Author: |
黃國賓 |
---|---|
Thesis Title: |
結合二硫化鐵奈米晶體與聚(3-己基塞吩)、[6,6]苯基富勒烯丁酸甲酯之無機/有機及與氧化鋅奈米晶體之全無機混掺光電元件應用 |
Advisor: | 陳家俊 |
Degree: |
碩士 Master |
Department: |
化學系 Department of Chemistry |
Thesis Publication Year: | 2008 |
Academic Year: | 96 |
Keywords (in Chinese): | 太陽能電池 、二硫化鐵 、光電元件 |
Thesis Type: | Academic thesis/ dissertation |
Reference times: | Clicks: 226 Downloads: 0 |
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摘要
二硫化鐵(FeS2),能隙0.95eV之半導體,具有高吸光性,製備容易且地球含量豐富,其塊材(黃鐵礦)早期亦作為太陽能電池之材料。,在本論文中以溶液法製備花形FeS2奈米粒子,以及FeS2混掺過渡元素銅、鎳及鈷之奈米粒子,並利用其製作各種光電元件:(1) FeS2奈米粒子與氧化鋅(ZnO)奈米柱混掺之全無機太陽能電池,其中ZnO亦為熱門之光電元件材料,且有機高分子與無機材料相比,其使用壽命是個不小挑戰,因此全無機太陽能電池應為往後之趨勢。FeS2及ZnO均無污染無毒,對地球並無負擔,在環保意識高漲的今日,不失為一種環境接受性良好之綠色材料; (2) FeS2、P3HT與PCBM之無機奈米粒子/有機高分子混掺太陽電池,期望加入FeS2奈米粒子後,正好能補足紅光區之吸收,達成全日光波長均能轉換為電能之目標,在AM1.5G的模擬光源下,其開路電壓提高為0.5V,短路電流提高為6.1mA;(3) FeS2與P3HT之無機奈米粒子/有機高分子混掺太陽電池,經改善FeS2在氯仿中分散度後,並全程在乾燥箱內製造元件,在AM1.5G的模擬光源下,其光電轉換效率可達0.139%。
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