sci. Reports Tohoku Univ. 17, 1157